Metal coordination complexes comprising at least one diazabutadiene based ligand having a structure represented by: ##STR00001## where A.sub.1, A.sub.2, A.sub.3, and A.sub.4 are atoms in a 6-membered ring and are independently selected from C, N, O, S, and P; and where R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, and R.sub.6 are independently selected from the group consisting of H, amino groups, C1-C6 alkyl groups, or C4-10 cycloalkyl groups; and further provided that alkyl groups may optionally contain silicon; and where the metal coordination complex is capable of participating in a Diels-Alder type reaction with a dienophile. Processing methods using the metal coordination complexes are also described.

In one aspect, phosphine compounds comprising three adamantyl moieties (PAd.sub.3) and associated synthetic routes are described herein. Each adamantyl moiety may be the same or different. For example, each adamantyl moiety (Ad) attached to the phosphorus atom can be independently selected from the group consisting of adamantane, diamantane, triamantane and derivatives thereof. Transition metal complexes comprising PAd.sub.3 ligands are also provided for catalytic synthesis including catalytic cross-coupling reactions.

The compound of the formula (1) and its complexes with metal cations are used for catalysis in hydroformylation processes. ##STR00001##

In one aspect, phosphine compounds comprising three adamantyl moieties (PAd.sub.3) and associated synthetic routes are described herein. Each adamantyl moiety may be the same or different. For example, each adamantyl moiety (Ad) attached to the phosphorus atom can be independently selected from the group consisting of adamantane, diamantane, triamantane and derivatives thereof. Transition metal complexes comprising PAd.sub.3 ligands are also provided for catalytic synthesis including catalytic cross-coupling reactions.

The present disclosure provides an organometallic compound below and an organic light emitting diode and an organic light emitting display device including the organometallic compound.

##STR00001##

Providing a novel organometallic complex represented by Structure Formula (G1). A.sup.1 to A.sup.4 independently represent an alkyl group having 1 to 6 carbon atoms or a cycloalkyl group having 3 to 6 carbon atoms. R.sup.1 to R.sup.5 independently represent any one of hydrogen, an alkyl group having 1 to 6 carbon atoms, a cycloalkyl group having 3 to 6 carbon atoms, and a cyano group, wherein at least one of R.sup.1 to R.sup.5 represents a cyano group. R.sup.11 to R.sup.14 independently represent an alkyl group having 2 to 6 carbon atoms or a cycloalkyl group having 3 to 6 carbon atoms. R.sup.15 and R.sup.16 independently represent any one of hydrogen, a methyl group, and an ethyl group. Note that R.sup.11 and R.sup.12 may be bonded to each other to form a ring, and R.sup.13 and R.sup.14 may be bonded to each other to form a ring.

##STR00001##

In one aspect, phosphine compounds comprising three adamantyl moieties (PAd.sub.3) and associated synthetic routes are described herein. Each adamantyl moiety may be the same or different. For example, each adamantyl moiety (Ad) attached to the phosphorus atom can be independently selected from the group consisting of adamantane, diamantane, triamantane and derivatives thereof. Transition metal complexes comprising PAd.sub.3 ligands are also provided for catalytic synthesis including catalytic cross-coupling reactions.

Provided are organometallic compounds. Also provided are formulations comprising these organometallic compounds. Further provided are OLEDs and related consumer products that utilize these organometallic compounds.

An ordered functional nanoporous material (OFMN) composition includes a pore defined by a sidewall, the sidewall comprising NCN linkages therein. A process for synthesis of a reagent includes the reaction of a 6,7-diaminoquinoxaline having R groups with hexaketocyclohexane (HKH) octahydrate, where R is independently in each occurrence H, Cl, Br, I, C.sub.4H.sub.4S (thiophenyl), SO.sub.3.sup., CO.sub.2.sup., CCH, CHCH.sub.2, NH.sub.2, OH, CN, C.sub.1-C.sub.4 alkyl, (CH.sub.2).sub.xCHCH.sub.2, or (CH.sub.2).sub.yCHCH(CH.sub.2).sub.z where x or (y+z) is an integer of 0 to 4 inclusive, (CH.sub.2).sub.jCHCH, or (CH.sub.2).sub.kCHC(CH.sub.2).sub.r where j or (k+r) 0 to 4 inclusive. A process of degasification that includes extracting a gas from a mixture by exposing the mixture to an OFNM to selectively pass the gas therethrough. A process of dehydrogenation includes exposing an aliphatically unsaturated feedstock to platinum modified OFNM under conditions to form hydrogen and selectively passing the hydrogen through the platinum modified OFNM.

A compound of Formula I

##STR00001##

having isoindoline moiety is disclosed. Their unique configuration of the fused rings enable the compound to exhibit phosphorescent emission in red color region to near infrared region and are useful as emitter materials in organic electroluminescence device.