Patent classifications
C07C17/38
Storage method for hydrochlorofluoroolefin, and storage container for hydrochlorofluoroolefin
To provide a method for safely and stably storing a hydrochlorofluoroolefin filled in a container for storage, transportation, etc. A method for storing a hydrochlorofluoroolefin in a sealed storage container, wherein the hydrochlorofluoroolefin is stored in such a state that a gas phase and a liquid phase coexist in the storage container, and the concentration of air in the gas phase in the storage container at a temperature of 25° C. is kept to be at most 3.0 vol %, and a method for storing a hydrochlorofluoroolefin in a sealed storage container, wherein the hydrochlorofluoroolefin is stored in such a state that a gas phase and a liquid phase coexist in the storage container, and the concentration of oxygen in the gas phase in the storage container at a temperature of 25° C. is kept to be at most 0.6 vol %.
Process for producing trifluoroiodomethane (CF3I) from trifluoroacetic anhydride (TFAA)
The present disclosure relates to a method for producing trifluoroiodomethane (CF.sub.3I) from iodine (I.sub.2) and trifluoroacetic anhydride (TFAA) under photochemical conditions using ultraviolet (UV) light.
Process for producing trifluoroiodomethane (CF3I) from trifluoroacetic anhydride (TFAA)
The present disclosure relates to a method for producing trifluoroiodomethane (CF.sub.3I) from iodine (I.sub.2) and trifluoroacetic anhydride (TFAA) under photochemical conditions using ultraviolet (UV) light.
Process for the preparation of 1,1,1,2,2-pentafluoropropane
The present invention provides a process for preparing 1,1,1,2,2-pentafluoropropane (245cb), the process comprising gas phase catalytic dehydrochlorination of a composition comprising 1,1,1-trifluoro-2,3-dichloropropane (243db) to produce an intermediate composition comprising 3,3,3-trifluoro-2-chloro-prop-1-ene (CF.sub.3CCI═CH.sub.2, 1233xf), hydrogen chloride (HCl) and, optionally, air; and gas phase catalytic fluorination with hydrogen fluoride (HF) of the intermediate composition to produce a reactor product composition comprising 245cb, HF, HCl and air; wherein the process is carried out with a co-feed of air.
METHOD FOR DEHYDROCHLORINATION OF HCFC-244BB TO MANUFACTURE HFO-1234YF
A process for making 2,3,3,3-tetrafluoropropene (HFO-1234yf) includes providing a composition including 2-chloro-1,1,1,2-tetrafluorepropane (HCFC-244bb) to a reactor including a heater surface at a surface temperature greater than about 850° F. (454°C), and then bringing the composition into contact with the heater surface for a contact time of less than 10 seconds to dehydrochlorinate a portion of the HCFC-244bb to make HFO-1234yf.
METHOD FOR DEHYDROCHLORINATION OF HCFC-244BB TO MANUFACTURE HFO-1234YF
A process for making 2,3,3,3-tetrafluoropropene (HFO-1234yf) includes providing a composition including 2-chloro-1,1,1,2-tetrafluorepropane (HCFC-244bb) to a reactor including a heater surface at a surface temperature greater than about 850° F. (454°C), and then bringing the composition into contact with the heater surface for a contact time of less than 10 seconds to dehydrochlorinate a portion of the HCFC-244bb to make HFO-1234yf.
High-purity 1,1,1,2,3,3-hexafluoropropane, method for producing same and use thereof
The present invention relates to a method for producing high-purity 1,1,1,2,3,3-hexafluoropropane and a composition containing mainly 1,1,1,2,3,3-hexafluoropropane, suitable for use as a cleaning agent in the semiconductor industry.
High-purity 1,1,1,2,3,3-hexafluoropropane, method for producing same and use thereof
The present invention relates to a method for producing high-purity 1,1,1,2,3,3-hexafluoropropane and a composition containing mainly 1,1,1,2,3,3-hexafluoropropane, suitable for use as a cleaning agent in the semiconductor industry.
Processes for producing very high purity 1,1,1,2,3-pentachloropropane
Disclosed is a process for preparing a highly pure 1,1,1,2,3-pentachloropropane product, comprising 1-a) providing a reaction mixture comprising ethylene, carbon tetrachloride and a catalyst in a principal alkylation zone to produce 1,1,1,3-tetrachloropropane in the reaction mixture, and 1-btreating the reaction mixture obtained in step 1-a) to obtain a 1,1,1,3-tetrachloropropane feedstock; 2-a) contacting the 1,1,1,3-tetrachloropropane feedstock with a catalyst in a dehydrochlorination zone to produce a reaction mixture comprising 1,1,1,3-tetrachloropropane and 1,1,3-trichloropropene, and 2-b) treating the reaction mixture obtained in step 2-a) to obtain a 1,1,3-trichloropropene feedstock; 3-a) contacting the 1,1,3-trichloropropene feedstock with chlorine in a reaction zone to produce a reaction mixture containing 1,1,1,2,3-pentachloropropane and 1,1,3-trichloropropene, the reaction zone being different from the dehydrochlorination zone, and 3-b) treating the reaction mixture obtained in step 3-a) to obtain the highly pure 1,1,1,2,3-pentachloropropane product.
Processes for producing very high purity 1,1,1,2,3-pentachloropropane
Disclosed is a process for preparing a highly pure 1,1,1,2,3-pentachloropropane product, comprising 1-a) providing a reaction mixture comprising ethylene, carbon tetrachloride and a catalyst in a principal alkylation zone to produce 1,1,1,3-tetrachloropropane in the reaction mixture, and 1-btreating the reaction mixture obtained in step 1-a) to obtain a 1,1,1,3-tetrachloropropane feedstock; 2-a) contacting the 1,1,1,3-tetrachloropropane feedstock with a catalyst in a dehydrochlorination zone to produce a reaction mixture comprising 1,1,1,3-tetrachloropropane and 1,1,3-trichloropropene, and 2-b) treating the reaction mixture obtained in step 2-a) to obtain a 1,1,3-trichloropropene feedstock; 3-a) contacting the 1,1,3-trichloropropene feedstock with chlorine in a reaction zone to produce a reaction mixture containing 1,1,1,2,3-pentachloropropane and 1,1,3-trichloropropene, the reaction zone being different from the dehydrochlorination zone, and 3-b) treating the reaction mixture obtained in step 3-a) to obtain the highly pure 1,1,1,2,3-pentachloropropane product.