C07C53/08

IONIC LIQUID, SOLVENT, PREPARATION, AND TRANSDERMALLY ABSORBABLE AGENT
20230140926 · 2023-05-11 ·

An ionic liquid has a structure represented by the following general formula (1). In the general formula (1), R represents a substituted or unsubstituted alkyl group or a substituted or unsubstituted alkenyl group, and at least one ethylene group comprising the alkenyl group may be substituted with a vinylene group. X.sup.+ represents a phospholipid with a cationic group.


R—COO.sup.−X.sup.+  General formula (1)

METHOD FOR PRODUCING PURIFIED ACETIC ACID
20230133006 · 2023-05-04 · ·

Provided is a method for producing purified acetic acid from a mixed solution containing acetic acid, an organic solvent, and water in an energy-efficient manner. The method, which is for producing purified acetic acid from a mixed solution containing acetic acid, an organic solvent, and water, includes: a distillation step in which the mixed solution is distilled and separated into a purified liquid rich in acetic acid and a separated liquid rich in an organic solvent; and a membrane separation step in which the water is separated from the purified liquid by a separation membrane. The purified liquid has a water concentration of 4 wt.% or less.

METHOD FOR PRODUCING PURIFIED ACETIC ACID
20230133006 · 2023-05-04 · ·

Provided is a method for producing purified acetic acid from a mixed solution containing acetic acid, an organic solvent, and water in an energy-efficient manner. The method, which is for producing purified acetic acid from a mixed solution containing acetic acid, an organic solvent, and water, includes: a distillation step in which the mixed solution is distilled and separated into a purified liquid rich in acetic acid and a separated liquid rich in an organic solvent; and a membrane separation step in which the water is separated from the purified liquid by a separation membrane. The purified liquid has a water concentration of 4 wt.% or less.

Preparative method for carboxylic acids

A preparative method for carboxylic acids is disclosed in the present invention. The method is characterized in that: compounds (II) are reacted in the presence of hydrogen peroxide and base to produce target products (I), as represented by the following reaction scheme: wherein R.sup.1 is aryl, pyridyl, pyrimidyl, pyridazinyl, pyrazinyl, benzothienyl, benzofuranyl, quinolinyl, isoquinolinyl, thiadiazolyl, C.sub.1-6 alkyl, C.sub.3-6 cycloalkyl, C.sub.2-6 alkenyl, C.sub.2-6 alkynyl and hydrogen; R.sup.2 is alkoxycarbonyl, alkylaminocarbonyl, aminocarbonyl, alkylthiolcarbonyl, cyano, sulfonyl, sulfinyl, carbonyl, aldehyde, carboxyl, nitro, alkyl and hydrogen; R.sup.3 is alkoxycarbonyl, alkyl amido carbonyl, aminocarbonyl, cyano, sulfonyl, sulfinyl, carbonyl, carboxyl and nitro. The present invention has the following main benefits: cheap and readily available starting materials, safe processes, high yield, good quality, which facilitates industrial production.

Preparative method for carboxylic acids

A preparative method for carboxylic acids is disclosed in the present invention. The method is characterized in that: compounds (II) are reacted in the presence of hydrogen peroxide and base to produce target products (I), as represented by the following reaction scheme: wherein R.sup.1 is aryl, pyridyl, pyrimidyl, pyridazinyl, pyrazinyl, benzothienyl, benzofuranyl, quinolinyl, isoquinolinyl, thiadiazolyl, C.sub.1-6 alkyl, C.sub.3-6 cycloalkyl, C.sub.2-6 alkenyl, C.sub.2-6 alkynyl and hydrogen; R.sup.2 is alkoxycarbonyl, alkylaminocarbonyl, aminocarbonyl, alkylthiolcarbonyl, cyano, sulfonyl, sulfinyl, carbonyl, aldehyde, carboxyl, nitro, alkyl and hydrogen; R.sup.3 is alkoxycarbonyl, alkyl amido carbonyl, aminocarbonyl, cyano, sulfonyl, sulfinyl, carbonyl, carboxyl and nitro. The present invention has the following main benefits: cheap and readily available starting materials, safe processes, high yield, good quality, which facilitates industrial production.

PROCESS FOR THE OXIDATION OF PRIMARY ALCOHOLS TO CARBOXYLIC ACIDS

The present invention relates to a process for preparing carboxylic acids by oxidizing primary alcohols in the liquid phase in the presence of ruthenium dioxide as a catalyst.

PROCESS FOR THE OXIDATION OF PRIMARY ALCOHOLS TO CARBOXYLIC ACIDS

The present invention relates to a process for preparing carboxylic acids by oxidizing primary alcohols in the liquid phase in the presence of ruthenium dioxide as a catalyst.

LIMITING ACETIC ACID PRODUCTION IN ETHANE ODH PROCESS

The present disclosure relates to limiting the production of acetic acid in an oxidative dehydrogenation process to convert ethane to ethylene. The process of oxidative dehydrogenation includes feeding acetic acid, along with ethane and oxygen into an oxidative dehydrogenation reactor where contact with a catalyst leads to conversion of the ethane into ethylene and acetic acid. By including acetic acid in the feed, the amount of acetic acid produced may be limited and the ratio of ethylene produced to ethane consumed may increase.

LIMITING ACETIC ACID PRODUCTION IN ETHANE ODH PROCESS

The present disclosure relates to limiting the production of acetic acid in an oxidative dehydrogenation process to convert ethane to ethylene. The process of oxidative dehydrogenation includes feeding acetic acid, along with ethane and oxygen into an oxidative dehydrogenation reactor where contact with a catalyst leads to conversion of the ethane into ethylene and acetic acid. By including acetic acid in the feed, the amount of acetic acid produced may be limited and the ratio of ethylene produced to ethane consumed may increase.

LIMITING ACETIC ACID PRODUCTION IN ETHANE ODH PROCESS

The present disclosure relates to limiting the production of acetic acid in an oxidative dehydrogenation process to convert ethane to ethylene. The process of oxidative dehydrogenation includes feeding acetic acid, along with ethane and oxygen into an oxidative dehydrogenation reactor where contact with a catalyst leads to conversion of the ethane into ethylene and acetic acid. By including acetic acid in the feed, the amount of acetic acid produced may be limited and the ratio of ethylene produced to ethane consumed may increase.