The present disclosure relates to the field of new materials, and aims at providing an A-site high-entropy nanometer metal oxide with high conductivity, and a preparation method thereof. The metal oxide has molecular formula of Gd.sub.0.4Er.sub.0.3La.sub.0.4Nd.sub.0.5Y.sub.0.4)(Zr.sub.0.7, Sn.sub.0.8, V.sub.0.5)O.sub.7 and is a powder, and has microstructure of the metal oxide as a square namometer sheet with a side length of 4-12 nm and a thickness of 1-3 nm. Compared with an existing high-entropy oxide, the product in the present disclosure has high conductivity, and can be well applied to a conductive alloy, an electrical contact composite material, a conductive composite material, a multifunctional bio-based composite material, a conductive/antistatic composite coating and the like.

The present disclosure relates to the field of new materials, and aims at providing an A-site high-entropy nanometer metal oxide with high conductivity, and a preparation method thereof. The metal oxide has molecular formula of Gd.sub.0.4Er.sub.0.3La.sub.0.4Nd.sub.0.5Y.sub.0.4)(Zr.sub.0.7, Sn.sub.0.8, V.sub.0.5)O.sub.7 and is a powder, and has microstructure of the metal oxide as a square nanometer sheet with a side length of 4-12 nm and a thickness of 1-3 nm. Compared with an existing high-entropy oxide, the product in the present disclosure has high conductivity, and can be well applied to a conductive alloy, an electrical contact composite material, a conductive composite material, a multifunctional bio-based composite material, a conductive/antistatic composite coating and the like.

A device including an LED light source optically coupled to a green-emitting U.sup.6+-doped phosphor having a composition selected from the group consisting of U.sup.6+-doped phosphate-vanadate phosphors, U.sup.6+-doped halide phosphors, U.sup.6+-doped oxyhalide phosphors, U.sup.6+-doped silicate-germanate phosphors, U.sup.6+-doped alkali earth oxide phosphors, and combinations thereof, is presented. The U.sup.6+-doped phosphate-vanadate phosphors are selected from the group consisting of compositions of formulas (A1)-(A12). The U.sup.6+-doped halide phosphors are selected from the group consisting of compositions for formulas (B1)-(B3). The U.sup.6+-doped oxyhalide phosphors are selected from the group consisting of compositions of formulas (C1)-(C5). The U.sup.6+-doped silicate-germanate phosphors are selected from the group consisting of compositions of formulas (D1)-(D11). The U.sup.6+-doped alkali earth oxide phosphors are selected from the group consisting of formulas (E1)-(E11).

Provided are a method of manufacturing a cathode active material including a first step of preparing a metal glycolate solution, a second step of mixing lithium-containing transition metal oxide particles and the metal glycolate solution and stirring in a paste state, a third step of drying the paste-state mixture, and a fourth step of performing a heat treatment on the dried mixture, a cathode active material including a metal oxide layer which is manufactured by the above method, and a secondary battery composed of a cathode including the cathode active material.

An all-solid-state battery having a positive electrode, a negative electrode having a negative electrode active material layer, and a solid electrolyte layer between the positive electrode and the negative electrode material layer. The negative electrode active material layer contains 60% by volume or more of an oxide having a LISICON-type crystal structure. The solid electrolyte layer contains a solid electrolyte having at least one of an oxide having a garnet-type crystal structure or an oxide having a LISICON-type crystal structure.

A device including an LED light source optically coupled to a green-emitting U.sup.6+-doped phosphor having a composition selected from the group consisting of U.sup.6+-doped phosphate-vanadate phosphors, U.sup.6+-doped halide phosphors, U.sup.6+-doped oxyhalide phosphors, U.sup.6+-doped silicate-germanate phosphors, U.sup.6+-doped alkali earth oxide phosphors, and combinations thereof, is presented. The U.sup.6+-doped phosphate-vanadate phosphors are selected from the group consisting of compositions of formulas (A1)-(A12). The U.sup.6+-doped halide phosphors are selected from the group consisting of compositions for formulas (B1)-(B3). The U.sup.6+-doped oxyhalide phosphors are selected from the group consisting of compositions of formulas (C1)-(C5). The U.sup.6+-doped silicate-germanate phosphors are selected from the group consisting of compositions of formulas (D1)-(D11). The U.sup.6+-doped alkali earth oxide phosphors are selected from the group consisting of formulas (E1)-(E11).

The present disclosure broadly relates to a process for recovering vanadium, iron, titanium and silica values from vanadiferous feedstocks. More specifically, but not exclusively, the present disclosure relates to a metallurgical process in which vanadium, iron, titanium and silica values are recovered from vanadiferous feedstocks such as vanadiferous titanomagnetite, iron ores, vanadium slags and industrial wastes and by-products containing vanadium. The process broadly comprises digesting the vanadiferous feedstocks into sulfuric acid thereby producing a sulfation cake; dissolving the sulfation cake and separating insoluble solids thereby producing a pregnant solution; reducing the pregnant solution thereby producing a reduced pregnant solution; and crystallizing ferrous sulfate hydrates from the reduced pregnant solution, producing an iron depleted reduced solution. The process further comprises removing titanium compounds from the iron depleted reduced solution thereby producing a vanadium-rich pregnant solution; concentrating vanadium and recovering vanadium products and/or a vanadium electrolyte.

Provided is a novel polyoxometalate and a method for producing the polyoxometalate. The polyoxometalate is represented by the compositional formula: M.sub.xO.sub.y in which M is tungsten, molybdenum or vanadium; 4x1000; and 2.5y/x7.

A mixed conductor represented by Formula 1:

A.sub.4+xM.sub.5-yM.sub.yO.sub.12-,Formula 1

wherein, in Formula 1, A is a monovalent cation, M is at least one of a divalent cation, a trivalent cation, or a tetravalent cation, M is at least one of a monovalent cation, a divalent cation, a trivalent cation, a tetravalent cation, a pentavalent cation, or a hexavalent cation, M and M are different from each other, and 0.3x<3, 0.01<y<2, and 01 are satisfied.

Provided is an anode particulate, having a dimension from 10 nm to 100 m, for use in an alkali metal battery, the particulate comprising (i) an anode active material capable of reversibly absorbing and desorbing lithium ions or sodium ions, (ii) an electron-conducting material, and (iii) a lithium ion-conducting or sodium ion-conducting electrolyte, wherein the electron-conducting material forms a three dimensional network of electron-conducting pathways in electronic contact with the anode active material and the electrolyte forms a three dimensional network of lithium ion- or sodium ion-conducting channels in ionic contact with the anode active material. The particulate can be of any shape, but preferably spherical or ellipsoidal in shape. Also provided is a cathode in a particulate form containing a cathode active material, an electron-conducting material forming a three dimensional network of electron-conducting pathways, and a lithium ion-conducting or sodium ion-conducting electrolyte forming a three dimensional network of ion-conducting channels.