C02F1/42

Process for a mild aqueous synthesis of titanium phosphates—ion—exchangers having solely—H2PO4 active groups

The invention relates to a process for performing a aqueous synthesis of titanium phosphates (TiP) having solely —H2PO4 groups, which process is characterised by the following steps: providing titanium (IV) oxysulphate, TiOSO4, in an aqueous solution or in a powder and H2SO4, substantially without transition divalent metal ions, including cobalt (II) and copper (II), heating of the thus formed aqueous solution to above 50° C., but below 85° C. for at least 30 minutes, providing a controlled amount of H3PO4 to said aqueous solution, to form an aqueous solution containing a molar ratio between TIO2 and P2Os being controlled to about 1:1, not above 1:1.5 and not below 1:0.7, stirring the thus formed aqueous solution for at least 3 hours to form precipitates of titanium phosphate, and allowing ageing of said solution, without stirring, acidic washing of the formed precipitate using HCI or other acids to obtain TiO(OH)(H2PO4)-H2O having solely —H2PO4 ion-exchange chemical groups and allowing said precipitates to dry to a powder product, substituting protons in the powder product TiO(OH)(H2PO4)-H2O to sodium cations by treatment of the latter with solutions of sodium carbonate and allowing the thus formed powder of Na—TiP1 to dry.

Process for a mild aqueous synthesis of titanium phosphates—ion—exchangers having solely—H2PO4 active groups

The invention relates to a process for performing a aqueous synthesis of titanium phosphates (TiP) having solely —H2PO4 groups, which process is characterised by the following steps: providing titanium (IV) oxysulphate, TiOSO4, in an aqueous solution or in a powder and H2SO4, substantially without transition divalent metal ions, including cobalt (II) and copper (II), heating of the thus formed aqueous solution to above 50° C., but below 85° C. for at least 30 minutes, providing a controlled amount of H3PO4 to said aqueous solution, to form an aqueous solution containing a molar ratio between TIO2 and P2Os being controlled to about 1:1, not above 1:1.5 and not below 1:0.7, stirring the thus formed aqueous solution for at least 3 hours to form precipitates of titanium phosphate, and allowing ageing of said solution, without stirring, acidic washing of the formed precipitate using HCI or other acids to obtain TiO(OH)(H2PO4)-H2O having solely —H2PO4 ion-exchange chemical groups and allowing said precipitates to dry to a powder product, substituting protons in the powder product TiO(OH)(H2PO4)-H2O to sodium cations by treatment of the latter with solutions of sodium carbonate and allowing the thus formed powder of Na—TiP1 to dry.

FLUOROCARBON DESTRUCTION SYSTEM AND METHOD
20230024923 · 2023-01-26 ·

A method of destroying a fluorocarbon compound includes regenerating an adsorbent to remove the fluorocarbon compound and to produce a regeneration fluid having a concentration of the fluorocarbon compound and directing the regeneration fluid to an electro-oxidation system. The method also includes applying a current to the electro-oxidation system to oxidize the fluorocarbon compound within the regeneration fluid and measuring a quantity of fluorides in the regeneration fluid to determine the progress of the removal of the fluorocarbon compound from the regeneration fluid.

FLUOROCARBON DESTRUCTION SYSTEM AND METHOD
20230024923 · 2023-01-26 ·

A method of destroying a fluorocarbon compound includes regenerating an adsorbent to remove the fluorocarbon compound and to produce a regeneration fluid having a concentration of the fluorocarbon compound and directing the regeneration fluid to an electro-oxidation system. The method also includes applying a current to the electro-oxidation system to oxidize the fluorocarbon compound within the regeneration fluid and measuring a quantity of fluorides in the regeneration fluid to determine the progress of the removal of the fluorocarbon compound from the regeneration fluid.

APPARATUSES, SYSTEMS, AND METHOD FOR FILTRATION
20230028182 · 2023-01-26 ·

Methods, systems, and apparatuses for recovering water from an aqueous stream containing a solute are disclosed herein. In accordance with an aspect, provided is method comprising receiving an inlet brine stream comprising water and a solute; producing a concentrated brine stream by contacting the inlet brine stream with an ion exchange resin configured to extract water from the inlet brine stream, the ion exchange resin comprising a plurality of pores adapted to receive water molecules; ceasing the contact of the ion exchange resin with the inlet brine stream and the concentrated brine stream; and evaporating at least a portion of the water contained in the ion exchange resin aided by unsaturated air with less than 100% relative humidity using an evaporation unit.

APPARATUSES, SYSTEMS, AND METHOD FOR FILTRATION
20230028182 · 2023-01-26 ·

Methods, systems, and apparatuses for recovering water from an aqueous stream containing a solute are disclosed herein. In accordance with an aspect, provided is method comprising receiving an inlet brine stream comprising water and a solute; producing a concentrated brine stream by contacting the inlet brine stream with an ion exchange resin configured to extract water from the inlet brine stream, the ion exchange resin comprising a plurality of pores adapted to receive water molecules; ceasing the contact of the ion exchange resin with the inlet brine stream and the concentrated brine stream; and evaporating at least a portion of the water contained in the ion exchange resin aided by unsaturated air with less than 100% relative humidity using an evaporation unit.

CONTAMINANT-SEQUESTERING COATINGS AND METHODS OF USING THE SAME

Contaminant-sequestering coatings include a network of hydrolyzed silane compounds including (i) a plurality of fluorinated functionalities, and (ii) a plurality of thiol functional groups are provided. The network of hydrolyzed silane compounds includes a fluorinated silane including (a) a hydrophilic polar head region. The polar head region includes one or multiple units of ethylene glycol (EG) functionality, (b) a fluorine-containing region, and (c) an anchor region including a silicon atom. The contaminant-sequestering coatings may sequester one or more per- and polyfluoroalkyl substances (PFAS), heavy metals, biological species, or any combination thereof.

HYBRID THERMAL - CHROMATOGRAPHIC SYSTEM FOR SIMULTANEOUS MINERAL PURIFICATION AND DESALINATION OF SALINE WATERS

Embodiments of the hybrid thermal-chromatograph systems described herein solve the co-product generation problem associated with seawater desalination, and result in significant reduction in the selling price of fresh water generated through the process, while also solving problems associated with traditional lithium mining practices.

HYBRID THERMAL - CHROMATOGRAPHIC SYSTEM FOR SIMULTANEOUS MINERAL PURIFICATION AND DESALINATION OF SALINE WATERS

Embodiments of the hybrid thermal-chromatograph systems described herein solve the co-product generation problem associated with seawater desalination, and result in significant reduction in the selling price of fresh water generated through the process, while also solving problems associated with traditional lithium mining practices.

WATER PURIFIER FILTER AND WATER PURIFIER COMPRISING SAME
20230227328 · 2023-07-20 ·

A filter for a liquid purifier, comprising: a filter housing having an inlet to receive water and an outlet to discharge the water; and a filter module provided in the filter housing, and configured to purify water introduced through the inlet, and to provide the purified water to the outlet, wherein the filter module includes a carbon block having a hollow tube shape by mixing activated carbon, a binder, ferric hydroxide, and titanium oxide, and the binder is mixed at a ratio of 13% to 23% by weight.