A positive-electrode active material contains a compound that has a crystal structure belonging to a space group FM3-M and that is represented by the composition formula (1) and a lithium ion conductor,
Li.sub.xMe.sub.yO.sub.F.sub.(1) wherein Me denotes one or two or more elements selected from the group consisting of Mn, Co, Ni, Fe, Al, B, Ce, Si, Zr, Nb, Pr, Ti, W, Ge, Mo, Sn, Bi, Cu, Mg, Ca, Ba, Sr, Y, Zn, Ga, Er, La, Sm, Yb, V, and Cr, and the following conditions are satisfied.
1.7x2.2
0.8y1.3
12.5
0.52

Provided is a battery including: a positive electrode containing a positive electrode active material; a negative electrode; and an electrolyte solution containing a nonaqueous solvent. The positive electrode active material contains a compound represented by composition formula (1) below and having a crystal structure belonging to space group FM3-M: Li.sub.xMe.sub.yO.sub.F.sub.. (1) Here, Me is one or two or more elements selected from the group consisting of Mn, Co, Ni, Fe, Al, B, Ce, Si, Zr, Nb, Pr, Ti, W, Ge, Mo, Sn, Bi, Cu, Mg, Ca, Ba, Sr, Y, Zn, Ga, Er, La, Sm, Yb, V, and C. x, y, , and satisfy the following conditions: 1.7x2.2, 0.8y1.3, 12.5, and 0.52, respectively. The nonaqueous solvent includes at least one solvent selected from hydrofluoroethers, phosphazenes, phosphates, and perfluoropolyethers.

A method for forming a cathode includes milling a suspension of precursors via a micromedia mill to form a mixture of primary particles in the suspension. The precursors include one or more metal compounds. The method includes spray drying the suspension after the milling to form secondary particles. The secondary particles are agglomerations of the primary particles. The method also includes annealing the secondary particles to form a disordered rocksalt powder.

A raw material of an electrolyte solution that is to be dissolved in a solvent to form an electrolyte solution, and the raw material of an electrolyte solution is a raw material of an electrolyte solution that is a solid or semisolid that contains Ti in an amount of 2 mass % to 83 mass % inclusive, Mn in an amount of 3 mass % to 86 mass % inclusive, and S in an amount of 6 mass % to 91 mass % inclusive.

A positive-electrode active material contains a compound that has a crystal structure belonging to a space group FM3-M and contains is represented by the composition formula (1) and an insulating compound,
Li.sub.xMe.sub.yO.sub.F.sub.(1) wherein Me denotes one or two or more elements selected from the group consisting of Mn, Co, Ni, Fe, Al, B, Ce, Si, Zr, Nb, Pr, Ti, W, Ge, Mo, Sn, Bi, Cu, Mg, Ca, Ba, Sr, Y, Zn, Ga, Er, La, Sm, Yb, V, and Cr, and the following conditions are satisfied.
1.7x2.2
0.8y1.3
12.5
0.52

A battery includes a positive electrode including a positive electrode active material, a negative electrode, and an electrolytic solution including a lithium hexafluorophosphate and an additive. The positive electrode active material includes a compound having a crystal structure belonging to a space group FM3-M and represented by Compositional Formula (1): Li.sub.xMe.sub.yO.sub.F.sub.. The additive is at least one selected from the group consisting of difluorophosphates, tetrafluoroborates, bis(oxalate)borate salts, bis(trifluoromethanesulfonyl)imide salts, and bis(fluorosulfonyl)imide salts.

A positive-electrode active material containing a compound that has a crystal structure belonging to the space group FM-3M and is represented by the composition formula (1):
Li.sub.xMe.sub.yO.sub.F.sub.(1) wherein Me denotes one or two or more elements selected from the group consisting of Mn, Co, Ni, Fe, and Al, and the following conditions are satisfied. 1.3x2.2 0.8y1.3 12.93 0.072

A process for synthesizing a Mn.sup.4+ doped phosphor of formula I by electrolysis is presented. The process includes electrolyzing a reaction solution comprising a source of manganese, a source of M and a source of A. One aspect relates to a phosphor composition produced by the process. A lighting apparatus including the phosphor composition is also provided. A.sub.x[MF.sub.y]:Mn.sup.4+ (I) where, A is Li, Na, K, Rb, Cs, or a combination thereof; M is Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Hf, Y, La, Nb, Ta, Bi, Gd, or a combination thereof; x is the absolute value of the charge of the [MF.sub.y] ion; and y is 5, 6 or 7.

A battery includes a positive electrode containing a positive electrode active material, a negative electrode, and a solid electrolyte. The positive electrode active material contains a compound which has a crystal structure belonging to the space group FM3-M and which is represented by the following formula:
Li.sub.xMe.sub.yO.sub.F.sub.(1)
where Me is one or more selected from the group consisting of Mn, Co, Ni, Fe, Al, B, Ce, Si, Zr, Nb, Pr, Ti, W, Ge, Mo, Sn, Bi, Cu, Mg, Ca, Ba, Sr, Y, Zn, Ga, Er, La, Sm, Yb, V and Cr and the conditions 1.7x2.2, 0.8y1.3, 12.5, and 0.52 are satisfied.

A battery includes a positive electrode including a positive electrode active material, a negative electrode, and an electrolytic solution including an additive. The positive electrode active material includes a compound having a crystal structure belonging to a space group FM3-M and represented by Compositional Formula (1): Li.sub.xMe.sub.yO.sub.F.sub., where, Me is one or more elements selected from the group consisting of Mn, Co, Ni, Fe, Al, B, Ce, Si, Zr, Nb, Pr, Ti, W, Ge, Mo, Sn, Bi, Cu, Mg, Ca, Ba, Sr, Y, Zn, Ga, Er, La, Sm, Yb, V, and Cr; and subscripts x, y, , and satisfy the following requirements: 1.7x2.2, 0.8y1.3, 12.5, and 0.52. The additive is at least one selected from dinitrile compounds and diisocyanate compounds.