C08F216/38

Composition for optical stereolithography, stereolithographic object, and method for producing the same

Provided is a composition for optical stereolithography the stereolithography (photocuring) of which is completed in a shorter time and which provides a stereolithographic object having excellent strength (strength that prevents the occurrence of a fracture and the like when the stereolithographic object is subjected to an impact, or dropping, and strength with which the stereolithographic object can withstand repeated folding). The composition for optical stereolithography of the present invention includes (A) a diallyl phthalate-based polymer; (B) radical polymerizable compounds having a methacrylic group and/or an acrylic group; (C) a radical polymerization initiator; and (D) a sensitizer. The (B) radical polymerizable compounds includes at least (B1) an epoxy (meth)acrylate having a methacrylic group and/or an acrylic group, or (B2) a dioxane (meth)acrylate having a methacrylic group and/or an acrylic group. The composition contains 0.5 to 10% by mass of (A), 5 to 43% by mass of (B1) and (B2), 20 to 95% by mass of (B) other than (B1) and (B2), 0.1 to 5% by mass of (C), and 0.1 to 5% by mass of (D).

Paper substrate comprising modified low molecular weight PVA with functional vinyl groups

The invention relates to a method for manufacturing a paper substrate suitable for binding silicone in a catalytic hydrosilation reaction and products thereof, wherein the molecular weight of polyvinyl alcohol is used to control the viscosity of the water-based acetalization reaction, such that a paper substrate may be coated with acetalized polyvinyl alcohol that contains high amount of functional vinyl groups, wherein the functional vinyl groups are part of catenated carbon structures which contain at least 4 carbon atoms and which have an acetal connectivity with the backbone chain of the acetalized polyvinyl alcohol.

Highly random addition bypolymers for destabilization of complex emulsions in crude oil blends

The present invention is related to the use of ethylene alkanoate-alkyl acrylate bipolymers with a high randomness monomers distribution, which are synthesized by semicontinuous emulsion polymerization process, characterized because it is carried out using slow addition rate of the pre-emulsion feeding ({dot over (q)}0.009 kgL.Math.L.sup.1.Math.min.sup.1), stabilized this last one by alkyl glycol ether type surfactants, at temperatures higher than 75 C. and with solids contents above 25 wt %, which avoids the formation of large sequences (blocks) of a same monomer. This structural characteristic gives the ethylene alkanoate-alkyl acrylate bipolymers a high efficiency as chemical agents for removal of complex water/crude oil emulsions of crude oil blends.

Highly random addition bypolymers for destabilization of complex emulsions in crude oil blends

The present invention is related to the use of ethylene alkanoate-alkyl acrylate bipolymers with a high randomness monomers distribution, which are synthesized by semicontinuous emulsion polymerization process, characterized because it is carried out using slow addition rate of the pre-emulsion feeding ({dot over (q)}0.009 kgL.Math.L.sup.1.Math.min.sup.1), stabilized this last one by alkyl glycol ether type surfactants, at temperatures higher than 75 C. and with solids contents above 25 wt %, which avoids the formation of large sequences (blocks) of a same monomer. This structural characteristic gives the ethylene alkanoate-alkyl acrylate bipolymers a high efficiency as chemical agents for removal of complex water/crude oil emulsions of crude oil blends.

PROCESS FOR TREATING KERATIN FIBRES WITH A PHOTOCROSSLINKABLE POLYVINYL ALCOHOL
20190343754 · 2019-11-14 ·

The invention relates to a cosmetic process for treating keratin fibres, comprising: (i) a step of applying to the keratin fibres a cosmetic composition containing a polyvinyl alcohol polymer comprising:an alcohol unitoptionally an acetate unita photocrosslinkable unita hydrophobic unit; (ii) a step of irradiating the composition on the keratin fibres to crosslink said polymer. The invention also relates to the novel polyvinyl alcohol polymer used in said process. The treated keratin fibres have good cosmetic properties in terms of a soft feel and disentangling, which properties are persistent after one or more shampoo washes.

PROCESS FOR TREATING KERATIN FIBRES WITH A PHOTOCROSSLINKABLE POLYVINYL ALCOHOL
20190343754 · 2019-11-14 ·

The invention relates to a cosmetic process for treating keratin fibres, comprising: (i) a step of applying to the keratin fibres a cosmetic composition containing a polyvinyl alcohol polymer comprising:an alcohol unitoptionally an acetate unita photocrosslinkable unita hydrophobic unit; (ii) a step of irradiating the composition on the keratin fibres to crosslink said polymer. The invention also relates to the novel polyvinyl alcohol polymer used in said process. The treated keratin fibres have good cosmetic properties in terms of a soft feel and disentangling, which properties are persistent after one or more shampoo washes.

