Patent classifications
C07F1/02
Phenanthroline-based compound for organic electroluminescence device
The present invention discloses a phenanthroline-based compound and an organic EL device employing the compound as phosphorescent light emitting host material of a light emitting layer and/or electron transporting layer material and/or hole blocking layer material and/or a thermally activated delayed fluorescence (TADF) material of a light emitting layer which can display good performance.
NON-AQUEOUS LIQUID ELECTROLYTE, ELECTRICITY STORAGE DEVICE USING SAME, AND PHOSPHORUS COMPOUND USED THEREIN
The present invention is concerned with a nonaqueous electrolytic solution having an electrolyte salt dissolved in a nonaqueous solvent, the nonaqueous electrolytic solution containing a compound represented by the following general formula (X), in which a polar group (X) is bound to a phosphorus atom (P), and capable of improving electrochemical characteristics in a broad temperature range; an energy storage device using the same; and a novel compound.
##STR00001##
In the formula, R.sup.10 and R.sup.20 are each independently an organic group selected from the group consisting of an alkyl group having 1 to 8 carbon atoms, an alkenyl group having 2 to 6 carbon atoms, an alkynyl group having 3 to 6 carbon atoms, and an aryl group having 6 to 12 carbon atoms, or a lithium atom; and X is a polar group (i) containing a —C(═O) group, a —P(═O) group, or an —S(═O).sub.2 group, a polar group (ii) containing a —CN group or an alkyl group having 1 to 6 carbon atoms, in which a part of hydrogen atoms is substituted with a fluorine atom, or a 4- to 7-membered ring polar group (iii) containing a —C(═O)—O— group or a —C(═O)—N— group, provided that when X is a 4- to 7-membered ring polar group (iii) containing a —C(═O)—N— group, at least one of R.sup.10 and R.sup.20 is a lithium atom.
ELECTROLYTIC SOLUTION AND NOVEL FLUORINATED PHOSPHORIC ACID ESTER
The present invention provides a novel electrolyte solution capable of providing electrochemical devices having a high storage capacity retention. The electrolyte solution of the present invention contains a fluorinated phosphoric acid ester containing a non-fluorinated alkylene group having one or more carbon atoms as a linking group.
ELECTROLYTIC SOLUTION AND NOVEL FLUORINATED PHOSPHORIC ACID ESTER
The present invention provides a novel electrolyte solution capable of providing electrochemical devices having a high storage capacity retention. The electrolyte solution of the present invention contains a fluorinated phosphoric acid ester containing a non-fluorinated alkylene group having one or more carbon atoms as a linking group.
Hydrocarbon-soluble halogen and thiolate/magnesium exchange reagents
The invention relates to hydrocarbon-soluble halogen or thiolate/magnesium exchange reagents of the general formula
R.sup.1MgR.sup.1.sub.1-n(OR.sup.3).sub.n.LiOR2.(1−n)LiOR.sup.3.aDonor
in which: R.sup.1 is a C1-C8 alkyl and OR.sup.2 as well as OR.sup.3 are same or different and represent primary, secondary, or tertiary alkoxide residues having 3 to 18 carbon atoms, wherein R.sup.2 and/or R.sup.3 can for their part contain an alkoxy substituent OR.sup.4; a assumes a value of 0 to 2, n assumes a value between 0 and 1, and the donor is an organic molecule containing at least 2 nitrogen atoms.
Lithium battery
A lithium battery includes a cathode including a cathode active material; an anode including an anode active material; and an organic electrolytic solution between the cathode and the anode, wherein the anode active material includes natural graphite and artificial graphite, an amount of the artificial graphite being about 50 wt % or more based on a total weight of the anode active material, and the organic electrolytic solution includes: a first lithium salt; an organic solvent; and a bicyclic sulfate-based compound represented by Formula 1 below: ##STR00001## wherein, in Formula 1, each of A.sub.1, A.sub.2, A.sub.3, and A.sub.4 is independently a covalent bond, a substituted or unsubstituted C.sub.1-C.sub.5 alkylene group, a carbonyl group, or a sulfinyl group, in which both A.sub.1 and A.sub.2 are not a covalent bond and both A.sub.3 and A.sub.4 are not a covalent bond.
Process and catalyst composition for producing selectively hydrogenated conjugated diene polymer
A catalyst composition for selectively hydrogenating a conjugated diene polymer in a homogeneous system is provided, wherein the conjugated diene polymer comprises a conjugated diene monomer or a combination of a conjugated diene monomer and a vinyl aromatic monomer. The catalyst composition includes the catalyst components of (a) a titanium compound; (b) an organometallic compound; and (c) an oligomer containing a polyglycol segment. The hydrogenated polymer produced using the catalyst composition and the method thereof is also provided.
Thin cathode for micro-battery
Batteries include an anode, an electrolyte having a high solubility for lithium ions and oxygen, and a cathode formed on a substrate. Lithium ions migrate from the anode through the electrolyte to form Li.sub.2O.sub.2 at a surface of the cathode. A current collector positioned in the electrolyte, the electrolyte separating the anode from the cathode.
Thin cathode for micro-battery
Batteries include an anode, an electrolyte having a high solubility for lithium ions and oxygen, and a cathode formed on a substrate. Lithium ions migrate from the anode through the electrolyte to form Li.sub.2O.sub.2 at a surface of the cathode. A current collector positioned in the electrolyte, the electrolyte separating the anode from the cathode.
STABLE ALKALI AMIDE SOLUTIONS AND PROCESSES FOR PREPARING SAME
The object of the invention are solutions of alkali metal amides MNR.sup.1R.sup.2, wherein M is an alkali metal selected from Li, Na, K, Rb, Cs; R.sup.1 and R.sup.2 independently of one another are linear, branched or cyclic alkyl groups having 1 to 8 C atoms or together are a cycloalkyl radical, the alkali metal amides being present in methyltetrahydropyran or in a solvent mixture containing methyltetrahydropyran, and processes for their preparation.