Patent classifications
C07C269/02
REACTION PRODUCTS CONTAINING AMIDOAMINE GROUPS
A reaction product containing amido amine groups, comprising one or more species of the general formula (I)
(R.sup.1X).sub.pZ.sup.1(XH).sub.y (I)
where p+y=w and w is an integer from 1 to 10, p is an integer from 1 to 10, y is an integer from 0 to 9, and X is independently O, NH and/or NZ.sup.2 and XH is independently a hydroxyl group OH, a primary amino group NH2 and/or a secondary amino group NHZ.sup.2 where Z.sup.2 is independently a branched or unbranched, saturated or unsaturated organic radical G(U)a where U is independently a hydroxyl group, a primary amino group or a secondary amino group and a is an integer from 0 to 9, where p+y+as 10, and G is a branched or unbranched, saturated or unsaturated organic radical, the p R.sup.1 radicals are independently a radical of the general formula (II)
YOCONHR.sup.2NHCO (II)
in which the p Y radicals are independently a branched or unbranched, saturated or unsaturated organic radical which has 1 to 1000 carbon atoms and does not contain any hydroxyl groups, any primary amino groups or any secondary amino groups, the p R.sup.2 radicals are independently a branched or unbranched, saturated or unsaturated organic radical having 6 to 20 carbon atoms, Z.sup.1 is a branched or unbranched, saturated or unsaturated organic radical containing at least two carbon atoms, having at least one amide group and at least one tertiary amino group.
REACTION PRODUCTS CONTAINING AMIDOAMINE GROUPS
A reaction product containing amido amine groups, comprising one or more species of the general formula (I)
(R.sup.1X).sub.pZ.sup.1(XH).sub.y (I)
where p+y=w and w is an integer from 1 to 10, p is an integer from 1 to 10, y is an integer from 0 to 9, and X is independently O, NH and/or NZ.sup.2 and XH is independently a hydroxyl group OH, a primary amino group NH2 and/or a secondary amino group NHZ.sup.2 where Z.sup.2 is independently a branched or unbranched, saturated or unsaturated organic radical G(U)a where U is independently a hydroxyl group, a primary amino group or a secondary amino group and a is an integer from 0 to 9, where p+y+as 10, and G is a branched or unbranched, saturated or unsaturated organic radical, the p R.sup.1 radicals are independently a radical of the general formula (II)
YOCONHR.sup.2NHCO (II)
in which the p Y radicals are independently a branched or unbranched, saturated or unsaturated organic radical which has 1 to 1000 carbon atoms and does not contain any hydroxyl groups, any primary amino groups or any secondary amino groups, the p R.sup.2 radicals are independently a branched or unbranched, saturated or unsaturated organic radical having 6 to 20 carbon atoms, Z.sup.1 is a branched or unbranched, saturated or unsaturated organic radical containing at least two carbon atoms, having at least one amide group and at least one tertiary amino group.
Compound having polymerizable group and crosslinkable group and method for producing the same
An acrylic or methacrylic compound having N-alkoxyalkyl group; and a method for producing the compound. An acrylic or methacrylic compound having N-alkoxyalkyl group, of Formula [1]: ##STR00001##
[where R.sup.1 is a hydrogen atom or methyl group; R.sup.2 is a C.sub.2-20 alkylene group etc.; R.sup.3 is an r-valent C.sub.2-20 aliphatic group etc.; R.sup.4 is a C.sub.1-20 alkyl group etc.; Z is >NCOO or OCON< (where - is a bond, > and < each have two bonds, and any one of > and < is bonded to CH.sub.2OR.sup.4); and r is a natural number of 2 or more and 9 or less].