HOT-WATER-STERILIZED PACKAGING AND METHOD FOR PRODUCING SAME
20190345280 · 2019-11-14 · ·

A hot-water sterilized package includes a container having a barrier layer filled with contents, wherein the barrier layer contains 96 mass % or more of a modified ethylene-vinyl alcohol copolymer based on the resin total, the modified ethylene-vinyl alcohol copolymer is represented by a following formula (I), contents (mol %) of a, b, and c based on the total monomer units satisfy following formulae (1) through (3), a degree of saponification (DS) defined by a following formula (4) is 90 mol % or more, and in measurement using a differential scanning calorimeter (DSC), crystalline melting enthalpy (H.sub.A: J/g) during temperature rise in a hydrated state and crystalline melting enthalpy (H.sub.B: J/g) during temperature rise after drying and melting followed by rapid cooling satisfy following formulae (5) and (6). A container constituting such a package has excellent in oxygen barrier properties even after hot-water sterilization, and thus degradation of content quality is inhibited for a long period.

##STR00001##


18a55(1)


0.01c20(2)


[100(a+c)]0.9b[100(a+c)](3)


DS=[(Total Number of Moles of Hydrogen Atoms in X,Y, and Z)/(Total Number of Moles of X,Y, and Z)]100(4)


H.sub.A/H.sub.B0.5(5)


H.sub.B70(6).

HOT-WATER-STERILIZED PACKAGING AND METHOD FOR PRODUCING SAME
20190345280 · 2019-11-14 · ·

A hot-water sterilized package includes a container having a barrier layer filled with contents, wherein the barrier layer contains 96 mass % or more of a modified ethylene-vinyl alcohol copolymer based on the resin total, the modified ethylene-vinyl alcohol copolymer is represented by a following formula (I), contents (mol %) of a, b, and c based on the total monomer units satisfy following formulae (1) through (3), a degree of saponification (DS) defined by a following formula (4) is 90 mol % or more, and in measurement using a differential scanning calorimeter (DSC), crystalline melting enthalpy (H.sub.A: J/g) during temperature rise in a hydrated state and crystalline melting enthalpy (H.sub.B: J/g) during temperature rise after drying and melting followed by rapid cooling satisfy following formulae (5) and (6). A container constituting such a package has excellent in oxygen barrier properties even after hot-water sterilization, and thus degradation of content quality is inhibited for a long period.

##STR00001##


18a55(1)


0.01c20(2)


[100(a+c)]0.9b[100(a+c)](3)


DS=[(Total Number of Moles of Hydrogen Atoms in X,Y, and Z)/(Total Number of Moles of X,Y, and Z)]100(4)


H.sub.A/H.sub.B0.5(5)


H.sub.B70(6).

Binder for power storage device electrode

The present invention aims to provide a binder for a power storage device electrode which favorably maintains adhesiveness between active materials in a long-term cycle, and which enables production of a high-capacity storage battery with a small irreversible capacity and low resistance to have excellent output characteristics. The present invention further aims to provide a composition for a power storage device electrode, a power storage device electrode, and a power storage device each prepared using the binder for a power storage device electrode. The present invention relates to a binder for a power storage device electrode used for an electrode of a power storage device, the binder containing a polyvinyl acetal resin, the polyvinyl acetal resin having a hydroxy group-containing structural unit of the formula (1) comprising a hydroxy group-containing structural unit with a sequence length of 1, the hydroxy group-containing structural unit with a sequence length of 1 constituting 25% by weight or less of the whole hydroxy group-containing structural unit in the polyvinyl acetal resin, the polyvinyl acetal resin having a hydroxy group content of 30 to 60 mol %: ##STR00001##

Binder for power storage device electrode

The present invention aims to provide a binder for a power storage device electrode which favorably maintains adhesiveness between active materials in a long-term cycle, and which enables production of a high-capacity storage battery with a small irreversible capacity and low resistance to have excellent output characteristics. The present invention further aims to provide a composition for a power storage device electrode, a power storage device electrode, and a power storage device each prepared using the binder for a power storage device electrode. The present invention relates to a binder for a power storage device electrode used for an electrode of a power storage device, the binder containing a polyvinyl acetal resin, the polyvinyl acetal resin having a hydroxy group-containing structural unit of the formula (1) comprising a hydroxy group-containing structural unit with a sequence length of 1, the hydroxy group-containing structural unit with a sequence length of 1 constituting 25% by weight or less of the whole hydroxy group-containing structural unit in the polyvinyl acetal resin, the polyvinyl acetal resin having a hydroxy group content of 30 to 60 mol %: ##STR00001##