Polyphosphate glass microspheres (PGMs) are prepared using a polyphosphate coacervate. PGMs can be loaded with various therapeutic agents and can be used for various medical and dental procedures and treatments.

A continuous sol-gel process for producing silicate-containing glasses and glass ceramics is proposed, comprising the following steps: (a) continuously feeding a silicon tetraalkoxide, a silicon alkoxide with at least one non-alcoholic functional group and an alcohol into a first reactor (R1), and at least partially hydrolyzing by the addition of a mineral acid to obtain a first product stream (A); (b) continuously providing a second product stream (B) in a second reactor (R2) by feeding a metal alkoxide component or continuously mixing an alcohol and a metal alkoxide component; (c) continuously mixing product streams (A) and (B) in a third reactor (R3) for producing a presol to obtain a third product stream (C); (d) continuously adding water or a diluted acid to the product stream (C) to obtain a sol (gelation); (e) continuously filling the emerging sol into molds to obtain an aquagel; (f) drying the aquagels to obtain xerogels; (g) sintering the xerogels to obtain silicate-containing glasses and glass ceramics.

A glass precursor gel and a method of making a glass product from the glass precursor gel are disclosed. The glass precursor gel includes a bulk amorphous oxide-based matrix that is homogeneously chemically mixed and includes 30 mol % to 90 wt. % silica and at least one of the following: (A) 0.1 mol % to 25 mol % of one or more alkali oxides in sum total, (B) 0.1 mol % to 25 mol % of one or more alkaline earth oxides in sum total, (C) 1 mol % to 20 mol % boric oxide, (D) 5 mol % to 80 mol % lead oxide, or (E) 0.1 mol % to 10 mol % aluminum oxide. A method of making a glass product from the glass precursor gel involves obtaining the glass precursor gel, melting the glass precursor gel into molten glass, and forming the molten glass into a glass product.

The disclosure provides a water-solvated glass/amorphous solid that is an ionic conductor-an electronic insulator, and a dielectric as well as electrochemical devices and processes that use this material, such as batteries, including rechargeable batteries, fuel cells, capacitors, electrolysis cells, and electronic devices. The electrochemical devices and products use a combination of ionic and electronic conduction as well as internal electric dipoles.

The present invention provides additive manufacturing compositions, also referred as inks in the field of additive manufacturing, which can be fine-tuned with respect to porosity by varying the intensity of the photopolymerisation light source and which can further be used to obtain objects out of glasses, ceramics or glass-ceramics and their respective alloys.

A method for producing a sulfide glass ceramic, including reacting a lithium compound, a phosphorus compound and a halogen compound in a solvent that contains a hydrocarbon and an ether compound to produce a sulfide glass that contains a Li element, a P element, a S element and one or more halogen elements, and heating the sulfide glass to produce a sulfide glass ceramic.

An electronic component includes a base body including a plurality of voids, a protective material covering a part or a whole of an outer surface of the base body, and an external electrode covering a part of an outer surface of the protective material. The protective material is glass containing a silane compound having a carbon chain with 3 or more carbon atoms. The protective material includes a filling portion occupying at least some of the voids, and a film portion covering the outer surface of the base body.

A method for fabricating glass structures on a substrate includes a step of contacting the substrate with a liquid reactive composition that includes a silsesquioxane, an acrylic oligomer or monomer, and a photoinitiator. The silsesquioxane and the acrylic oligomer or monomer are each independently functionalized with at least two acrylate groups. Light is directed to the substrate such that the reactive composition forms polymeric coating on the substrate. The polymeric coating is heat treated in an oxygen-containing gas environment at a sufficiently high temperature to convert the partially cured coating to a glass, the sufficiently high temperature being lower than the melting point of the substrate.

The disclosure provides a method of producing a mesoporous phosphate-based glass. The method comprises (a) contacting a phosphate with an alcohol and/or a glycol ether to create a reaction mixture; (b) contacting the reaction mixture with alkali metal cations and/or alkaline earth metal cations; (c) contacting the alcohol, the glycol ether or the reaction mixture with a surfactant, wherein the surfactant is configured to provide channel-like pores in the resultant mesoporous phosphate-based glass; (d) allowing the reaction mixture to gel; and (e) calcinating the gel to obtain the mesoporous phosphate-based glass.