The present disclosure relates to a high-strength concrete and a preparation method thereof. The high-strength concrete includes lignin, recycled fine powder, cement, water, sand, gravels and a water reducing agent. The recycled fine powder is recycled fine powder of discarded concrete, and is prepared by separating solid waste of discarded buildings, then performing impurity removal and crushing processing, and grinding same by a ball mill into dust with a particle size of less than 0.16 mm. The lignin is discarded wood lignin, which is prepared by crushing the wood, stirring and extracting a sodium hydroxide aqueous solution with a mass concentration of 5% for 1 to 2 hours at the temperature of 80 DEG C. to obtain a black lignin alkali solution, adding a hydrochloric acid solution with a mass concentration of 30% into the alkali solution for stirring, and making the pH reduced to 7.0 for standing and layering.

The invention relates to a mineral binder suitable for use in binding aggregate in a mineral mortar or concrete mixture, said binder comprising the following components:

a) at least 40 wt % of calcined kaolinitic clay and ultrafine crushed CDW,
wherein the ratio between calcined clay and ultrafine crushed CDW is between 3:7 and 1:1 (w/w),
b) optionally 2-50 wt. % of a chemical activator; and
wherein the calcined kaolinitic clay, the ultrafine crushed CDW and the optionally present chemical activator are present in a combined amount of at least 90 wt. %, based on the total weight of the binder. The invention further relates to mineral mortar or concrete mixtures based on this mineral binder, as well as building units made from these mixtures.

The invention relates to a mineral binder suitable for use in binding aggregate in a mineral mortar or concrete mixture, said binder comprising the following components:

a) at least 40 wt % of calcined kaolinitic clay and ultrafine crushed CDW,
wherein the ratio between calcined clay and ultrafine crushed CDW is between 3:7 and 1:1 (w/w),
b) optionally 2-50 wt. % of a chemical activator; and
wherein the calcined kaolinitic clay, the ultrafine crushed CDW and the optionally present chemical activator are present in a combined amount of at least 90 wt. %, based on the total weight of the binder. The invention further relates to mineral mortar or concrete mixtures based on this mineral binder, as well as building units made from these mixtures.

An insulating material, in particular a permeable fire-proof insulating material comprising water glass and polystyrene, consisting of a hardening mixture which contains 1 to 32.4 wt % of expanded polystyrene, 57.5 to 96.0 wt % of aqueous sodium silicate solution, 2 to 6 wt % of aluminium hydroxide, 0.8 to 2.6 wt % water glass hardener and 0.1 to 0.5 wt % of water glass stabilizer, while the surface of the expanded polystyrene is provided with carbon black, the carbon black making up 0.1 to 1 wt % of total weight. A method for the production of insulating material, in particular a method for the production of permeable fire-proof insulating material comprising water glass and polystyrene, according to which firstly the polystyrene beads are mixed with an aqueous solution of carbon black so as to coat their entire surface, then is added to the aqueous sodium silicate solution aluminium hydroxide and the whole is mixed so as to form an insulating mixture, and then a water glass stabilizer is added to the aqueous sodium silicate solution, and then to this solution is mixed water glass hardener, with this solution being further stirred for 1 to 10 minutes to form a binder solution, and the insulating mixture is added to the binder solution with constant stirring, and the whole is mixed, and the resulting mixture is then poured into the application site.

An insulating material, in particular a permeable fire-proof insulating material comprising water glass and polystyrene, consisting of a hardening mixture which contains 1 to 32.4 wt % of expanded polystyrene, 57.5 to 96.0 wt % of aqueous sodium silicate solution, 2 to 6 wt % of aluminium hydroxide, 0.8 to 2.6 wt % water glass hardener and 0.1 to 0.5 wt % of water glass stabilizer, while the surface of the expanded polystyrene is provided with carbon black, the carbon black making up 0.1 to 1 wt % of total weight. A method for the production of insulating material, in particular a method for the production of permeable fire-proof insulating material comprising water glass and polystyrene, according to which firstly the polystyrene beads are mixed with an aqueous solution of carbon black so as to coat their entire surface, then is added to the aqueous sodium silicate solution aluminium hydroxide and the whole is mixed so as to form an insulating mixture, and then a water glass stabilizer is added to the aqueous sodium silicate solution, and then to this solution is mixed water glass hardener, with this solution being further stirred for 1 to 10 minutes to form a binder solution, and the insulating mixture is added to the binder solution with constant stirring, and the whole is mixed, and the resulting mixture is then poured into the application site.

