C07C1/32

Production of linear alpha olefins from organic sulfides

Embodiments of the disclosure provide a system and method for producing a linear alpha olefin. A disulfide, a hydrogen donating compound, and water are combined to produce a mixture. The mixture is introduced to a reactor operated at a pressure equal to or greater than 22.06 MPa and a temperature equal to or greater than 374 deg. C. to produce an effluent stream. The effluent stream is separated to produce a product stream including the linear alpha olefin. The disulfide can be a compound of formula R—S—S—R′ where R is a first alkyl group having carbon atoms ranging from 1 to 12 and R′ is a second alkyl group having carbon atoms ranging from 5 to 12. The hydrogen donating compound can include a partially hydrogenated multi-ring aromatic compound.

SYNTHESIS OF E,E-FARNESOL, FARNESYL ACETATE AND SQUALENE FROM FARNESENE VIA FARNESYL CHLORIDE
20210114953 · 2021-04-22 ·

The present disclosure provides methods for preparing polyunsaturated hydrocarbons, such as E,E-farnesol, farnesyl acetate and squalene, by base catalyzed addition of a dialkylamine to a 3-methylene-1-alkene, such as farnesene. The present disclosure also provides compositions including one more farnesene derivatives prepared using the disclosed methods.

SYNTHESIS OF E,E-FARNESOL, FARNESYL ACETATE AND SQUALENE FROM FARNESENE VIA FARNESYL CHLORIDE
20210114953 · 2021-04-22 ·

The present disclosure provides methods for preparing polyunsaturated hydrocarbons, such as E,E-farnesol, farnesyl acetate and squalene, by base catalyzed addition of a dialkylamine to a 3-methylene-1-alkene, such as farnesene. The present disclosure also provides compositions including one more farnesene derivatives prepared using the disclosed methods.

SYNTHESIS OF E,E-FARNESOL, FARNESYL ACETATE AND SQUALENE FROM FARNESENE VIA FARNESYL CHLORIDE
20210114953 · 2021-04-22 ·

The present disclosure provides methods for preparing polyunsaturated hydrocarbons, such as E,E-farnesol, farnesyl acetate and squalene, by base catalyzed addition of a dialkylamine to a 3-methylene-1-alkene, such as farnesene. The present disclosure also provides compositions including one more farnesene derivatives prepared using the disclosed methods.

METHOD FOR SYNTHESIZING ORGANIC MAGNESIUM COMPOUND, METHOD FOR SYNTHESIZING ORGANIC BORONIC ACID COMPOUND, AND COUPLING METHOD

An object is to establish a technology with which an organic magnesium compound can be easily and efficiently synthesized at a low cost with few steps that do not involve a complex chemical method. A method for synthesizing an organic magnesium compound includes, in a reaction solvent, reacting an organic halide represented by General Formula I (R.sup.aX.sup.a) with a dispersion product obtained by dispersing sodium in a dispersion solvent to obtain an organic sodium compound represented by General Formula II (R.sup.aNa), and reacting the obtained organic sodium compound with a magnesium halide represented by General Formula III (Mg(X.sup.b).sub.2) to obtain an organic magnesium compound represented by General Formula IV (R.sup.aMgX.sup.b).

METHODS FOR GENERATING PURIFIED CYCLOPROPENES
20210047247 · 2021-02-18 ·

The present invention relates to methods of preparing purified cyclopropylene (1-methylcyclopropylene) gas employing one or more non-reactive purification processes to purify substances including, without limitation, cyclopropene (1-methylcyclopropylene) gas and/or lithio-cyclopropene.

METHOD OF PREPARING SILICA SUPPORTED CoMoS HYDRODESULFURIZATION CATALYSTS

A method of preparing hydrodesulfurization catalysts having cobalt and molybdenum sulfide deposited on a support material containing mesoporous silica. The method utilizes a sulfur-containing silane that dually functions as a silica source and a sulfur precursor. The method involves an one-pot strategy for hydrothermal treatment and a single-step calcination and sulfidation procedure. The application of the hydrodesulfurization catalysts in treating a hydrocarbon feedstock containing sulfur compounds to produce a desulfurized hydrocarbon stream is also specified.

HYDRODESULFURIZATION CATALYST WITH A ZEOLITE-GRAPHENE MATERIAL COMPOSITE SUPPORT AND METHODS THEREOF

A hydrodesulfurization catalyst, which includes (i) a catalyst support including a zeolite doped with 0.1 to 0.5 wt. % of a graphene material, based on a total weight of the catalyst support, (ii) 5 to 20 wt. % of molybdenum, based on a total weight of the hydrodesulfurization catalyst, and (iii) 1 to 6 wt. % of a promoter selected from the group consisting of cobalt and nickel, based on a total weight of the hydrodesulfurization catalyst. The molybdenum and the promoter are homogeneously disposed on the catalyst support. A method of producing the hydrodesulfurization catalyst via incipient wetness impregnation techniques, and a method for desulfurizing a hydrocarbon feedstock with the hydrodesulfurization catalyst are also provided.

Surface-modified calcium carbonate as carrier for transition metal-based catalysts

The present invention relates to a catalyst system comprising a transition metal compound on a solid carrier which is a surface-reacted calcium carbonate. The invention further relates to a method for manufacturing said catalyst system and to its use in heterogeneous catalysis.

Synthesis of polyaryl substituted aryl compounds

A method for the synthesis of a aryl compound of Formula (1).
Uprivate use character ParenopenstT-WR.sub.1).sub.n (1)