Provided are a sacrificial positive electrode material with a reduced gas generation amount and a method of preparing the same. The method includes calcinating a raw material mixture of lithium oxide (Li.sub.2O) and cobalt oxide (CoO) to prepare a lithium cobalt metal oxide, wherein the lithium oxide (Li.sub.2O) has an average particle size (D50) of 50 .Math.m or less, and the resulting sacrificial positive electrode material has an electrical conductivity of 1 × 10.sup.-4 S/cm or more. The method of preparing a sacrificial positive electrode material can reduce the generation of gas, particularly, oxygen (O.sub.2) gas, in an electrode assembly during charging of a battery by adjusting the electrical conductivity of the sacrificial positive electrode material within a specific range using lithium oxide that satisfies a specific size, and thus the stability and lifespan of the battery including the same can be effectively enhanced.

The invention discloses a method of fabricating a copper-cobalt (Cu—Co) oxysulfide nanoarchitecture, the method comprising dissolving cobalt nitrate hexahydrate and copper nitrate in de-ionized (DI) water forming a growth solution, mixing disodium thiosulfate and urea to the formed growth solution, immersing a pre-cleaned Ni-foam substrate in the growth solution forming a total solution and transferring the total solution to a sealed glass bottle. The method further comprises heating the sealed glass bottle in an oil bath, thereby forming a flower-like morphology sample of copper-cobalt oxysulfide and cleaning and drying the formed sample of copper-cobalt oxysulfide. Also disclosed is a hybrid supercapacitor (HSC) comprising copper-cobalt (Cu—Co) oxysulfide nanosheets (NFs) on Ni foam as positive electrode; and copper-cobalt (Cu—Co) oxysulfide nanosheets (NFs) on porous carbon as negative electrode.

A hydrothermal synthesis for LiFePO.sub.4 is provided. First, each raw material solution is prepared using a degassed water in advance, second, those solution are mixed by dripping in a fixed order, and then those materials are reacted in a hydrothermal synthesis, so that LiFePO.sub.4 is obtained in a predesigned form.

A battery includes a positive electrode including a positive electrode active material, a negative electrode, and an electrolytic solution including an additive. The positive electrode active material includes a compound having a crystal structure belonging to a space group FM3-M and represented by Compositional Formula (1): Li.sub.xMe.sub.yO.sub.αF.sub.β, where, Me is one or more elements selected from the group consisting of Mn, Co, Ni, Fe, Al, B, Ce, Si, Zr, Nb, Pr, Ti, W, Ge, Mo, Sn, Bi, Cu, Mg, Ca, Ba, Sr, Y, Zn, Ga, Er, La, Sm, Yb, V, and Cr; and subscripts x, y, α, and β satisfy the following requirements: 1.7≤x≤2.2, 0.8≤y≤1.3, 1≤α≤2.5, and 0.5≤β≤2. The additive is at least one selected from dinitrile compounds and diisocyanate compounds.

Provided is a precursor of a positive electrode active material containing, in a reduced amount, impurities which do not contribute to a charge/discharge reaction but rather corrode a firing furnace and peripheral equipment and thus having excellent battery characteristics and safety, and production method thereof.

A method for producing a precursor of a positive electrode active material for nonaqueous electrolyte secondary batteries having a hollow structure or porous structure includes obtaining the precursor by washing nickel-manganese composite hydroxide particles having a particular composition ratio and a pore structure in which pores are present within the particles with an aqueous carbonate solution having a carbonate concentration of 0.1 mol/L or more.

The present invention relates to a method of preparing a buffer material composed of bentonite modified with a layered double hydroxide (LDH) as a buffer material used for deep geological disposal of radioactive waste, the method including a step (a) of producing a first mixture by adding a compound containing a divalent cationic material, aluminum nitrate (Al(NO.sub.3).sub.3), and bismuth nitrate (Bi(NO.sub.3).sub.3) to a reactor.

Improved methods for preparing lithium transition metal oxide particulate such as lithium nickel metal cobalt oxide (“NMC”) for use in lithium batteries and other applications are disclosed. The lithium transition metal oxide particulate is prepared from appropriate transition metal oxide and Li compound precursors mainly using dry, solid state processes including dry impact milling and heating. Further, novel precursor particulates and novel methods for preparing precursor particles for this and other applications are disclosed.

A compound semiconductor which has an improved thermoelectric performance index together with excellent electrical conductivity, and thus may be utilized for various purposes such as a thermoelectric conversion material of thermoelectric conversion devices, solar cells, and the like, and to a method for preparing the same.

Simple, material-efficient microgranulation methods are disclosed for aggregating precursor particles into larger product particles with improved properties and, in some instances, novel structures. The product particles are useful in applications requiring uniform, smooth, spherical, or rounded particles such as for electrode materials in lithium batteries and other applications.

An object of the present invention is to provide a positive electrode active substance for a lithium secondary battery, the positive electrode active substance, when being used as a positive electrode active substance for a lithium secondary battery, being little in deterioration of cycle characteristics and being high in the energy density retention rate, even in repetition of charge and discharge at high voltages, and a lithium secondary battery little in deterioration of cycle characteristics and high in the energy density retention rate, even in repetition of charge and discharge at high voltages. The positive electrode active substance for a lithium secondary battery comprises a lithium cobalt-based composite oxide particle having a Ti-containing compound and an Mg-containing compound adhered on at least part of the particle surface.