Synthesis of the silicoaluminophosphate and metal silicoaluminophosphate polymorphs of the molecular sieve SAPO-18 using cyclic quaternary ammoniums as organic structure-directing agents (OSDA) and use thereof as a catalyst.

Synthesis of the silicoaluminophosphate and metal silicoaluminophosphate polymorphs of the molecular sieve SAPO-18 using cyclic quaternary ammoniums as organic structure-directing agents (OSDA) and use thereof as a catalyst.

Provided is a method for producing an inexpensive, high-performance AEI type zeolite and an AEI type zeolite having a Si/Al ratio of 6.5 or less by using neither an expensive Y type zeolite as a raw material nor dangerous hydrofluoric acid. The method for producing an AEI type zeolite having a Si/Al ratio of 50 or less includes: preparing a mixture including a silicon atom material, an aluminum atom material, an alkali metal atom material, an organic structure-directing agent, and water; and performing hydrothermal synthesis of the obtained mixture, in which a compound having a Si content of 20% by weight or less and containing aluminum is used as the aluminum atom material; and the mixture includes a zeolite having a framework density of 14 T/1000 Å.sup.3 or more in an amount of 0.1% by weight or more with respect to SiO.sub.2 assuming that all Si atoms in the mixture are formed in SiO.sub.2.

A new family of crystalline microporous silicometallophosphate designated SAPO-69 has been synthesized. These silicometallophosphate are represented by the empirical formula of:

R.sup.p+.sub.rM.sub.m.sup.+E.sub.xPSi.sub.yO.sub.z

where M is an alkali metal such as potassium, R is an organoammonium cation such as ethyltrimethylammonium and E is a trivalent framework element such as aluminum or gallium. The SAPO-69 family of materials represent the first phosphate-based molecular sieves to have the OFF topology and have catalytic properties for carrying out various hydrocarbon conversion processes and separation properties for separating at least one component.

A molecular sieve of MFI structure has a ratio of n(SiO2)/n(Al2O3) of more than 15 and less than 70. It has a content of phosphorus of 1-15 wt %, calculated as P.sub.2O.sub.5 and based on the dry weight of the molecular sieve and a content of the supported metal in the molecular sieve 1-10 wt % based on the oxide of the supported metal and the dry weight of the molecular sieve. The supported metal is one or two selected from lanthanum and cerium. The volume of mesopores in the molecular sieve represents 40-70% by volume of the total pore volume of the molecular sieve by volume, measured by a nitrogen adsorption BET specific surface area method, and the volume of mesopores means the pore volume of the pores having a diameter of more than 2 nm and less than 100 nm.

A composite material of Angstrom-scale nanowire arrays in zeolite and its fabrication methods are provided. The zeolite can be prepared by a hydrothermal method and the Angstrom-scale nanowire arrays can be prepared by using zeolite as a template. The zeolite can have porous structures with an average pore size of 0.74 nm and the plurality of nanowires can have an average diameter smaller than 1 nm and can be dispersed on internal or external surfaces of the porous structures. The Angstrom-scale nanowire arrays can be made of aluminum (Al), gallium (Ga), zinc (Zn), or carbon (C). A composite material of the Angstrom-scale aluminum (Al), gallium (Ga), or zinc (Zn) nanowire arrays in zeolite can exhibit characteristics of one-dimensional (1D) superconductor.

A composite material of Angstrom-scale nanowire arrays in zeolite and its fabrication methods are provided. The zeolite can be prepared by a hydrothermal method and the Angstrom-scale nanowire arrays can be prepared by using zeolite as a template. The zeolite can have porous structures with an average pore size of 0.74 nm and the plurality of nanowires can have an average diameter smaller than 1 nm and can be dispersed on internal or external surfaces of the porous structures. The Angstrom-scale nanowire arrays can be made of aluminum (Al), gallium (Ga), zinc (Zn), or carbon (C). A composite material of the Angstrom-scale aluminum (Al), gallium (Ga), or zinc (Zn) nanowire arrays in zeolite can exhibit characteristics of one-dimensional (1D) superconductor.

A catalyst material for abatement of exhaust gas emissions from a lean burn engine is provided, the catalyst material including a metal-exchanged SAPO-34 material, and an oxide layer at least partially covering an outside surface of the SAPO-34 material, wherein the oxide layer is not substantially blocking the pores of the SAPO-34 material.

A catalyst material for abatement of exhaust gas emissions from a lean burn engine is provided, the catalyst material including a metal-exchanged SAPO-34 material, and an oxide layer at least partially covering an outside surface of the SAPO-34 material, wherein the oxide layer is not substantially blocking the pores of the SAPO-34 material.

The invention concerns a process for preparing a copper-comprising SAPO material with AFX structure, comprising at least the steps of mixing, in an aqueous medium, at least one aluminum source, at least one silicon source, at least one copper source, at least one phosphorus source, a TETA complexing agent and a TMHD structuring agent, in order to obtain a gel, and hydrothermal treatment of said gel with a shear rate of less than 50 s.sup.−1 in order to obtain crystallization of said copper-comprising SAPO material with AFX structure.