Patent classifications
C08F8/14
Oxygen-absorbing resin composition and oxygen-absorbing multilayer body using same, and molded article and medical container using these
Provided is a novel oxygen-absorbing resin composition having excellent oxygen-absorbing performance and suppressing odor generation after absorption of oxygen even if a material responsive to a metal detector is not used. Further provided is an oxygen-absorbing resin composition having excellent oxygen-absorbing performance in a wide range of humidity conditions from low humidity to high humidity. Such an oxygen-absorbing resin composition contains a copolymerized polyolefin compound and a transition metal catalyst, in which the copolymerized polyolefin compound contains at least one constituent unit having a tetralin ring.
Oxygen-absorbing resin composition and oxygen-absorbing multilayer body using same, and molded article and medical container using these
Provided is a novel oxygen-absorbing resin composition having excellent oxygen-absorbing performance and suppressing odor generation after absorption of oxygen even if a material responsive to a metal detector is not used. Further provided is an oxygen-absorbing resin composition having excellent oxygen-absorbing performance in a wide range of humidity conditions from low humidity to high humidity. Such an oxygen-absorbing resin composition contains a copolymerized polyolefin compound and a transition metal catalyst, in which the copolymerized polyolefin compound contains at least one constituent unit having a tetralin ring.
Oxygen-absorbing resin composition and oxygen-absorbing multilayer body using same, and molded article and medical container using these
Provided is a novel oxygen-absorbing resin composition having excellent oxygen-absorbing performance and suppressing odor generation after absorption of oxygen even if a material responsive to a metal detector is not used. Further provided is an oxygen-absorbing resin composition having excellent oxygen-absorbing performance in a wide range of humidity conditions from low humidity to high humidity. Such an oxygen-absorbing resin composition contains a copolymerized polyolefin compound and a transition metal catalyst, in which the copolymerized polyolefin compound contains at least one constituent unit having a tetralin ring.
VINYL ALCOHOL POLYMER AND USE THEREOF
There is provided a vinyl alcohol-based polymer having an ethylenic double bond with a saponification degree of 70 mol % or more, wherein the vinyl alcohol-based polymer is water-soluble; a molar ratio of the ethylenic double bond to the total of vinyl alcohol units and vinyl acetate units is 0.05/100 to 2/100; and a limiting viscosity [η] and a weight-average molecular weight Mw of a vinyl ester-based polymer which is produced by esterifying the vinyl alcohol-based polymer satisfy the following formulas (1) and (2).
4.7≦log Mw 6.3 (1)
0.60<(log [η]+3.75)/log Mw<0.69 (2)
QUATERNARY AMMONIUM COMPOUNDS AND THEIR USE AS FUEL OR LUBRICANT ADDITIVES
A quaternary ammonium salt of formula wherein each of R.sup.1, R.sup.2, R.sup.3 and R.sup.4 is independently selected from an optionally substituted alkyl, alkenyl or aryl group having less than 8 carbon atoms and R.sup.5 is hydrogen or an optionally substituted hydrocarbyl group.
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QUATERNARY AMMONIUM COMPOUNDS AND THEIR USE AS FUEL OR LUBRICANT ADDITIVES
A quaternary ammonium salt of formula wherein each of R.sup.1, R.sup.2, R.sup.3 and R.sup.4 is independently selected from an optionally substituted alkyl, alkenyl or aryl group having less than 8 carbon atoms and R.sup.5 is hydrogen or an optionally substituted hydrocarbyl group.
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WATER-ABSORBENT RESIN AND ABSORBENT ARTICLE
Provided are: a water-absorbent resin which, when used as an absorbent material, retains a high water-absorption performance, increases the diffusivity of a to-be-absorbed liquid and makes it possible to effectively decrease the amount of re-wet; and an absorbent article formed using an absorbent material including the water-absorbent resin. The water-absorbent resin according to the present invention is a water-absorbent resin obtained by polymerizing a water-soluble ethylenically monomer in the presence of an internal-crosslinking agent and thereafter post-crosslinking the polymer with a post-crosslinking agent, characterized in that when subjected to a liquid flow test, the water-absorbent resin has an effective absorbent material index (K) indicated by equation (I) of 250 or greater.
Effective absorbent material index (K)=[(the amount of liquid flow) (g)]×[(artificial-urine absorption ratio) (g/g)] (I)
WATER-ABSORBENT RESIN AND ABSORBENT ARTICLE
Provided are: a water-absorbent resin which, when used as an absorbent material, retains a high water-absorption performance, increases the diffusivity of a to-be-absorbed liquid and makes it possible to effectively decrease the amount of re-wet; and an absorbent article formed using an absorbent material including the water-absorbent resin. The water-absorbent resin according to the present invention is a water-absorbent resin obtained by polymerizing a water-soluble ethylenically monomer in the presence of an internal-crosslinking agent and thereafter post-crosslinking the polymer with a post-crosslinking agent, characterized in that when subjected to a liquid flow test, the water-absorbent resin has an effective absorbent material index (K) indicated by equation (I) of 250 or greater.
Effective absorbent material index (K)=[(the amount of liquid flow) (g)]×[(artificial-urine absorption ratio) (g/g)] (I)
MODULAR SURFACE FUNCTIONALIZATION OF POLYISOBUTYLENE-BASED MATERIALS
A polymer composite includes a functionalized polyisobutylene and an additional polyisobutylene-containing material. One or more methods of making the polymer composite are also provided. Where the functionalized polyisobutylene is applied to a polyisobutylene-containing material, the method of applying the functionalized polyisobutylene compound can be described as a modular method.
Method for producing end-modified polybutadiene or end-modified hydrogenated polybutadiene and composition containing same
It is an object of the present invention to provide a method for producing a terminal-modified polybutadiene or terminal-modified hydrogenated polybutadiene that does not become colored or white and turbid, without using an organotin compound. The production method of the present invention includes reacting an acrylate or methacrylate represented by formula (I), a diisocyanate compound represented by formula (II), and a polybutadiene or hydrogenated polybutadiene having a hydroxyl group at a polymer terminal, represented by formula (III), in the presence of at least one selected from an organoaluminum compound and an organozinc compound (with the proviso that zinc naphthenate is excluded). ##STR00001##