Hydrodeoxygenating a biorenewable feed that is concentrated in free fatty acids with 10-13 carbon atoms at a moderate hydrodeoxygenation ratio that is less than the ratio of hydrodeoxygenation utilized for traditional biorenewable feeds such as vegetable oil or even mineral feedstocks, normal paraffins in the range desired by the detergents industry can be produced. Either hydroisomerization or an iso-normal separation can be performed to provide green fuel streams. Two reactors are proposed, one for hydrodeoxygenation of the biorenewable feed that is concentrated in free fatty acids with 10-13 carbon atoms and the other for a traditional biorenewable feed or even a mineral feed operated at a higher deoxygenation ratio.

Hydrodeoxygenating a biorenewable feed that is concentrated in free fatty acids with 10-13 carbon atoms at a moderate hydrodeoxygenation ratio that is less than the ratio of hydrodeoxygenation utilized for traditional biorenewable feeds such as vegetable oil or even mineral feedstocks, normal paraffins in the range desired by the detergents industry can be produced. Either hydroisomerization or an iso-normal separation can be performed to provide green fuel streams. Two reactors are proposed, one for hydrodeoxygenation of the biorenewable feed that is concentrated in free fatty acids with 10-13 carbon atoms and the other for a traditional biorenewable feed or even a mineral feed operated at a higher deoxygenation ratio.

Disclosed is a method for producing hydrogen, carbon, and ethylene from a methane-containing feedstock even without recycling of unreacted methane by providing a single process or system in which a methane-containing feedstock is subjected to two methane conversion steps. The method includes a first conversion step of producing hydrogen and carbonaceous materials and a second conversion step of producing acetylene from unreacted methane and hydrogen discharged from the first conversion step while maintaining a good methane conversion and suppressing coke formation, followed by separating and recovering ethylene and hydrogen produced through selective hydrogenation of acetylene.

Disclosed is a method for producing hydrogen, carbon, and ethylene from a methane-containing feedstock even without recycling of unreacted methane by providing a single process or system in which a methane-containing feedstock is subjected to two methane conversion steps. The method includes a first conversion step of producing hydrogen and carbonaceous materials and a second conversion step of producing acetylene from unreacted methane and hydrogen discharged from the first conversion step while maintaining a good methane conversion and suppressing coke formation, followed by separating and recovering ethylene and hydrogen produced through selective hydrogenation of acetylene.

Disclosed herein are methane conversion devices that achieve autothermal conditions and related methods using the methane conversion devices.

Disclosed herein are methane conversion devices that achieve autothermal conditions and related methods using the methane conversion devices.

Provided is a composite catalyst used in a dehydro-aromatization reaction of methane, the composite catalyst including a glasslike metal oxide catalyst which includes a supported catalyst including a porous support and a catalyst of a transition metal oxide supported on the support, and a nickel oxide (NiO) physically dispersed in the supported catalyst.

Provided is a composite catalyst used in a dehydro-aromatization reaction of methane, the composite catalyst including a glasslike metal oxide catalyst which includes a supported catalyst including a porous support and a catalyst of a transition metal oxide supported on the support, and a nickel oxide (NiO) physically dispersed in the supported catalyst.

The present invention provides a one-pot process of synthesis of phenyl naphthalene compounds that are employed as heat transfer agents. More particularly, the present invention provides a process of preparation of 1-phenylnaphthalene and 2-methyl-1-phenylnaphthalene using refinery spent catalyst. These molecules are known for application as synthetic heat transfer fluids that deliver outstanding performance and thermal stability at continuously high operating temperatures. The reaction is carried out in aqueous medium using a spent catalyst which is a palladium based charcoal catalyst as obtained from various refinery processes. Further, the present invention provides a heat resistant formulation using the synthesized polyhydrocarbons, wherein the formulation is optimized with a free radical scavenger.

The present invention provides a one-pot process of synthesis of phenyl naphthalene compounds that are employed as heat transfer agents. More particularly, the present invention provides a process of preparation of 1-phenylnaphthalene and 2-methyl-1-phenylnaphthalene using refinery spent catalyst. These molecules are known for application as synthetic heat transfer fluids that deliver outstanding performance and thermal stability at continuously high operating temperatures. The reaction is carried out in aqueous medium using a spent catalyst which is a palladium based charcoal catalyst as obtained from various refinery processes. Further, the present invention provides a heat resistant formulation using the synthesized polyhydrocarbons, wherein the formulation is optimized with a free radical scavenger.