A controlled-type recalcitrant high-concentration freeze-separation apparatus, includes: a condenser having therein a condenser stainless antifreeze tube formed in a cell and tube form, and a condenser copper refrigerant tube formed in a cell and tube form inside the stainless antifreeze tube to block direct contact between circulating water flowing into the condenser and the condenser copper refrigerant tube; and an evaporator having therein an evaporator stainless antifreeze tube formed in a form of a cell and tube inside, and an evaporator copper refrigerant tube formed in a cell and tube form inside the evaporator stainless antifreeze tube to block direct contact between circulating water flowing into the evaporator and the evaporator copper refrigerant tube.

A method for purifying an aqueous mixture is provided. The method can include at least partially crystallizing an aqueous mixture derived from a hydrocarbon process to provide a crystallized aqueous mixture. The aqueous mixture can comprise water and one or more contaminants to be separated from the water. The crystallized aqueous mixture can be separated into a contaminant-rich fraction and a water-rich fraction. Water can be recovered from the water-rich fraction and the one or more contaminants can be recovered from the contaminant-rich fraction.

A method for purifying an aqueous mixture is provided. The method can include at least partially crystallizing an aqueous mixture derived from a hydrocarbon process to provide a crystallized aqueous mixture. The aqueous mixture can comprise water and one or more contaminants to be separated from the water. The crystallized aqueous mixture can be separated into a contaminant-rich fraction and a water-rich fraction. Water can be recovered from the water-rich fraction and the one or more contaminants can be recovered from the contaminant-rich fraction.

A precipitation system for precipitating the target component is provided. The precipitation system includes: a reverse osmosis module; a precipitation device; a membrane separation device that includes a semipermeable membrane module including a first chamber and a second chamber separated by a semipermeable membrane, and that makes the feed solution after precipitation of the target component in the precipitation device flow to each of the first chamber and the second chamber and pressurizes the feed solution in the first chamber to transfer water into the second chamber via the semipermeable membrane and thereby concentrate the feed solution in the first chamber and dilute the feed solution in the second chamber; first return means for returning the feed solution concentrated in the membrane separation device to the precipitation device; and second return means for returning the feed solution diluted in the membrane separation device to the reverse osmosis module.

A precipitation system for precipitating the target component is provided. The precipitation system includes: a reverse osmosis module; a precipitation device; a membrane separation device that includes a semipermeable membrane module including a first chamber and a second chamber separated by a semipermeable membrane, and that makes the feed solution after precipitation of the target component in the precipitation device flow to each of the first chamber and the second chamber and pressurizes the feed solution in the first chamber to transfer water into the second chamber via the semipermeable membrane and thereby concentrate the feed solution in the first chamber and dilute the feed solution in the second chamber; first return means for returning the feed solution concentrated in the membrane separation device to the precipitation device; and second return means for returning the feed solution diluted in the membrane separation device to the reverse osmosis module.

An apparatus and method for separating tritiated water (HTO) and/or heavy water (D20) from light water (H2O). A disposable, dense, plastic filter mesh is disposed within a cylinder which is configured to rotate. Chilled heavy water is pumped into the rotating cylinder. Tritiated heavy water, which is preferably frozen, is pressed to the interior wall of the cylinder which is lined with the filter mesh. The heavy water becomes affixed to the mesh, and light water is drained from the cylinder to be reused as coolant. The mesh filter, when needed, is safely disposed in accordance with industry guidelines. The mesh filter is then replaced with a new iteration of the filter.

A water treatment process (10) includes, in a crystallisation stage (12), passing a saline water feed (16) through an elongate conduit kept in a cold environment at a temperature below the equilibrium freezing temperature of the saline water, forming a slurry of brine and ice crystals inside the conduit, and, in a separation stage (14), separating the ice crystals from a bulk of the brine, producing a brine stream (22) and an ice stream (26). The elongate conduit is of a material, or has an inner material layer in contact with the saline water and with the slurry of brine and ice crystals, with a thermal conductivity of less than 5 W/m.Math.K and has a length configured to ensure formation of the slurry of brine and ice crystals in the conduit at the flow rate of the saline water feed through the elongate conduit.

A water treatment process (10) includes, in a crystallisation stage (12), passing a saline water feed (16) through an elongate conduit kept in a cold environment at a temperature below the equilibrium freezing temperature of the saline water, forming a slurry of brine and ice crystals inside the conduit, and, in a separation stage (14), separating the ice crystals from a bulk of the brine, producing a brine stream (22) and an ice stream (26). The elongate conduit is of a material, or has an inner material layer in contact with the saline water and with the slurry of brine and ice crystals, with a thermal conductivity of less than 5 W/m.Math.K and has a length configured to ensure formation of the slurry of brine and ice crystals in the conduit at the flow rate of the saline water feed through the elongate conduit.

The present invention relates to treatment systems for polluted and sea water by recrystallization and may be used in everyday life, the food industry, in the catering business and healthcare.

The system comprises at least two heat-exchange devices that contain chambers for water freezing and ice melting, cooling and heating components, a water circulation loop, a refrigerant circulation loop connected with cooling and heating components able to alternate water freezing and ice melting in the chambers of heat-exchange devices and to transfer the heat generated in the water freezing chamber into the ice melting chamber, a control and monitoring tool. Heat-exchange devices are arranged as a cascade one under another and comprise outer and inner housings as well as a cylindrical baffle, which are coaxial relatively to each other and form an annular cavity between their walls; an air supply manifold, cooling and heating components, a heating component fastened at the top of the inner housing and at least one drain nozzle. The outer housing is cylindrical or truncated cone-shaped with a cone angle directed upwards. The outer housing has an additional inner wall, the shape and height of which meet the outer housing while cooling and heating components are located between the said walls. The baffle and the housing internal wall may be connected to an electrical current source.

The combination of sufficiently large performance and high quality of water treatment in the system allows it to use for treating initial water with a wide range of with organic and inorganic contaminants.

The present invention relates to treatment systems for polluted and sea water by recrystallization and may be used in everyday life, the food industry, in the catering business and healthcare.

The system comprises at least two heat-exchange devices that contain chambers for water freezing and ice melting, cooling and heating components, a water circulation loop, a refrigerant circulation loop connected with cooling and heating components able to alternate water freezing and ice melting in the chambers of heat-exchange devices and to transfer the heat generated in the water freezing chamber into the ice melting chamber, a control and monitoring tool. Heat-exchange devices are arranged as a cascade one under another and comprise outer and inner housings as well as a cylindrical baffle, which are coaxial relatively to each other and form an annular cavity between their walls; an air supply manifold, cooling and heating components, a heating component fastened at the top of the inner housing and at least one drain nozzle. The outer housing is cylindrical or truncated cone-shaped with a cone angle directed upwards. The outer housing has an additional inner wall, the shape and height of which meet the outer housing while cooling and heating components are located between the said walls. The baffle and the housing internal wall may be connected to an electrical current source.

The combination of sufficiently large performance and high quality of water treatment in the system allows it to use for treating initial water with a wide range of with organic and inorganic contaminants.