C02F2103/06

SILVER COORDINATION POLYMERS FOR MEASURING ARSENIC LEVELS IN WATER

Measurement devices can be used for identifying concentration of arsenic species in water samples. The measurement devices can take the form of test strips including a substrate with at least one testing region that includes an amount of a testing medium. The silver reagent includes a polymer framework and a silver component that is stabilized by the framework, yet remains reactive enough to function as a colorimetric sensor for arsenic, e.g., ((Ag(H.sub.2btc))(Ag.sub.2(Hbtc))).sub.n. The initially substantially colorless testing medium exhibits a color change response when exposed to arsenic species, e.g., arsine, generated from samples including as little as 5 ppb arsenic, with an increasingly dark color as the concentration of arsenic is increased. Test strips fabricated with the silver coordination polymer display robust stability towards both light and water, allowing for an alternative to mercury-based field test kits in real-world field tests under direct sunlight and high humidity conditions.

Pelletized Compositions for Liquid Solidification and Moisture Retention and Methods of Making and Using the Same
20230211315 · 2023-07-06 ·

A method of using a pelletized composition for liquid solidification and moisture retention includes the steps of: Providing a pelletized absorption material having i) at least 60% by weight agricultural fibers; and ii) 0.1-20% by weight superabsorbent polymer, wherein the pellets are substantially uniform and have a density of less than 40 LBS/Cubic Foot; and Blending the pelletized absorption material with one of i) Sludge, ii) Landfill leachate; iii) material used in hydroseeding; iv) grass seeds, fertilizer, and/or mulch to form a soil amendment; v) settling pond; and vi) wastewater streams.

Composition with a time release material for removing halogenated hydrocarbons from contaminated environments
11548802 · 2023-01-10 · ·

A composition for remediation of soil and groundwater containing halogenated compounds. The remediation composition includes an elemental iron-based composition, which may include activated carbon capable of absorbing the halogenated compounds with numerous pores impregnated with elemental iron. The remediation composition further includes a first bioremediation material including a blend of one-to-many organisms capable of degrading the halogenated compounds. The remediation composition includes an organic compound or polymeric substance and a second bioremediation material including a blend of one-to-many organisms capable of degrading the organic compound or polymeric substance over time (e.g., 20 to 365 or more days to provide a time release substrate-creating material or platform) into smaller molecules or compounds used by the organisms in the first bioremediation material while degrading the halogenated compounds. The organic compound may be a complex carbohydrate such as food grade starch, chitin, or other complex carbohydrate such as one with low water solubility.

SYSTEMS FOR CATALYTICALLY REMOVING PER- AND POLYFLUOROALKYL SUBSTANCES FROM A FLUID AND RELATED METHODS
20230002263 · 2023-01-05 ·

The present invention relates to systems and methods for catalytic removal of per- and polyfluoroalkyl substances (PFAS) from water and wastewater. The system and methods utilize a catalyst film and a biofilm to synergystically remove PFAS from water. In some aspects, the catalyst film reduces and defluorinates PFAS into less fluorinated counterparts of PFAS, and the biofilm metabolizes the less fluroinated counterparts of PFAS into CO.sub.2 or shorter chain PFAS.

Medium material for removing phenol contamination from groundwater, method of producing the same, and use of the same

A medium material for removing phenol contamination from groundwater, a method of producing the same, and use of the same id disclosed. In at least some embodiments, the medium material is a granular material which has an average particle diameter of 0.5-1.5 cm and is formed from a bacteria-entrapping solution, a manganese sand filter material, modified bentonite, and biochar at a mass ratio of 1:0.2-0.4:0.2-0.4:0.1-0.2 by a series of processes including strain culturing, catalysis, mixing, solidification, and the like. The medium material can remove phenol from groundwater, is a safe and environment-friendly material, has a long service life, and/or achieves waste treatment with waste.

Systems and methods for electrochemically enhanced water filtration
11535533 · 2022-12-27 · ·

A system for electrochemically enhanced water filtration is provided. The system includes: a chamber plug-flow electrochemical cell; a first cathode and anode pair disposed in the cell; and a second cathode and anode pair disposed in the cell. The first and the second pair are collectively operative to apply a 2D electric field in at least one of a horizontal direction and a vertical direction with respect to the chamber plug-flow electrochemical cell.

Anaerobic and aerobic treatment system and process for landfill wastewater
11535545 · 2022-12-27 · ·

There is disclosed a system and process for the anaerobic and aerobic treatment of landfill wastewater, including landfill condensate, landfill leachate and mixtures thereof.

PFAS TREATMENT SCHEME USING SEPARATION AND ELECTROCHEMICAL ELIMINATION

A system for treating a source of water contaminated with PFAS is disclosed. The system includes a PFAS separation stage having an inlet fluidly connectable to the source of water contaminated with PFAS, a diluate outlet, and a concentrate outlet and a PFAS elimination stage positioned downstream of the PFAS separation stage and having an inlet fluidly connected to an outlet of the PFAS separation stage, the elimination of the PFAS occurring onsite with respect to the source of water contaminated with PFAS, with the system maintaining an elimination rate of PFAS greater than about 99%. A method of treating water contaminated with PFAS is also disclosed. The method includes introducing contaminated water from a source of water contaminated with a first concentration of PFAS to an inlet of a

PFAS separation stage, treating the contaminated water in the PFAS separation stage to produce a product water substantially free of PFAS and a PFAS concentrate having a second PFAS concentration greater than the first PFAS concentration, introducing the PFAS concentrate to an inlet of a PFAS elimination stage; and activating the PFAS elimination stage to eliminate the PFAS in the PFAS concentrate. A method of retrofitting a water treatment system as described herein is also disclosed. The method includes providing a PFAS elimination module as described herein and fluidly connecting the PFAS elimination module downstream of a PFAS separation stage.

SYSTEMS AND PROCESSES FOR DECONTAMINATING AN AQUEOUS FLOW CONTAMINATED WITH MUNITIONS CONTAMINANTS
20220402778 · 2022-12-22 ·

Systems and processes for treating a contaminated aqueous flow which includes contaminants, such as munitions contaminants including metallic contaminants, energetic material contaminants, and/or propellant contaminants, are disclosed. The systems include an adsorption layer which includes bone char particulates, titanium dioxide particulates and/or aluminum oxide particulates which promotes adsorption of the contaminants upon contact of the contaminated stream and the adsorption layer so as to produce a treated aqueous flow, which is depleted in the munitions contaminants. Optionally, the adsorption layer can be buried in granulates particles so the contaminated aqueous water can percolate down through the earth and towards the adsorption layer, so the treated water can further percolate through the earth. The system can alternatively include more than one adsorption layer, which can be arranged in series or in parallel, in situ or ex situ.

NANO-REACTOR SYSTEM FOR DECOMPOSITION OF PER- AND POLYFLUOROALKYL SUBSTANCES

A reactor system for decomposing at least one of a per- or polyfluoroalkyl substance (PFAS) is provided. The system includes a material having an interior surface that defines a compartment; a subaqueous liquid in the compartment; and an electron donor in the subaqueous liquid, the electron donor configured to release a hydrated electron upon ultraviolet (UV) irradiation. The reactor system is configured so that when the electron donor releases a hydrated electron into the subaqueous liquid, the hydrated electron has a longer lifespan relative to an electron released in normal bulk phase water, and when a PFAS is present within the subaqueous liquid, the hydrated electron is capable of reductively defluorinating the PFAS and to generate fluoride ions (F). A method of operating the system to decompose PFAS is also provided.