The invention concerns a process for preparing a copper-comprising SAPO material with AFX structure, comprising at least the steps of mixing, in an aqueous medium, at least one aluminum source, at least one silicon source, at least one copper source, at least one phosphorus source, a TETA complexing agent and a TMHD structuring agent, in order to obtain a gel, and hydrothermal treatment of said gel with a shear rate of less than 50 s.sup.−1 in order to obtain crystallization of said copper-comprising SAPO material with AFX structure.

The invention relates to a molecular sieve composition, a process of preparing same and use thereof in the production of lower olefins. The molecular sieve composition comprises an aluminophosphate molecular sieve and a CO adsorbing component, both of which are present independently of each other. When the molecular sieve composition is used as a catalyst for producing lower olefins using synthesis gas as a raw material, the molecular sieve composition has the advantages of high selectivity to lower olefins and the like.

The invention relates to a molecular sieve composition, a process of preparing same and use thereof in the production of lower olefins. The molecular sieve composition comprises an aluminophosphate molecular sieve and a CO adsorbing component, both of which are present independently of each other. When the molecular sieve composition is used as a catalyst for producing lower olefins using synthesis gas as a raw material, the molecular sieve composition has the advantages of high selectivity to lower olefins and the like.

A peak intensity of a (002) plane is greater than or equal to 0.5 times a peak intensity of a (100) plane in an X-ray diffraction pattern obtained by irradiation of X-rays to a membrane surface of the ERI membrane.

A peak intensity of a (002) plane is greater than or equal to 0.5 times a peak intensity of a (100) plane in an X-ray diffraction pattern obtained by irradiation of X-rays to a membrane surface of the ERI membrane.

An aluminophosphate-metal oxide bonded body including a metal oxide having a bonding surface on a part of the surface thereof, and aluminophosphate that is disposed on the bonding surface of the metal oxide, wherein an alkali metal, an alkaline earth metal or both of these is/are disposed on the bonding surface of the metal oxide, and the content rate of the alkali metal, alkaline earth metal or both is from 0.3 to 30.0% by mass with respect to all of the substances that are disposed on the bonding surface of the metal oxide. An aluminophosphate-metal oxide bonded body that provides a favorable bonded state even for complicated shapes is provided.

An aluminophosphate molecular sieve SCM-18 has a schematic chemical composition, expressed on a molar basis, of Al.sub.2O.sub.3.n P.sub.2O.sub.5, in which wherein n represents a phosphorus to aluminum molar ratio, and is in a range of about 0.8-1.2. The aluminophosphate molecular sieve has a unique X-ray diffraction pattern, and can be used as an adsorbent, a catalyst or a catalyst carrier.

An aluminophosphate molecular sieve SCM-18 has a schematic chemical composition, expressed on a molar basis, of Al.sub.2O.sub.3.n P.sub.2O.sub.5, in which wherein n represents a phosphorus to aluminum molar ratio, and is in a range of about 0.8-1.2. The aluminophosphate molecular sieve has a unique X-ray diffraction pattern, and can be used as an adsorbent, a catalyst or a catalyst carrier.

A novel silicoaluminophosphate molecular sieve has a schematic chemical composition, expressed on a molar basis, of mSiO.sub.2.Al.sub.2O.sub.3.nP.sub.2O.sub.5, in which m represents the molar ratio of SiO.sub.2 to Al.sub.2O.sub.3 and is in a range of about 0.005-0.15, and n represents the molar ratio of P.sub.2O.sub.5 to Al.sub.2O.sub.3 and is in a range of about 0.7-1.1. The silicoaluminophosphate molecular sieve has a unique X-ray diffraction pattern, and can be used as an adsorbent, a catalyst or a catalyst carrier.

A novel silicoaluminophosphate molecular sieve has a schematic chemical composition, expressed on a molar basis, of mSiO.sub.2.Al.sub.2O.sub.3.nP.sub.2O.sub.5, in which m represents the molar ratio of SiO.sub.2 to Al.sub.2O.sub.3 and is in a range of about 0.005-0.15, and n represents the molar ratio of P.sub.2O.sub.5 to Al.sub.2O.sub.3 and is in a range of about 0.7-1.1. The silicoaluminophosphate molecular sieve has a unique X-ray diffraction pattern, and can be used as an adsorbent, a catalyst or a catalyst carrier.