Provided are novel cross-linked polymers and their use in various materials, including packaging films and injection molded articles. These polymers, which comprise certain hydroxyl-containing crosslinking compounds, as well as optionally adjuvants, show improved creep resistance when compared to conventional ethylene acrylic or methacrylic acid copolymers and their ionomers.

Provided are novel cross-linked polymers and their use in various materials, including packaging films and injection molded articles. These polymers, which comprise certain hydroxyl-containing crosslinking compounds, as well as optionally adjuvants, show improved creep resistance when compared to conventional ethylene acrylic or methacrylic acid copolymers and their ionomers.

The present disclosure relates to a formaldehyde-free aqueous curable composition comprising: A) a polymer polymerized from a monomer mixture comprising (a) 30-90 wt % of C.sub.1-C.sub.10 alkyl acrylate; (b) 10-60 wt % of vinylaromatics; (c) 0.5-10 wt % of an ethylenically unsaturated compound having at least two carboxylic acid groups; (d) 0-10 wt % of an ethylenically unsaturated acid having one carboxylic acid group; (e) 0-5 wt % of other ethylenically unsaturated monomers; wherein the percentages are based on the total weight of the monomer mixture; and B) a titanium catalyst.

The present disclosure relates to a formaldehyde-free aqueous curable composition comprising: A) a polymer polymerized from a monomer mixture comprising (a) 30-90 wt % of C.sub.1-C.sub.10 alkyl acrylate; (b) 10-60 wt % of vinylaromatics; (c) 0.5-10 wt % of an ethylenically unsaturated compound having at least two carboxylic acid groups; (d) 0-10 wt % of an ethylenically unsaturated acid having one carboxylic acid group; (e) 0-5 wt % of other ethylenically unsaturated monomers; wherein the percentages are based on the total weight of the monomer mixture; and B) a titanium catalyst.

This invention relates to a process for preparing succinic acid and succinate ester from a succinic acid salt in fermentation broth. In the first stage of this invention, renewable carbon resources are utilized to produce succinic acid through biological fermentation. The succinic acid salt in the fermentation process is subjected to double displacement reaction with a strong acid leading to release of succinic acid. Succinic acid is recovered by fractional crystallization integrated with simulated moving bed chromatography to produce succinic acid and succinate ester.

This invention relates to a process for preparing succinic acid and succinate ester from a succinic acid salt in fermentation broth. In the first stage of this invention, renewable carbon resources are utilized to produce succinic acid through biological fermentation. The succinic acid salt in the fermentation process is subjected to double displacement reaction with a strong acid leading to release of succinic acid. Succinic acid is recovered by fractional crystallization integrated with simulated moving bed chromatography to produce succinic acid and succinate ester.

Thermoformed articles comprising a film thermoformed to be in the form of a pouch defining an interior pouch volume, the film comprising a mixture of a polyvinyl alcohol resin and a plasticizer, wherein the plasticizer is provided in an amount in a range of about 5 to about 30 weight parts, based on 100 weight parts of total polyvinyl alcohol resin; wherein the thermoformed film in the form of a pouch defining an interior pouch volume is characterized by a draw ratio in a range of about 2.3 to about 2.9; the article is characterized by a release time of at least 30 seconds when formed into a sealed packet and tested in accordance with the Liquid Release Test; and the article is characterized by a residue value of at most 9%, as determined by the Residue Test.

Thermoformed articles comprising a film thermoformed to be in the form of a pouch defining an interior pouch volume, the film comprising a mixture of a polyvinyl alcohol resin and a plasticizer, wherein the plasticizer is provided in an amount in a range of about 5 to about 30 weight parts, based on 100 weight parts of total polyvinyl alcohol resin; wherein the thermoformed film in the form of a pouch defining an interior pouch volume is characterized by a draw ratio in a range of about 2.3 to about 2.9; the article is characterized by a release time of at least 30 seconds when formed into a sealed packet and tested in accordance with the Liquid Release Test; and the article is characterized by a residue value of at most 9%, as determined by the Residue Test.

A gypsum slurry includes water, a hydraulic component including calcium sulfate hemihydrate and a linear polycarboxylate dispersant. The linear polycarboxylate anionic dispersant includes a first monomeric repeating unit and a second monomeric repeating unit. The first repeating unit of the linear polycarboxylate dispersant is an olefinic unsaturated carboxylic acid repeating unit or salt thereof. The second repeating unit of the linear polycarboxylate dispersant is a vinyl sulfonate. The slurry can be made into a gypsum panel. Methods of making gypsum slurry and a gypsum panel are also disclosed.

A gypsum slurry includes water, a hydraulic component including calcium sulfate hemihydrate and a linear polycarboxylate dispersant. The linear polycarboxylate anionic dispersant includes a first monomeric repeating unit and a second monomeric repeating unit. The first repeating unit of the linear polycarboxylate dispersant is an olefinic unsaturated carboxylic acid repeating unit or salt thereof. The second repeating unit of the linear polycarboxylate dispersant is a vinyl sulfonate. The slurry can be made into a gypsum panel. Methods of making gypsum slurry and a gypsum panel are also disclosed.