Disclosed are a precursor for preparation of a lithium composite transition metal oxide, a method for preparing the same and a lithium composite transition metal oxide obtained from the same. More particularly, the transition metal precursor which has a composition represented by Formula 1 below and is prepared in an aqueous transition metal solution, mixed with a transition metal-containing salt, including an alkaline material, the method for preparing the same and the lithium composite transition metal oxide obtained from the same are disclosed.
Mn.sub.aM.sub.b(OH.sub.1-x).sub.2-yA.sub.y(1) wherein M is at least one selected form the group consisting of Ni, Ti, Co, Al, Cu, Fe, Mg, B, Cr, Zr, Zn and Period II transition metals; A is at least one selected form the group consisting of anions of PO.sub.4, BO.sub.3, CO.sub.3, F and NO.sub.3, and 0.5a1.0; 0b0.5; a+b=1; 0<x<1.0; and 0y0.02.

With an aim to provide a method for producing an oxide particle with controlled color characteristics and also provide an oxide particle with controlled color characteristics, the present invention provides a method for producing an oxide particle, wherein the color characteristics of the oxide particle are controlled by controlling a ratio of an M-OH bond between an element (M) and a hydroxide group (OH) or an M-OH bond/M-O bond ratio, where the element (M) is one element or plural different elements other than oxygen or hydrogen included in the oxide particle selected from metal oxide particles and semi-metal oxide particles. According to the present invention, by controlling the M-OH bond or the M-OH bond/M-O bond ratio of the metal oxide particle or the semi-metal oxide particle, the oxide particle with controlled color characteristics of any of reflectance, transmittance, molar absorption coefficient, hue, and saturation can be provided.

The disclosed embodiments relate to the manufacture of a precursor co-precipitate material for a cathode active material composition. During manufacture of the precursor co-precipitate material, an aqueous solution containing at least one of a manganese sulfate and a cobalt sulfate is formed. Next, a NH.sub.4OH solution is added to the aqueous solution to form a particulate solution comprising irregular secondary particles of the precursor co-precipitate material. A constant pH in the range of 10-12 is also maintained in the particulate solution by adding a basic solution to the particulate solution.

A method for producing a nickel cobalt complex hydroxide includes first crystallization of supplying a solution containing Ni, Co and Mn, a complex ion forming agent and a basic solution separately and simultaneously to one reaction vessel to obtain nickel cobalt complex hydroxide particles, and a second crystallization of, after the first crystallization, further supplying a solution containing nickel, cobalt, and manganese, a solution of a complex ion forming agent, a basic solution, and a solution containing said element M separately and simultaneously to the reaction vessel to crystallize a complex hydroxide particles containing nickel, cobalt, manganese and said element M on the nickel cobalt complex hydroxide particles crystallizing a complex hydroxide particles comprising Ni, Co, Mn and the element Mon the nickel cobalt complex hydroxide particles.

A highly active trimetallic mixed transition metal oxide material has been developed. The material may be sulfided to generate metal sulfides which are used as a catalyst in a conversion process such as hydroprocessing. The hydroprocessing may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking.

The invention relates to a chemical compound of the formula Ni.sub.bM1.sub.cM2.sub.d(O).sub.x(OH).sub.y, wherein M1 denotes at least one element from the group consisting of Fe, Co, Mg, Zn, Cu and/or mixtures thereof, M2 denotes at least one element from the group consisting of Mn, Al, B, Ca, Cr and/or mixtures thereof, wherein b0.8, c0.5, d0.5, and x is a number between 0.1 and 0.8, y is a number between 1.2 and 1.9, and x+y=2. A process for the preparation thereof, and the use thereof as a precursor for the preparation of cathode material for secondary lithium batteries are described.

Precursor compounds of sodium alloy(s), for use as negative electrode active material in a sodium-ion battery, as well as to a negative electrode have the precursor compound of sodium alloy(s), as well as a sodium-ion battery having a negative electrode of this kind.

A positive-electrode active material contains a compound represented by the following composition formula (1):

Li.sub.xMe.sub.yO.sub.X.sub.(1) where Me denotes one or more elements selected from the group consisting of Mn, Ni, Co, Fe, Al, Sn, Cu, Nb, Mo, Bi, Ti, V, Cr, Y, Zr, Zn, Na, K, Ca, Mg, Pt, Au, Ag, Ru, Ta, W, La, Ce, Pr, Sm, Eu, Dy, and Er, X denotes two or more elements selected from the group consisting of F, Cl, Br, I, N, and S, and x, y, , and satisfy 0.75x2.25, 0.75y1.50, 1<3, and 0<2, respectively. A crystal structure of the compound belongs to a space group Fm-3m.

According to one embodiment, a positive electrode active material for a non-aqueous electrolyte secondary battery contains a lithium/transition metal composite oxide that contains 80 mol % or more, relative to the total mol number of metal elements other than Li, of Ni and at least one kind of metal element selected from among Co, Mn, Al, W, Mg, Mo, Nb, Ti, Si and Zr. When a filtrate of a suspension, said suspension being prepared by adding 250 mg of the positive electrode active material to 10 mL of a 17.5 mass % aqueous solution of hydrochloric acid, dissolving by heating at 90? C. for 2 hours and then diluting to 50 mL, is analyzed by inductively coupled plasma mass spectrometry, the elution amount of S in the filtrate is 0.002 mmol or greater.

An inorganic green pigment includes a material with spinel structure of the general formula selected from the following formulas a) (A.sub.1-xB.sub.1+x)(C.sub.3-x-yD.sub.2xB.sub.1-x-2yNi.sub.3y)O.sub.8, wherein 0.05x0.9 and 0.05y0.5, and wherein x+2y1; b) (A.sub.1-xB.sub.1+x)(C.sub.3-x-yD.sub.2x-yB.sub.1-x-yNi.sub.2y)O.sub.8, wherein 0.05x0.5 and 0.05y0.5; c) (A.sub.1-xB.sub.1+x)(C.sub.3-x-4yD.sub.2xB.sub.1-x+yNb.sub.y)O.sub.8, wherein 0.05x0.5 and 0.05y0.2; d) (A.sub.1-xB.sub.1+x)(C.sub.3-xD.sub.2x-2yB.sub.1-x+yNb.sub.y)O.sub.8, wherein 0.05x0.9 and 0.05y0.2, and wherein xy; and e) (A.sub.1-xB.sub.1+x)(C.sub.3-x-3yD.sub.2xB.sub.1-xNb.sub.2yNi.sub.y)O.sub.8, wherein 0.05x0.9 and 0.05y0.2, wherein A is at least one element selected from Co, Zn, Ca, Mg and Cu, wherein B is at least one element selected from Li and Na, wherein C is at least one element selected from Ti, Mn, Sn and Ge, and wherein D is at least one element selected from Cr, B, Fe, Mn and Al.