A method for making a carbonated precast concrete product includes: obtaining a mixture including at least one binder material, an aggregate, and water; molding the mixture into a molded intermediate; demolding the molded intermediate to obtain a demolded intermediate, the demolded intermediate having a first water-to-binder ratio; conditioning the demolded intermediate to provide a conditioned article having a second water-to-binder ratio less than the first water-to-binder ratio of the demolded intermediate; moisturizing at least one surface of the conditioned article with an aqueous medium, thereby causing a weight gain of the conditioned article and providing a moisturized product, a first portion of the moisturized product having a third water-to-binder ratio greater than a fourth water-to-binder ratio of a remainder of the moisturized product; and curing the moisturized product with carbon dioxide to obtain the carbonated precast concrete product.

A method for making a carbonated precast concrete product includes: obtaining a mixture including at least one binder material, an aggregate, and water; molding the mixture into a molded intermediate; demolding the molded intermediate to obtain a demolded intermediate, the demolded intermediate having a first water-to-binder ratio; conditioning the demolded intermediate to provide a conditioned article having a second water-to-binder ratio less than the first water-to-binder ratio of the demolded intermediate; moisturizing at least one surface of the conditioned article with an aqueous medium, thereby causing a weight gain of the conditioned article and providing a moisturized product, a first portion of the moisturized product having a third water-to-binder ratio greater than a fourth water-to-binder ratio of a remainder of the moisturized product; and curing the moisturized product with carbon dioxide to obtain the carbonated precast concrete product.

The invention relates to a method for layer-by-layer deposition of concrete by providing extrudable concrete. A first flow comprising a binder material and water and a second flow comprising a carrier material, an additional component and water are mixed in a static mixer to form a third flow of extrudable concrete. The material of the second flow has a shorter initial setting time than the material of the first flow. The first flow has a first viscosity V1 and the second flow has a second viscosity V2 so that the ratio V1/V2 ranges between 1/40 and 40. The third flow has a viscosity larger than the viscosity of the first flow and the second flow and a yield stress larger than the yield stress of the first flow and the second flow. The material of the third flow has an initial setting time shorter than initial setting time of the first flow.

The invention further relates to a system to extrude concrete, in particular for layer-by-layer deposition of concrete.

The invention relates to a method for layer-by-layer deposition of concrete by providing extrudable concrete. A first flow comprising a binder material and water and a second flow comprising a carrier material, an additional component and water are mixed in a static mixer to form a third flow of extrudable concrete. The material of the second flow has a shorter initial setting time than the material of the first flow. The first flow has a first viscosity V1 and the second flow has a second viscosity V2 so that the ratio V1/V2 ranges between 1/40 and 40. The third flow has a viscosity larger than the viscosity of the first flow and the second flow and a yield stress larger than the yield stress of the first flow and the second flow. The material of the third flow has an initial setting time shorter than initial setting time of the first flow.

The invention further relates to a system to extrude concrete, in particular for layer-by-layer deposition of concrete.

A high-strength geopolymer hollow microsphere, a preparation method thereof and a phase change energy storage microsphere are provided, including: dissolving sodium hydroxide, sodium silicate and spheroidizing aid in water to form a solution A, and adding active powder to the solution A, stirring and uniformly mixing to form a slurry B, adding the slurry B to an oil phase, stirring and dispersing into balls, filtering to obtain geopolymer microspheres I, washing the geopolymer microspheres I, and then carrying out a high-temperature calcination to obtain the high-strength geopolymer hollow microspheres II; using the high-strength geopolymer hollow microsphere as a carrier, absorbing a phase change material into the carrier, and mixing a microsphere carrying the phase change material with an epoxy resin, adding a powder dispersant and stirring to disperse the microsphere, after the epoxy resin is solidified, screening the superfluous powder dispersant to obtain the phase energy storage microsphere.