In an aspect, provided herein are methods for producing sulfuric acid and hydrogen gas, the methods comprising steps of: providing sulfur dioxide formed by thermal conversion of a sulfur-containing species; electrochemically oxidizing said sulfur dioxide to sulfuric acid in the presence of water; and electrochemically forming hydrogen gas via a reduction reaction. In some embodiments, the methods comprise a step of thermally converting said sulfur-containing species to said sulfur dioxide. Systems configured to perform these methods are also disclosed herein. Also provided herein are methods and systems for producing sulfuric acid and hydrogen gas by electrochemically forming the sulfuric acid and the hydrogen gas in a mixture comprising a sulfur material, a supporting acid, and water. Also provided herein are methods and systems for producing a cement material.

The present invention is directed to a gypsum panel and a method of making such gypsum panel. For instance, in one embodiment, the gypsum panel comprises a gypsum core and a first facing material and a second facing material sandwiching the gypsum core, wherein the gypsum core includes gypsum and one or more carbon sequestration additives. The methods of the present invention are directed to making the aforementioned gypsum panels by providing the first facing material, providing a gypsum slurry comprising gypsum, water, and one or more carbon sequestration additives onto the first facing material, and providing a second facing material on the gypsum slurry.

The present invention is directed to a gypsum panel and a method of making such gypsum panel. For instance, in one embodiment, the gypsum panel comprises a gypsum core and a first facing material and a second facing material sandwiching the gypsum core, wherein the gypsum core includes gypsum and one or more carbon sequestration additives. The methods of the present invention are directed to making the aforementioned gypsum panels by providing the first facing material, providing a gypsum slurry comprising gypsum, water, and one or more carbon sequestration additives onto the first facing material, and providing a second facing material on the gypsum slurry.

A method for preparing calcium sulphate comprising a production of DCP by the attack of a source of phosphate by an acid, a digestion of the isolated DCP by the sulphuric acid under conditions giving rise to the formation of a first slurry of gypsum suspended in an acidic aqueous phase having a content of free SO.sub.3 equal to or less than 1.5% and a content of free P.sub.2O.sub.5, a conversion of at least part of said first slurry by heating to a temperature greater than 80 C. and potentially by adding sulphuric acid, with solubilisation of the gypsum crystals and recrystallisation of the solubilised calcium sulphate in a second slurry of -calcium sulphate hemihydrate crystals suspended in an aqueous phase based-on phosphoric acid, wherein the content of free SO.sub.3 is less than 10% by weight, and a separation between said aqueous phase and a filter cake based on particularly pure -calcium sulphate hemihydrate.

A method for preparing calcium sulphate comprising a production of DCP by the attack of a source of phosphate by an acid, a digestion of the isolated DCP by the sulphuric acid under conditions giving rise to the formation of a first slurry of gypsum suspended in an acidic aqueous phase having a content of free SO.sub.3 equal to or less than 1.5% and a content of free P.sub.2O.sub.5, a conversion of at least part of said first slurry by heating to a temperature greater than 80 C. and potentially by adding sulphuric acid, with solubilisation of the gypsum crystals and recrystallisation of the solubilised calcium sulphate in a second slurry of -calcium sulphate hemihydrate crystals suspended in an aqueous phase based-on phosphoric acid, wherein the content of free SO.sub.3 is less than 10% by weight, and a separation between said aqueous phase and a filter cake based on particularly pure -calcium sulphate hemihydrate.

An accelerator for accelerating the rate of hydration of calcined gypsum is disclosed. The accelerator comprises calcium sulfate dihydrate particles and a starch. The starch has a cold water solubility of at least about 25% (e.g., at least about 35%) and a viscosity of about 25 Brabender Units (BU) or less when the starch is in a 30% aqueous slurry at 92 C. Also disclosed are a method of preparing an accelerator, method of hydrating stucco to form set gypsum, slurry, and method of making gypsum board.

Wasted gypsum boards are crushed and heated to convert semi-hydrated gypsum and/or anhydrous type III gypsum, and the obtained semi-hydrated gypsum and/or anhydrous type III gypsum is mixed with gypsum slurry. The gypsum slurry is solid/liquid separated by a filtration device into gypsum particles and filtrate which has passed through the filter cloth of the filtration device. The filtrate is returned into the gypsum slurry. The solid/liquid separation is performed such that the concentration of the suspended solid in the filtrate that has passed through the filter cloth and consists of gypsum granules and inorganic impurities derived from wasted gypsum boards is made 1000 to 8000 mass ppm. The clogging of the filter cloth is reduced.

Wasted gypsum boards are crushed and heated to convert semi-hydrated gypsum and/or anhydrous type III gypsum, and the obtained semi-hydrated gypsum and/or anhydrous type III gypsum is mixed with gypsum slurry. The gypsum slurry is solid/liquid separated by a filtration device into gypsum particles and filtrate which has passed through the filter cloth of the filtration device. The filtrate is returned into the gypsum slurry. The solid/liquid separation is performed such that the concentration of the suspended solid in the filtrate that has passed through the filter cloth and consists of gypsum granules and inorganic impurities derived from wasted gypsum boards is made 1000 to 8000 mass ppm. The clogging of the filter cloth is reduced.

A low-cost four-element system cementitious material, a preparation method and an application thereof are provided by the present disclosure, and the cementitious material is used in the fields of mine cementing filling and building materials. The four-element system cementitious material includes the following raw materials in percentage by mass: 20-60% of water-quenched blast furnace slag, 10-40% of waste incineration bottom ash, 20% of pretreated waste incineration fly ash and the balance of desulfurization gypsum. The low-cost four-element system cementitious material is used to replace cement to prepare mine cementing filling materials, and is also used to prepare concrete materials for construction industry.

Wasted gypsum boards are crushed and calcined to gypsum granular solid, and the gypsum granular solid is mixed with water to form gypsum slurry. Gypsum particles are deposited from the gypsum slurry in a crystallization tank. Heated steam is blown into the gypsum slurry at a height from surface of the gypsum slurry and down to upper ? of the gypsum slurry to heat the gypsum slurry and to eliminate foam on the gypsum slurry.