Disclosed herein are methods for forming low melting point glass fibers comprising providing a glass feedstock comprising a low melting point glass and melt-spinning the glass feedstock to produce glass fibers, wherein the glass transition temperature of the glass fibers is less than or equal to about 120% of the glass transition temperature of the glass feedstock. The disclosure also relates to method for forming low melting point glass frit further comprising jet-milling the glass fibers. Low melting point glass frit and fibers produced by the methods described above are also disclosed herein.

Disclosed herein are methods for forming low melting point glass fibers comprising providing a glass feedstock comprising a low melting point glass and melt-spinning the glass feedstock to produce glass fibers, wherein the glass transition temperature of the glass fibers is less than or equal to about 120% of the glass transition temperature of the glass feedstock. The disclosure also relates to method for forming low melting point glass frit further comprising jet-milling the glass fibers. Low melting point glass frit and fibers produced by the methods described above are also disclosed herein.

The present invention relates to compositions in the form of precursor glass powders, pastes and preforms comprising said precursor glass powders and glass-ceramics produced from the precursor glass powders, pastes or preforms. The present invention also relates to a method of forming a seal between a first and second material with a glass-ceramic, and a joint comprising a first material, a second material and a glass-ceramic sealing material joining the first and second materials together.

A glass ceramic seal is formed from a precursor material that includes from 80 mol % to 100 mol % of a primary component containing, on an oxide basis, from 25 mol % to 55 mol % SiO.sub.2, from 20 mol % to 45 mol % CaO, from 5 mol % to 30 mol % MgO, and from 0 mol % to 15 mol % Al.sub.2O.sub.3.

A glass ceramic seal is formed from a precursor material that includes from 80 mol % to 100 mol % of a primary component containing, on an oxide basis, from 25 mol % to 55 mol % SiO.sub.2, from 20 mol % to 45 mol % CaO, from 5 mol % to 30 mol % MgO, and from 0 mol % to 15 mol % Al.sub.2O.sub.3.

A glass ceramic seal contains by weight, on an oxide basis 40-60% of SiO.sub.2, 25-28% of BaO, 10-20% of B.sub.2O.sub.3, 8-12% of Al.sub.2O.sub.3, 0-2% of ZrO.sub.2, 0-1% of Y.sub.2O.sub.3, 0-1% of CaO, and 0-1% of MgO.

A glass ceramic seal contains by weight, on an oxide basis 40-60% of SiO.sub.2, 25-28% of BaO, 10-20% of B.sub.2O.sub.3, 8-12% of Al.sub.2O.sub.3, 0-2% of ZrO.sub.2, 0-1% of Y.sub.2O.sub.3, 0-1% of CaO, and 0-1% of MgO.

There is provided a gas trapping material and vacuum heat insulation equipment where the gas trapping material can be activated in a sealing step of the vacuum heat insulation equipment, and production efficiency can be enhanced by maintaining a high gas trapping characteristic even when a gas is released in a baking step or in a sealing step under an air atmosphere. The gas trapping material contains porous metal oxide and silver particles having an average particle size of 0.5 nm to 100 nm inclusive.

What is disclosed is a lead-free glass, which is a V.sub.2O.sub.5—TeO.sub.2—RO (at least one selected from the group consisting of MgO, CaO, SrO, and BaO)—ZnO glass and has a low softening point, comprising: 5-55 wt % of V.sub.2O.sub.5, 5-75 wt % of TeO.sub.2, 1-25 wt % of RO (at least one selected from the group consisting of MgO, CaO, SrO, and BaO) in total, 0.1-6 wt % of ZnO, and 0.1-3 wt % of R.sub.2O (at least one selected from the group consisting of Li.sub.2O, Na.sub.2O, and K.sub.2O) in total. This glass can be used as a sealing material providing fluidity which is capable of being sealed at a temperature of 400° C. or less

What is disclosed is a lead-free glass, which is a V.sub.2O.sub.5—TeO.sub.2—RO (at least one selected from the group consisting of MgO, CaO, SrO, and BaO)—ZnO glass and has a low softening point, comprising: 5-55 wt % of V.sub.2O.sub.5, 5-75 wt % of TeO.sub.2, 1-25 wt % of RO (at least one selected from the group consisting of MgO, CaO, SrO, and BaO) in total, 0.1-6 wt % of ZnO, and 0.1-3 wt % of R.sub.2O (at least one selected from the group consisting of Li.sub.2O, Na.sub.2O, and K.sub.2O) in total. This glass can be used as a sealing material providing fluidity which is capable of being sealed at a temperature of 400° C. or less