C07C67/44

PROCESS FOR PREPARING ESTERS OF LACTIC ACID, AND 2-HYDROXY-3-BUTENOIC ACID OR ALPHA-HYDROXY METHIONINE ANALOGUES FROM SUGARS
20190016674 · 2019-01-17 ·

A continuous flow process for the preparation of one or more esters of lactic acid and 2-hydroxy-3-butenoic acid or -hydroxy methionine analogues from a sugar in the presence of a solid Lewis acid catalyst and a solvent comprising an organic solvent and water. The invention provides a means for stabilizing a Lewis acid catalyst for use in a continuous reaction process wherein the water is present in an amount of up to or equal to 10 vol. % of the organic solvent.

Method for preparing carboxylic esters from aldehydes

A method can prepare a carboxylic ester. The method includes reacting an aldehyde in the presence of an aluminium alkoxide applied to a support material.

Method for preparing carboxylic esters from aldehydes

A method can prepare a carboxylic ester. The method includes reacting an aldehyde in the presence of an aluminium alkoxide applied to a support material.

Method for preparing carboxylic esters from aldehydes

A method can prepare a carboxylic ester. The method includes reacting an aldehyde in the presence of an aluminium alkoxide applied to a support material.

Process for preparing esters of lactic acid, and 2-hydroxy-3-butenoic acid or α-hydroxy methionine analogues from sugars

A continuous flow process for the preparation of one or more esters of lactic acid and 2-hydroxy-3-butenoic acid or -hydroxy methionine analogs from a sugar in the presence of a solid Lewis acid catalyst and a solvent comprising an organic solvent and water. The invention provides a means for stabilizing a Lewis acid catalyst for use in a continuous reaction process wherein the water is present in an amount of up to or equal to 10 vol. % of the organic solvent.

Process for preparing esters of lactic acid, and 2-hydroxy-3-butenoic acid or α-hydroxy methionine analogues from sugars

A continuous flow process for the preparation of one or more esters of lactic acid and 2-hydroxy-3-butenoic acid or -hydroxy methionine analogs from a sugar in the presence of a solid Lewis acid catalyst and a solvent comprising an organic solvent and water. The invention provides a means for stabilizing a Lewis acid catalyst for use in a continuous reaction process wherein the water is present in an amount of up to or equal to 10 vol. % of the organic solvent.

PREPARATION OF A CATALYST FOR THE OXIDATIVE ESTERIFICATION OF METHACROLEIN TO METHYL METHACRYLATE, FOR EXTENDING SERVICE LIFE

A process for performing a heterogeneously catalysed reaction for the oxidative esterification of aldehydes to carboxylic esters can be performed. Against this background, the process has made it possible to keep the heterogeneous, precious metal catalyst used in this method active during operation in a particularly effective manner, in order to lengthen the period between downtimes and to effect particularly sustainable catalyst management. This gives rise to the possibility of performing such processes in a very simple, economically viable and environmentally benign manner.

PREPARATION OF A CATALYST FOR THE OXIDATIVE ESTERIFICATION OF METHACROLEIN TO METHYL METHACRYLATE, FOR EXTENDING SERVICE LIFE

A process for performing a heterogeneously catalysed reaction for the oxidative esterification of aldehydes to carboxylic esters can be performed. Against this background, the process has made it possible to keep the heterogeneous, precious metal catalyst used in this method active during operation in a particularly effective manner, in order to lengthen the period between downtimes and to effect particularly sustainable catalyst management. This gives rise to the possibility of performing such processes in a very simple, economically viable and environmentally benign manner.

Optimized method for producing methacrolein

The present invention relates to an optimized process for the preparation of methacrolein. Methacrolein is used in chemical synthesis particularly as an intermediate for the preparation of methacrylic acid, methyl methacrylate or even active ingredients, fragrances or flavorings. In particular the present invention relates to the optimization of the process parameters by which, inter alia, a reduction of the content of harmful dimeric methacrolein in the end product may be achieved.

Aldehyde oxidation processes

The oxidation of isobutyraldehyde produces isobutyric acid and byproducts, such as isopropyl formate. A process of reducing the isopropyl formate byproduct and other byproducts in the oxidation of isobutyraldehyde is described. The process uses a carbonyl compound, such as acetone, to reduce byproduct levels in the resulting product. Process for use of static mixers in oxidation reactions of aldehydes are also provided.