C08F8/18

POLYMER PRODUCTION METHOD AND RADICAL POLYMERIZATION INITIATING GROUP-CONTAINING COMPOUND
20210261713 · 2021-08-26 ·

The present invention provides: a novel production technique that enables production of a polymer whose molecular weight and molecular weight distribution are controlled and production of a polymer having a complicated structure in a desirably controlled manner using commercially available materials without using a radical polymerization initiator or a special material for use in living radical polymerization and without the need for strict polymerization conditions; and a radical polymerization initiating group-containing compound for use in the technique. The present invention relates to: a method for producing a polymer, the method including a polymerization step of mixing and warming (1) a radically polymerizable monomer, (2) an organic compound wherein at least one group that functions as a group for initiating polymerization of the monomer and that has a structure represented by formula 1 or formula 2 (X in the formula represents Cl or Br) is introduced in a molecule of the organic compound, and (3) an iodine-containing compound, thereby initiating, from the group having the structure, radical polymerization accompanied by a termination reaction; and the organic compound of (2) for use in the method.

##STR00001##

POLYMER PRODUCTION METHOD AND RADICAL POLYMERIZATION INITIATING GROUP-CONTAINING COMPOUND
20210261713 · 2021-08-26 ·

The present invention provides: a novel production technique that enables production of a polymer whose molecular weight and molecular weight distribution are controlled and production of a polymer having a complicated structure in a desirably controlled manner using commercially available materials without using a radical polymerization initiator or a special material for use in living radical polymerization and without the need for strict polymerization conditions; and a radical polymerization initiating group-containing compound for use in the technique. The present invention relates to: a method for producing a polymer, the method including a polymerization step of mixing and warming (1) a radically polymerizable monomer, (2) an organic compound wherein at least one group that functions as a group for initiating polymerization of the monomer and that has a structure represented by formula 1 or formula 2 (X in the formula represents Cl or Br) is introduced in a molecule of the organic compound, and (3) an iodine-containing compound, thereby initiating, from the group having the structure, radical polymerization accompanied by a termination reaction; and the organic compound of (2) for use in the method.

##STR00001##

Anion exchange membranes and polymers for use in same

Embodiments of the invention relate generally to anion exchange membranes and, more particularly, to anion exchange membranes comprising a styrene block copolymer and methods for their manufacture. In one embodiment, the invention provides a polymer according to formula IV, wherein x and y are mol %, QA is or each of R.sub.1 and R.sub.2 is, independently, a linear alkyl chain or a cyclic alkyl chain, and Z is selected from a group consisting of: a linear alkyl chain, a cyclic alkyl chain, and an alkylene ether chain.

Anion exchange membranes and polymers for use in same

Embodiments of the invention relate generally to anion exchange membranes and, more particularly, to anion exchange membranes comprising a styrene block copolymer and methods for their manufacture. In one embodiment, the invention provides a polymer according to formula IV, wherein x and y are mol %, QA is or each of R.sub.1 and R.sub.2 is, independently, a linear alkyl chain or a cyclic alkyl chain, and Z is selected from a group consisting of: a linear alkyl chain, a cyclic alkyl chain, and an alkylene ether chain.

Halogen-containing synthetic base oils, and preparation method and use thereof

The present invention provides a class of halogen-containing synthetic base oils, and preparation method and use thereof. The synthetic base oils have introduced with halogen, especially fluorine, wherein the dipole motion of the halogen groups results in dipole interaction between the dipoles of other components and the base oil molecules of dipole-dipole and dipole-induced halogen (especially fluorine), and the interaction force is stronger and more localized than the dispersion force between the molecules of pure hydrocarbon synthetic oils, and thus the performance of the base oils is directly affected. It solved the problem of oil solubility of pure hydrocarbon synthetic oils, and also improved the properties of oxidation resistance and thermal stability.

Halogen-containing synthetic base oils, and preparation method and use thereof

The present invention provides a class of halogen-containing synthetic base oils, and preparation method and use thereof. The synthetic base oils have introduced with halogen, especially fluorine, wherein the dipole motion of the halogen groups results in dipole interaction between the dipoles of other components and the base oil molecules of dipole-dipole and dipole-induced halogen (especially fluorine), and the interaction force is stronger and more localized than the dispersion force between the molecules of pure hydrocarbon synthetic oils, and thus the performance of the base oils is directly affected. It solved the problem of oil solubility of pure hydrocarbon synthetic oils, and also improved the properties of oxidation resistance and thermal stability.

METHOD FOR MANUFACTURING GRAFT POLYMER, GRAFT POLYMER, AND INITIATOR OF GRAFT POLYMER

A method for manufacturing a graft polymer, that ensures more stable progress of a living radical polymerization by using a monomer structural unit containing an iodine initiating group as an initiator, includes performing a living radical polymerization of a compound with a vinyl monomer by an organic catalyst to manufacture the graft polymer. The compound has a recurring unit represented by a formula (1) below in a main chain:

##STR00001##

where, R.sup.1: linking group (linear, branched, or cyclic alkylene group having 1 to 30 carbon atoms that may contain an ether bond, an amide bond, or an ester bond, an aromatic group), R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6: an aromatic group, an aliphatic group, a hydrogen atom, an aliphatic group, and n=1 to 5.

METHOD FOR MANUFACTURING GRAFT POLYMER, GRAFT POLYMER, AND INITIATOR OF GRAFT POLYMER

A method for manufacturing a graft polymer, that ensures more stable progress of a living radical polymerization by using a monomer structural unit containing an iodine initiating group as an initiator, includes performing a living radical polymerization of a compound with a vinyl monomer by an organic catalyst to manufacture the graft polymer. The compound has a recurring unit represented by a formula (1) below in a main chain:

##STR00001##

where, R.sup.1: linking group (linear, branched, or cyclic alkylene group having 1 to 30 carbon atoms that may contain an ether bond, an amide bond, or an ester bond, an aromatic group), R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6: an aromatic group, an aliphatic group, a hydrogen atom, an aliphatic group, and n=1 to 5.

METHOD FOR MANUFACTURING GRAFT POLYMER, GRAFT POLYMER, AND INITIATOR OF GRAFT POLYMER

A method for manufacturing a graft polymer, that ensures more stable progress of a living radical polymerization by using a monomer structural unit containing an iodine initiating group as an initiator, includes performing a living radical polymerization of a compound with a vinyl monomer by an organic catalyst to manufacture the graft polymer. The compound has a recurring unit represented by a formula (1) below in a main chain:

##STR00001##

where, R.sup.1: linking group (linear, branched, or cyclic alkylene group having 1 to 30 carbon atoms that may contain an ether bond, an amide bond, or an ester bond, an aromatic group), R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6: an aromatic group, an aliphatic group, a hydrogen atom, an aliphatic group, and n=1 to 5.

RADIOPAQUE POLYMERS

A polymer having a backbone comprising a polyhydroxylated polymer cross linked by a C3 to C8 diacid.