An improved method for recovering metals from spent supported catalysts, including spent supported hydroprocessing catalysts. The method and associated processes comprising the method are useful to recover spent supported catalyst metals used in the petroleum and chemical processing industries. The method generally involves a combination of a pyrometallurgical and a hydrometallurgical method and includes forming a potassium carbonate calcine from the spent supported catalyst containing Group VIIIB/Group VIB/Group VB metal compound(s) combined with potassium carbonate, and extracting and recovering soluble Group VIB metal and soluble Group VB metal compounds from the potassium carbonate calcine.

An inorganic material in a form of open-porosity particles, each of the particles comprising a lead vanadate or phosphovanadate of formula Pb.sub.3-xX.sub.x(VO.sub.4)2.sub.-2y(PO.sub.4)2.sub.y,wherein x = 0 or x > 0 but ≤ 0.33; y = 0 or y > 0 but < 1;X = Ba.sup.2+, Ca.sup.2+, Sr.sup.2+ or Cd.sup.2+; and metallic lead or a lead salt. A method for preparing the material, a method for capturing iodine present in a gaseous effluent as well as a method for conditioning iodine present in a gaseous effluent in a form of an iodoapatite.

A hybrid photoactive heterojunction including a copper vanadate, Cu.sub.2V.sub.2O.sub.7 (CVO) and a zinc vanadate, Zn.sub.2V.sub.2O.sub.6 (ZVO). Particles of the ZVO are dispersed in particles of the CVO to form the hybrid photoactive heterojunction. The hybrid photoactive heterojunction in the form of a photoactive film includes a substrate which is at least partially coated with the hybrid photoactive heterojunction. A method of photodegrading a dye includes contacting the photoactive film and the dye in a solution and exposing the solution to light. A method of photoelectrochemically oxidizing water includes contacting the photoactive film with water in a solution and exposing the solution to light.

A hybrid photoactive heterojunction including a copper vanadate, Cu.sub.2V.sub.2O.sub.7 (CVO) and a zinc vanadate, Zn.sub.2V.sub.2O.sub.6 (ZVO). Particles of the ZVO are dispersed in particles of the CVO to form the hybrid photoactive heterojunction. The hybrid photoactive heterojunction in the form of a photoactive film includes a substrate which is at least partially coated with the hybrid photoactive heterojunction. A method of photodegrading a dye includes contacting the photoactive film and the dye in a solution and exposing the solution to light. A method of photoelectrochemically oxidizing water includes contacting the photoactive film with water in a solution and exposing the solution to light.

Materials, designs, methods of manufacture, and devices are provided for an anode material for a rechargeable lithium-ion battery. For example, an anode material may include Li.sub.3±xV.sub.2±yO.sub.5±z, wherein 0≤x≤7, 0≤y≤1, and z may be based on the charge resulting from Li.sub.3±x and V.sub.2±y. Also, a cell can include a lithiated anode material. The lithiated anode material may include Li.sub.3±xV.sub.2±y O.sub.5±z. The lithiated anode material may be casted on a first substrate to form a lithiated anode, having a separator stacked on the lithiated anode. The separator may include electrolytes. A cathode can be stacked on the separator. The cathode being formed by casting a cathode material on a second substrate.

A CoVO.sub.x composite electrode and method of making is described. The composite electrode comprises a substrate with an average 0.5-5 μm thick layer of CoVO.sub.x having pores with average diameters of 2-200 nm. The method of making the composite electrode involves contacting the substrate with an aerosol comprising a solvent, a cobalt complex, and a vanadium complex. The CoVO.sub.x composite electrode is capable of being used in an electrochemical cell for water oxidation.

Disclosed is a positive electrode active material for a lithium-ion battery, wherein the positive electrode active material has small volume changes during charging and discharging, and when applied to a battery, can improve the cycle characteristics of the battery. The positive electrode active material of the present disclosure has a disordered rock salt structure belonging to space group Fm-3m, and has a composition represented by Li.sub.1+xTi.sub.yV.sub.zO.sub.2 (where 0<x≤0.20, 0<y≤0.40, and 0.40≤z≤0.85).

An electrode comprising a space group Pna2.sub.1 VOPO.sub.4 lattice, capable of electrochemical insertion and release of alkali metal ions, e.g., sodium ions. The VOPO.sub.4 lattice may be formed by solid phase synthesis of KVOPO.sub.4, milled with carbon particles to increase conductivity. A method of forming an electrode is provided, comprising milling a mixture of ammonium metavanadate, ammonium phosphate monobasic, and potassium carbonate; heating the milled mixture to a reaction temperature, and holding the reaction temperature until a solid phase synthesis of KVOPO.sub.4 occurs; milling the KVOPO.sub.4 together with conductive particles to form a conductive mixture of fine particles; and adding binder material to form a conductive cathode. A sodium ion battery is provided having a conductive NaVOPO.sub.4 cathode derived by replacement of potassium in KVOPO.sub.4, a sodium ion donor anode, and a sodium ion transport electrolyte. The VOPO.sub.4, preferably has a volume greater than 90 Å.sup.3 per VOPO.sub.4.

A hybrid photoactive heterojunction including a copper vanadate, Cu.sub.2V.sub.2O.sub.7 (CVO) and a zinc vanadate, Zn.sub.2V.sub.2O.sub.6 (ZVO). Particles of the ZVO are dispersed in particles of the CVO to form the hybrid photoactive heterojunction. The hybrid photoactive heterojunction in the form of a photoactive film includes a substrate which is at least partially coated with the hybrid photoactive heterojunction. A method of photodegrading a dye includes contacting the photoactive film and the dye in a solution and exposing the solution to light. A method of photoelectrochemically oxidizing water includes contacting the photoactive film with water in a solution and exposing the solution to light.

An electrode comprising: NaVOPO.sub.4 having orthorhombic crystalline symmetry and space group Pna2.sub.1, as an active intercalation host material, wherein the electrode is capable of electrochemical insertion and release of greater than one sodium ion per vanadium, wherein the NaVOPO.sub.4 is formed by a solid phase synthesis process from a heated powdered mixture of ammonium metavanadate, ammonium phosphate monobasic, and potassium carbonate, to yield KVOPO.sub.4 having corner-sharing VO.sub.6 octahedra and PO.sub.4 tetrahedra, defining two types of tunnels comprising a first type of tunnel formed of rings of two PO.sub.4 tetrahedra and a second type of tunnel formed of rings of three PO.sub.4 tetrahedra and three VO.sub.6 octahedra, followed by substitution of the potassium ions with sodium ions.