Disclosed herein are the methods of using di-cationic or di-anionic compounds, which are derived from primary amine through an aza-Michael addition with an activated olefin, in a corrosion control composition to mitigate corrosion of a surface in a water system. The disclosed methods or compositions are found to be more effective than those methods or compositions including commonly used single quaternary compounds for mitigating corrosion for a metal surface in water systems.

In some embodiments, a method may include treating pulp in pulp and paper mills. The methods may include providing a peracetate oxidant solution and generating a reactive oxygen species. The peracetate solution may include peracetate anions and a peracid. In some embodiments, the peracetate solution may include a pH from about pH 10 to about pH 12. In some embodiments, the peracetate solution has a molar ratio of peracetate anions to peracid ranging from about 60:1 to about 6000:1. In some embodiments, the peracetate solution has a molar ratio of peracetate to hydrogen peroxide of greater than about 16:1. The peracetate oxidant solution may provide enhanced treatment methods of bleaching, brightening, and delignifying pulp fibers involving the use of peracetate oxidant solutions.

A method for electrolysis-ozone-corrosion inhibitor/electrolysis-ozone-hydrogen peroxide-corrosion inhibitor coupling treatment on toxic and refractory wastewater includes the following steps: adding toxic and refractory wastewater to be treated into a wastewater treatment reaction tank equipped with a plate anode and a plate cathode, and starting a direct current (DC) power supply connected to the plate anode and the plate cathode to treat the toxic and refractory wastewater at an appropriate current density under stirring, during which a corrosion inhibitor and hydrogen peroxide are added to the toxic and refractory wastewater to be treated and ozone is introduced into the toxic and refractory wastewater to be treated through an aeration device. The method can increase the production rate and production quantity of free radicals in a reaction system, effectively improve the treatment efficiency for toxic and refractory wastewater, and reduce the treatment cost.

Certain examples of the present disclosure relate to apparatuses and methods for treating a fluid, such as water, when initially introduced into an empty fluid circuit (such as a heating and/or cooling system) via a temporary fluid connection 602 from a fluid supply connector 601; and also for treating existing fluid in a fluid circuit of a heating and/or cooling system. Certain examples provide an apparatus 101 comprising a vessel 102 having an open upper end 103 and a removable lid 108. The vessel includes: a circulating fluid inlet port 104 in a side wall 105 thereof, a circulating fluid outlet port 106 in a lower end 107 thereof, and a combined drain and water inlet port 600 in the lower end 107 thereof.

The present disclosure relates to corrosion inhibitor compositions, formulations, and compounds. The compositions, formulations, and compounds may be used is various methods to inhibit corrosion of metallic surfaces in aqueous environments. The corrosion inhibitor compositions may include one of the following compounds or any combination of any of the compounds of formula (I): ##STR00001##

A process performed by a plant for oxidation of a waste stream with oxidizable material is described. In a start-up phase, supercritical water is fed to a supercritical water oxidation reactor, heating the process up to supercritical conditions. In a treatment phase, the waste stream is fed to the reactor for supercritical water oxidation treatment, in which sufficient mass of water under supercritical conditions is present in the reactor to retain supercritical conditions with the newly introduced waste stream. Oxygen is used as oxidant and a stoichiometric quantum is added to the reactor. The energy released from the oxidation reaction substitutes the energy provided by the addition of supercritical water up to a point where the reactor achieves near autothermal conditions with supercritical water providing trim heat requirement. The reactor outlet is quench cooled, neutralised and energy is recovered from it. A gas liquid separator ensures that the effluent stream is degassed.

Disclosed are oleyl propylenediamine-based compounds used in compositions and methods for inhibiting corrosion. The method comprises introducing into a fluid source a composition comprising one or more oleyl propylenediamine-based compounds comprising Formula I:

##STR00001##

wherein Y.sub.1, Y.sub.2, and Y.sub.3 independently are hydrogen or a substituent of Formula (II):

##STR00002##

wherein V is —O— or —NH—, W is optionally present and is a linear or branched C.sub.1-10 aliphatic group, X is —H, —NZ.sub.3.sup.+, —COOH, —SO.sub.3H, —OSO.sub.3H.sub.2, —PO.sub.3H, —OPO.sub.3H.sub.2, or a salt thereof, each Z independently is hydrogen or a linear or branched C.sub.1-20 aliphatic group optionally interrupted or substituted with one or more oxygen atoms, and R is hydrogen or methyl, provided that at least one of Y.sub.1, Y.sub.2, or Y.sub.3 is a substituent of Formula (II).

Random terpolymers are characterized for being tolerant to high concentrations of divalent ions, such as calcium, magnesium, strontium and barium, and that for their application in the reservoir or production rig, treated water, sea water and/or connate water can be used as means of transportation. Furthermore, the terpolymer also can be used to inhibit and disperse mineral scales presents in cooling system and boiler employed in the chemical and oil industry.

Also, random terpolymers of the present invention have the characteristic of complying with environmental standards established internationally and are classified as particularly non-toxic, so it can be used in pipes and equipment of the petrochemical industry and with the use characteristic freshwater and seawater from offshore and onshore facilities.

In some embodiments, a method may include reducing the microbial load in contaminated water of water recycle loops. These water recycling loops may include pulp and paper mills, cooling towers and water loops, evaporation ponds, feedstock processing systems and/or non-potable water systems. The methods may include providing a peracetate oxidant solution. The peracetate solution may include peracetate anions and a peracid. In some embodiments, the peracetate solution may include a pH from about pH 10 to about pH 12. In some embodiments, the peracetate solution has a molar ratio of peracetate anions to peracid ranging from about 60:1 to about 6000:1. In some embodiments, the peracetate solution has a molar ratio of peracetate to hydrogen peroxide of greater than about 16:1. The peracetate solution may provide bleaching, sanitizing and/or disinfection of contaminated water and surfaces. The peracetate oxidant solution may provide enhanced separation of microbes from contaminated water.

Materials which react with (“scavenge”) sulfur compounds, such as hydrogen sulfide and mercaptans, are useful for limiting sulfur-induced corrosion. Surface-modified particles incorporating a hexahydrotriazine moiety are disclosed and used as sulfur scavengers. These surface-modified particles are used a filter media in fixed filter systems and as additives to fluids including sulfur compounds. The hexahydrotriazine moiety can react with sulfur compounds in such a manner as to bind sulfur atoms to the surface-modified particles, thus allowing removal of the sulfur atoms from fluids such as crude oil, natural gas, hydrocarbon combustion exhaust gases, sulfur polluted air and water. The surface-modified particles may, in general, be sized to allow separation of the particles from the process fluid by sedimentation, size-exclusion filtration or the like.