Synthesizing lithium lanthanum zirconate includes combining a reagent composition with a salt composition to yield a molten salt reaction medium, wherein the reagent composition comprises a lithium component, a lanthanum component, and zirconium component having a lithium:lanthanum:zirconium molar ratio of about 7:3:2; heating the molten salt reaction medium to yield a reaction product; and washing the reaction product to yield a crystalline powder comprising lithium lanthanum zirconate.

Zirconium and yttrium oxide-based composition with a specific surface area of at least 12 m 2/g following calcination at 1000° C. for 10 hours. This composition is obtained via a method wherein a mixture of zirconium and yttrium compounds is precipitated with a base; the resulting precipitate-containing medium is heated; a compound selected from anionic surfactants, non-ionic surfactants, polyethylene glycols, carboxylic acids and the salts thereof and carboxymethylated fatty alcohol ethoxylate-type surfactants is then added to said precipitate, and, finally, the precipitate is calcined. Said composition can be used as a catalyst.

In an amorphous complex metal oxide and a method for producing the same of the present disclosure, the amorphous complex metal oxide is a three-components metal oxide containing titanium (Ti), cerium (Ce), and zirconium (Zr), wherein the amorphous complex metal oxide is amorphous.

Disclosed is a process for coating onto a substrate, including preparing a precursor having a general formula Q.sub.m/nMO.sub.xF.sub.y by a reaction M(OH).sub.x+yHF+m/nQ(OH).sub.n.fwdarw.Q.sup.n+.sub.m/n(MO.sub.xF.sub.y).sup.m−, wherein Q is an onium ion, selected from quaternary alkyl ammonium, quaternary alkyl phosphonium and trialkylsulfonium; M is a metal capable of forming an oxofluorometallate, where M may further comprise one or more additional metal, metalloid, and one or more of phosphorus (P), sulfur (S) and selenium (Se), iodine (I), and arsenic (As) or a combination thereof, and x>0, y>0, m≥1, n≥1; combining the precursor with a lithium ion source and with the substrate, and mixing to form a coating composition comprising a lithium oxofluorometallate having a general formula Li.sub.mMO.sub.xF.sub.y on the substrate. Further disclosed is a core-shell electrode active material including a core capable of intercalating and deintercalating lithium coated with the lithium oxofluorometallate having the general formula Li.sub.mMO.sub.xF.sub.y.

Fabricating a layer including lithium lanthanum zirconate (Li.sub.7La.sub.3Zr.sub.2O.sub.12) layer includes forming a slurry including lanthanum zirconate (La.sub.2Zr.sub.2O.sub.7) nanocrystals, a lithium precursor, and a lanthanum precursor in stoichiometric amounts to yield a dispersion including lithium, lanthanum, and zirconium. In some cases, the dispersion includes lithium, lanthanum, and zirconium in a molar ratio of 7:3:2. In certain cases, the slurry includes excess lithium. The slurry is dispensed onto a substrate and dried. The dried slurry is calcined to yield the layer including lithium lanthanum zirconate.

The present invention is directed to battery technologies and processing techniques thereof. In various embodiments, ceramic electrolyte powder material (or component thereof) is mixed with two or more flux to form a fluxed powder material. The fluxed powder material is shaped and heated again at a temperature less than 1100° C. to form a dense lithium conducting material. There are other variations and embodiments as well.

The present invention relates to a mixed oxide composition based on zirconium and cerium, to the process for preparing it and to its use in the field of catalysis. The mixed oxide is characterized by a high specific surface area and a specific porosity after calcination at 1100° C.

Set forth herein are garnet material compositions, e.g., lithium-stuffed garnets and lithium-stuffed garnets doped with alumina, which are suitable for use as electrolytes and catholytes in solid state battery applications. Also set forth herein are lithium-stuffed garnet thin films having fine grains therein. Disclosed herein are novel and inventive methods of making and using lithium-stuffed garnets as catholytes, electrolytes and/or anolytes for all solid state lithium rechargeable batteries. Also disclosed herein are novel electrochemical devices which incorporate these garnet catholytes, electrolytes and/or anolytes. Also set forth herein are methods for preparing novel structures, including dense thin (<50 um) free standing membranes of an ionically conducting material for use as a catholyte, electrolyte, and, or, anolyte, in an electrochemical device, a battery component (positive or negative electrode materials), or a complete solid state electrochemical energy storage device. Also, the methods set forth herein disclose novel sintering techniques, e.g., for heating and/or field assisted (FAST) sintering, for solid state energy storage devices and the components thereof.

An electromechanical transducer includes an electromechanical transducer film of laminated layers including a perovskite-type complex oxide represented by a general formula of ABO.sub.3; and a pair of electrodes opposed to each other with the electromechanical transducer film interposed between the pair of electrodes. In the general formula of ABO.sub.3, A includes Pb and B includes Zr and Ti. A variable ratio ΔPb of Pb, determined by Pb(max)−Pb(min), is 6% or less and a variable ratio ΔZr of Zr, determined by Zr(max)−Zr(min), is 9% or less, where an atomic weight ratio of Pb in the electromechanical transducer film is denoted by Pb/B, an atomic weight ratio of Zr in the electromechanical transducer film is denoted by Zr/B, a maximum value and a minimum value of the atomic weight ratio of Pb in a film thickness direction of the electromechanical transducer film are denoted by Pb(max) and Pb(min), respectively, and a maximum value and a minimum value of the atomic weight ratio of Zr in the film thickness direction of the electromechanical transducer film are denoted by Zr(max) and Zr(min), respectively.

The present invention provides titanium nitride-reinforced zirconia toughened alumina (ZTA) ceramic powder and a preparation method thereof, and belongs to the technical field of ceramic materials. The preparation method provided in the present invention includes the following steps: mixing an aluminum salt, a zirconium salt, a yttrium salt, and a titanium salt with water to obtain a mixed aqueous solution, where the aluminum salt, the zirconium salt, the yttrium salt, and the titanium salt are water-soluble inorganic salts; mixing the obtained mixed aqueous solution and an alkaline precipitant for precipitation, to obtain hydroxide precipitate powder; successively conducting first calcination and second calcination on the obtained hydroxide precipitate powder, to obtain oxide solid solution powder; and subjecting the obtained oxide solid solution powder to selective nitridation reaction, to obtain titanium nitride-reinforced ZTA ceramic powder.