The present invention relates to a separation method and a separation process system for easily recovering ethanol from an ethanol oligomerization reactant containing unreacted ethanol. A separation method according to the present invention may improve the economics and increase separation efficiency by easily refluxing ethylene while reducing or excluding the use of a reflux system which uses an expensive cooling medium, and the like, and may also improve process efficiency by reducing the amount of heat used by a reboiler.

The present invention relates to a separation method and a separation process system for easily recovering ethanol from an ethanol oligomerization reactant containing unreacted ethanol. A separation method according to the present invention may improve the economics and increase separation efficiency by easily refluxing ethylene while reducing or excluding the use of a reflux system which uses an expensive cooling medium, and the like, and may also improve process efficiency by reducing the amount of heat used by a reboiler.

The present invention relates to a separation method and a separation process system for easily recovering ethanol from an ethanol oligomerization reactant containing unreacted ethanol. A separation method according to the present invention may improve the economics and increase separation efficiency by easily refluxing ethylene while reducing or excluding the use of a reflux system which uses an expensive cooling medium, and the like, and may also improve process efficiency by reducing the amount of heat used by a reboiler.

The method of making a wall-coated open tubular capillary column with a poly benzyl stationary phase is a method of preparing a capillary column for gas chromatography. An inner wall of a fused silica capillary column is cleaned and then rinsed with a sodium hydroxide solution. The fused silica capillary column is flushed with isopropanol to form a pre-treated capillary column, and the pre-treated capillary column is loaded with a mixture of phenyl tri-methoxy silane and alcohol. The loaded pre-treated capillary column is heated to form a treated capillary column, which is then washed. A thin layer of a poly benzyl stationary phase is then coated on the inner wall through condensation polymerization of benzyl chloride monomers with a Lewis acid catalyst in a non-polar solvent.

The method of making a wall-coated open tubular capillary column with a poly benzyl stationary phase is a method of preparing a capillary column for gas chromatography. An inner wall of a fused silica capillary column is cleaned and then rinsed with a sodium hydroxide solution. The fused silica capillary column is flushed with isopropanol to form a pre-treated capillary column, and the pre-treated capillary column is loaded with a mixture of phenyl tri-methoxy silane and alcohol. The loaded pre-treated capillary column is heated to form a treated capillary column, which is then washed. A thin layer of a poly benzyl stationary phase is then coated on the inner wall through condensation polymerization of benzyl chloride monomers with a Lewis acid catalyst in a non-polar solvent.

Method for separating the diamondoids by liquid chromatography from a sample of iso-alkanes and cycloalkanes, or from a mixture of organic compounds, this method comprising introducing the sample into a column comprising a stationary phase comprising a material capable of forming inclusion complexes with the diamondoids, eluting with an eluent, and collecting the eluted fraction.

The present invention relates to a separation method and a separation process system for easily recovering ethanol from an ethanol oligomerization reactant containing unreacted ethanol. A separation method according to the present invention may improve the economics and increase separation efficiency by easily refluxing ethylene while reducing or excluding the use of a reflux system which uses an expensive cooling medium, and the like, and may also improve process efficiency by reducing the amount of heat used by a reboiler.

The present invention relates to a separation method and a separation process system for easily recovering ethanol from an ethanol oligomerization reactant containing unreacted ethanol. A separation method according to the present invention may improve the economics and increase separation efficiency by easily refluxing ethylene while reducing or excluding the use of a reflux system which uses an expensive cooling medium, and the like, and may also improve process efficiency by reducing the amount of heat used by a reboiler.

The present invention provides a zirconium-based metal-organic framework material and a preparation method therefor and the use thereof, and an adsorption separation device and method. The zirconium-based metal-organic framework material has a chemical structural formula of [C.sub.18H.sub.6O.sub.16Zr.sub.3].sub.n, and comprises zirconium and an organic ligand forming a coordination bond with zirconium, wherein the organic ligand is diphenylethyne-3,3,5,5-tetracarboxylic acid. The molecular structure of the zirconium-based metal-organic framework material of the present invention is a three-position network structure having a one-dimensional channel; and in the present invention, the size of the one-dimensional channel is accurately controlled by changing the aspect ratio of the organic ligand, such that the zirconium-based metal-organic framework material efficiently separates a hexane isomer by means of a kinetic effect.