Herein presented is a high electrical conductivity, uniform, material based on nanoparticles-Li.sup.+-polycarboxylate grafted few-layer graphene oxide including perovskite type nanoparticles for filler in polymeric matrices, in direct and reverse osmosis membranes, in lithium batteries, among others. The material is obtained by a method comprising the step of: preparation of a composite material having polymers with mono- or di-acid groups covalently bonded to graphene; optionally further comprising the preparation of a composite material with graphene covalently bonded to polymers having mono- or di-acid groups that have been replaced by lithium ion; and optionally further comprising the preparation of a composite material with graphene covalently bonded to polymers having mono- or di-acid groups that have been replaced by lithium ion in addition to grafted nanoparticles, including nanoparticles perovskite type.

Herein presented is a high electrical conductivity, uniform, material based on nanoparticles-Li.sup.+-polycarboxylate grafted few-layer graphene oxide including perovskite type nanoparticles for filler in polymeric matrices, in direct and reverse osmosis membranes, in lithium batteries, among others. The material is obtained by a method comprising the step of: preparation of a composite material having polymers with mono- or di-acid groups covalently bonded to graphene; optionally further comprising the preparation of a composite material with graphene covalently bonded to polymers having mono- or di-acid groups that have been replaced by lithium ion; and optionally further comprising the preparation of a composite material with graphene covalently bonded to polymers having mono- or di-acid groups that have been replaced by lithium ion in addition to grafted nanoparticles, including nanoparticles perovskite type.

The invention relates to an aqueous coating composition, comprising: a) an aqueous polymer dispersion with said polymer containing monomeric units of at least one dicarboxylic acid monomer, bearing two carboxylic acid functional groups and said polymer remaining insoluble in water after neutralization and remaining in the form of dispersed polymeric particles having a mean particle size varying from 10 to 1000 nm, b) a crosslinker selected from aminoacids bearing at least two amino functional groups capable of reacting with said carboxylic functional groups. It also relates to its use in the treatment of flexible fibrous substrates, a method for and the coated or treated fibrous substrate.

The invention relates to an aqueous coating composition, comprising: a) an aqueous polymer dispersion with said polymer containing monomeric units of at least one dicarboxylic acid monomer, bearing two carboxylic acid functional groups and said polymer remaining insoluble in water after neutralization and remaining in the form of dispersed polymeric particles having a mean particle size varying from 10 to 1000 nm, b) a crosslinker selected from aminoacids bearing at least two amino functional groups capable of reacting with said carboxylic functional groups. It also relates to its use in the treatment of flexible fibrous substrates, a method for and the coated or treated fibrous substrate.

Improved, micronutrient-supplemented polymeric seed coatings are provided which include at least one polyanionic polymer in combination with respective amounts of Zn, Mn, and Cu micronutrients. Preferably, the coatings comprise polyanionic polymers having a backbone comprising dicarboxylic repeat units with Zn, Mn, and Cu bound to the backbone. The most preferred polymers contain maleic and itaconic repeat units, optionally with sulfonate repeat units. The invention also provides a method of treating seeds using the coatings, and coated seed products.

A Polymer used as a treatment means, having an acid number greater than 100. The Polymer has a valent metal ion which is bonded to at least one reactive group. The characteristics of the Polymer include, conductivities of 4 S/cm to 200 S/cm or more, depending upon the concentration and nature of the metal bound. The conductivity proportional to the amount of metal bound, the ability of the Polymer to bind metals having a +1, +2, +3, +4, or +5 valence charge to the Polymer, and the ability to bind two or more different metals to separate binding sites on the Polymer.

A Polymer used as a treatment means, having an acid number greater than 100. The Polymer has a valent metal ion which is bonded to at least one reactive group. The characteristics of the Polymer include, conductivities of 4 S/cm to 200 S/cm or more, depending upon the concentration and nature of the metal bound. The conductivity proportional to the amount of metal bound, the ability of the Polymer to bind metals having a +1, +2, +3, +4, or +5 valence charge to the Polymer, and the ability to bind two or more different metals to separate binding sites on the Polymer.

Multi-piece golf balls containing a dual-layered core and dual-layered cover are provided. The core structure includes a small, heavy inner core (center) having a relatively high specific gravity, and a surrounding outer core layer. The core layers may have different hardness gradients. The center of the core comprises a metal material such as copper, steel, brass, tungsten, titanium, aluminum, and combinations and alloys thereof preferably dispersed in a thermoplastic polymeric matrix. The outer core layer is preferably formed from a thermoset composition such as polybutadiene. The multi-layered cores and covers have selective specific gravity relationships between the different layers. This helps provide the ball with good flight distance and spin control. The resulting balls have good resiliency and other playing performance properties.

Multi-piece golf balls containing a dual-layered core and dual-layered cover are provided. The core structure includes a small, heavy inner core (center) having a relatively high specific gravity, and a surrounding outer core layer. The core layers may have different hardness gradients. The center of the core comprises a metal material such as copper, steel, brass, tungsten, titanium, aluminum, and combinations and alloys thereof preferably dispersed in a thermoplastic polymeric matrix. The outer core layer is preferably formed from a thermoset composition such as polybutadiene. The multi-layered cores and covers have selective specific gravity relationships between the different layers. This helps provide the ball with good flight distance and spin control. The resulting balls have good resiliency and other playing performance properties.

The present invention provides a resin composition comprising the following resin (a) and filler particles. The use of this composition makes it possible to obtain a separator having excellent heat resistance. Resin (a): a copolymer comprising a structural unit represented by a formula (1) and a structural unit represented by a formula (2), ##STR00001##
wherein M.sup.n+ represents a metal ion, and n represents the valence thereof, ##STR00002##