The present invention is a modified resin for a molded article obtained by modifying an ethylene/unsaturated carboxylic acid copolymer with guanidine carbonate, wherein a melt flow rate of the ethylene/unsaturated carboxylic acid copolymer is 20 (g/10 minutes) or more and 600 (g/10 minutes) or less.

A system and method of producing polyethylene, including: polymerizing ethylene in presence of a catalyst system in a reactor to form polyethylene, wherein the catalyst system includes a first catalyst and a second catalyst; and adjusting reactor conditions and an amount of the second catalyst fed to the reactor to control melt index (MI), density, and melt flow ratio (MFR) of the polyethylene.

A system and method of producing polyethylene, including: polymerizing ethylene in presence of a catalyst system in a reactor to form polyethylene, wherein the catalyst system includes a first catalyst and a second catalyst; and adjusting reactor conditions and an amount of the second catalyst fed to the reactor to control melt index (MI), density, and melt flow ratio (MFR) of the polyethylene.

A terpolymer compositions made from or containing: A) From 80 wt % to 97 wt %; of a first propylene, ethylene, 1-butene terpolymer having: i) the content of ethylene derived units ranging from 0.5 wt % to 3.2 wt %; ii) the content of 1-butene derived units ranging from 7.2 wt % to 14.8 wt %; and B) From 20 wt % to 3 wt %; of a second propylene, ethylene, 1-butene terpolymer having: i) the content of ethylene derived units ranging from 0.5 wt % to 3.2 wt %; ii) the content of 1-butene derived units ranging from 14.4 wt % to 26.5 wt %; and the terpolymer composition having the melt flow rate, MFR, measured according to ISO 1133 at 230° C. with a load of 2.16 kg, ranging from 3.0 g/10 min to 20.0 g/10 min; the sum of the amounts of A) and B) being 100 wt %.

A terpolymer compositions made from or containing: A) From 80 wt % to 97 wt %; of a first propylene, ethylene, 1-butene terpolymer having: i) the content of ethylene derived units ranging from 0.5 wt % to 3.2 wt %; ii) the content of 1-butene derived units ranging from 7.2 wt % to 14.8 wt %; and B) From 20 wt % to 3 wt %; of a second propylene, ethylene, 1-butene terpolymer having: i) the content of ethylene derived units ranging from 0.5 wt % to 3.2 wt %; ii) the content of 1-butene derived units ranging from 14.4 wt % to 26.5 wt %; and the terpolymer composition having the melt flow rate, MFR, measured according to ISO 1133 at 230° C. with a load of 2.16 kg, ranging from 3.0 g/10 min to 20.0 g/10 min; the sum of the amounts of A) and B) being 100 wt %.

A method of determining multimodal polyethylene quality comprising the steps of (a) providing a multimodal polyethylene resin sample; (b) determining, in any sequence, the following: that the multimodal polyethylene resin sample has a melt index within 30% of a target melt index; that the multimodal polyethylene resin sample has a density within 2.5% of a target density; that the multimodal polyethylene resin sample has a dynamic viscosity deviation (% MVD) from a target dynamic viscosity of less than about 100%; that the multimodal polyethylene resin sample has a weight average molecular weight (M.sub.w) deviation (% M.sub.wD) from a target M.sub.w of less than about 20%; and that the multimodal polyethylene resin sample has a gel permeation chromatography (GPC) curve profile deviation (% GPCD) from a target GPC curve profile of less than about 15%; and (c) responsive to step (b), designating the multimodal polyethylene resin sample as a high quality resin.

Embodiments of polyethylene compositions and articles comprising polyethylene compositions are disclosed. The polyethylene compositions may include a first polyethylene fraction area defined by an area in the elution profile in a temperature range of 70° C. to 97° C. via improved comonomer composition distribution (iCCD) analysis method; a first peak in the temperature range of 70° C. to 97° C. in the elution profile; a second polyethylene fraction area defined by an area in the elution profile in a temperature range of 97° C. to 110° C.; and a second peak in the temperature range of 97° C. to 110° C. The polyethylene composition may have a density of 0.935 g/cm.sup.3 to 0.955 g/cm.sup.3 and a melt index (I.sub.2) of 1.0 g/10 minutes to 10.0 g/10 minutes. A ratio of the first polyethylene fraction area to the second polyethylene fraction area may be less than 2.0.

Embodiments of polyethylene compositions and articles comprising polyethylene compositions are disclosed. The polyethylene compositions may include a first polyethylene fraction area defined by an area in the elution profile in a temperature range of 70° C. to 97° C. via improved comonomer composition distribution (iCCD) analysis method; a first peak in the temperature range of 70° C. to 97° C. in the elution profile; a second polyethylene fraction area defined by an area in the elution profile in a temperature range of 97° C. to 110° C.; and a second peak in the temperature range of 97° C. to 110° C. The polyethylene composition may have a density of 0.935 g/cm.sup.3 to 0.955 g/cm.sup.3 and a melt index (I.sub.2) of 1.0 g/10 minutes to 10.0 g/10 minutes. A ratio of the first polyethylene fraction area to the second polyethylene fraction area may be less than 2.0.

##STR00001##

Embodiments of the present application are directed to procatalysts, and catalyst systems including procatalysts, including a metal-ligand complex having the structure of formula (I):

##STR00001##

Embodiments of the present application are directed to procatalysts, and catalyst systems including procatalysts, including a metal-ligand complex having the structure of formula (I):