The present disclosure relates to a Ziegler-Natta catalyst system with self-extinguishing properties suitable for olefin polymerization. The catalyst system of the present disclosure comprises a pro-catalyst, a co-catalyst, and an external donor having a mixture of a selectivity control agent and an activity control agent. The catalyst system of the present disclosure is adapted to prevent the temperature of the polymerization reaction to go beyond the softening temperature of the polymer, thereby exhibiting the self-extinguishing properties.

The present disclosure relates to a Ziegler-Natta catalyst system with self-extinguishing properties suitable for olefin polymerization. The catalyst system of the present disclosure comprises a pro-catalyst, a co-catalyst, and an external donor having a mixture of a selectivity control agent and an activity control agent. The catalyst system of the present disclosure is adapted to prevent the temperature of the polymerization reaction to go beyond the softening temperature of the polymer, thereby exhibiting the self-extinguishing properties.

The invention provides (meth)acrylic oligomers prepared from C1-C20 alkyl and C5-C20 cycloalkyl (meth)acrylates, wherein said oligomers have a Mn of about 300 g/mole to about 3,000 g/mole; a Mw of about 700 g/mole to about 6,000 g/mole; a Mz of about 900 g/mole to about 10,000 g/mole. The oligomers may have a Yellowness Index, according to ASTM E313 of less than 2. The oligomers of the invention are useful as tackifiers in adhesive compositions, but also are believed to be useful also in general polymer modification as plasticizers, leveling agents, viscosity reducers (i.e., rheology modifiers), and for increasing solids content in solvent-borne applications of all types with little detrimental impact on viscosity. The invention also provides adhesive compositions and laminate articles coated on at least one side with the adhesive compositions of the invention.

The invention provides (meth)acrylic oligomers prepared from C1-C20 alkyl and C5-C20 cycloalkyl (meth)acrylates, wherein said oligomers have a Mn of about 300 g/mole to about 3,000 g/mole; a Mw of about 700 g/mole to about 6,000 g/mole; a Mz of about 900 g/mole to about 10,000 g/mole. The oligomers may have a Yellowness Index, according to ASTM E313 of less than 2. The oligomers of the invention are useful as tackifiers in adhesive compositions, but also are believed to be useful also in general polymer modification as plasticizers, leveling agents, viscosity reducers (i.e., rheology modifiers), and for increasing solids content in solvent-borne applications of all types with little detrimental impact on viscosity. The invention also provides adhesive compositions and laminate articles coated on at least one side with the adhesive compositions of the invention.

A liquid composition is disclosed. The liquid composition comprises a silicone-acrylate polymer. The silicone-acrylate polymer comprises acrylate-derived monomeric units comprising siloxane moieties, optionally epoxide-functional moieties, and optionally, hydrocarbyl moieties. A method of preparing the silicone-acrylate polymer and the liquid composition is also disclosed.

A liquid composition is disclosed. The liquid composition comprises a silicone-acrylate polymer. The silicone-acrylate polymer comprises acrylate-derived monomeric units comprising siloxane moieties, optionally epoxide-functional moieties, and optionally, hydrocarbyl moieties. A method of preparing the silicone-acrylate polymer and the liquid composition is also disclosed.

A process for preparing a polydiene, the process comprising (i) preparing an active catalyst composition by combining a rare-earth compound including a rare-earth metal, an alkylating agent, an aluminoxane, and optionally a halogen-containing compound, where the catalyst composition includes halogen at molar ratio to the rare-earth metal of from about 0.5:1 to about 2.0:1; and (ii) introducing the active catalyst composition to conjugated diene monomer.

A process for preparing a polydiene, the process comprising (i) preparing an active catalyst composition by combining a rare-earth compound including a rare-earth metal, an alkylating agent, an aluminoxane, and optionally a halogen-containing compound, where the catalyst composition includes halogen at molar ratio to the rare-earth metal of from about 0.5:1 to about 2.0:1; and (ii) introducing the active catalyst composition to conjugated diene monomer.

Provided is a method for producing a fluoropolymer, the method including a polymerizing step of polymerizing tetrafluoroethylene in an aqueous medium in the presence of an initiator, a chain transfer agent, and a surfactant to provide a fluoropolymer containing more than 80 mol % of a polymerized unit based on tetrafluoroethylene, the chain transfer agent including at least one selected from the group consisting of a dithioester compound, a dithiocarbamate compound, a trithiocarbonate compound, and a xanthate compound. Also provided is a fluoropolymer represented by the formula Af-CRP defined in the description.

Provided is a method for producing a fluoropolymer, the method including a polymerizing step of polymerizing tetrafluoroethylene in an aqueous medium in the presence of an initiator, a chain transfer agent, and a surfactant to provide a fluoropolymer containing more than 80 mol % of a polymerized unit based on tetrafluoroethylene, the chain transfer agent including at least one selected from the group consisting of a dithioester compound, a dithiocarbamate compound, a trithiocarbonate compound, and a xanthate compound. Also provided is a fluoropolymer represented by the formula Af-CRP defined in the description.