Compound having polymerizable group and crosslinkable group and method for producing the same
An acrylic or methacrylic compound having N-alkoxyalkyl group; and a method for producing the compound. An acrylic or methacrylic compound having N-alkoxyalkyl group, of Formula [1]: ##STR00001##
[where R.sup.1 is a hydrogen atom or methyl group; R.sup.2 is a C.sub.2-20 alkylene group etc.; R.sup.3 is an r-valent C.sub.2-20 aliphatic group etc.; R.sup.4 is a C.sub.1-20 alkyl group etc.; Z is >NCOO or OCON< (where - is a bond, > and < each have two bonds, and any one of > and < is bonded to CH.sub.2OR.sup.4); and r is a natural number of 2 or more and 9 or less].
Crosslinking component for binder resins
This invention relates to a crosslinking component for binder resins which is especially suitable to be used together with epoxy-group containing binders and/or (poly)isocyanates such as blocked (poly)isocyanates and which comprises at least two blocked isocyanate groups per molecule of the crosslinking component whereby at least one of the at least two blocked isocyanate groups is a group according to structural unit (I), wherein the ratio of structural units of formula (II), if present, to structural units of formula (I) is 0.40 or below. The cross-linking component may also be self-cross-linkable. The present invention further relates to a coating composition, e.g. a one-component coating composition comprising the crosslinking component and a method of its manufacture.
Crosslinking component for binder resins
This invention relates to a crosslinking component for binder resins which is especially suitable to be used together with epoxy-group containing binders and/or (poly)isocyanates such as blocked (poly)isocyanates and which comprises at least two blocked isocyanate groups per molecule of the crosslinking component whereby at least one of the at least two blocked isocyanate groups is a group according to structural unit (I), wherein the ratio of structural units of formula (II), if present, to structural units of formula (I) is 0.40 or below. The cross-linking component may also be self-cross-linkable. The present invention further relates to a coating composition, e.g. a one-component coating composition comprising the crosslinking component and a method of its manufacture.
ADDITION-FRAGMENTATION AGENTS
Addition-fragmentation agents of the formula are disclosed:
##STR00001##
wherein
R.sup.1, R.sup.2 and R.sup.3 are each independently Z-Q-, a (hetero)alkyl group or a (hetero)aryl group with the proviso that at least one of R.sup.1, R.sup.2 and R.sup.3 is Z.sub.m-Q-,
Q is a linking group have a valence of m+1;
Z is an ethylenically unsaturated polymerizable group,
m is 1 to 6;
each X.sup.1 is independently O or NR.sup.4, where R.sup.4 is H or C.sub.1-C.sub.4 alkyl, and
n is 0 or 1.
ADDITION-FRAGMENTATION AGENTS
Addition-fragmentation agents of the formula are disclosed:
##STR00001##
wherein
R.sup.1, R.sup.2 and R.sup.3 are each independently Z-Q-, a (hetero)alkyl group or a (hetero)aryl group with the proviso that at least one of R.sup.1, R.sup.2 and R.sup.3 is Z.sub.m-Q-,
Q is a linking group have a valence of m+1;
Z is an ethylenically unsaturated polymerizable group,
m is 1 to 6;
each X.sup.1 is independently O or NR.sup.4, where R.sup.4 is H or C.sub.1-C.sub.4 alkyl, and
n is 0 or 1.
ADDITION-FRAGMENTATION AGENTS
Addition-fragmentation agents of the formula are disclosed:
##STR00001##
wherein
R.sup.1, R.sup.2 and R.sup.3 are each independently Z-Q-, a (hetero)alkyl group or a (hetero)aryl group with the proviso that at least one of R.sup.1, R.sup.2 and R.sup.3 is Z.sub.m-Q-,
Q is a linking group have a valence of m+1;
Z is an ethylenically unsaturated polymerizable group,
m is 1 to 6;
each X.sup.1 is independently O or NR.sup.4, where R.sup.4 is H or C.sub.1-C.sub.4 alkyl, and
n is 0 or 1.
Intermediate of tapentadol
The present invention relates to novel carbamate intermediate of formula (II), process for its preparation and process for its conversion into 3-[(1R,2R)-3-(dimethylamino)-1-ethyl-2-methylpropyl]phenol, tapentadol and its pharmaceutically acceptable salts. ##STR00001##