Provided herein according to some embodiments is a dual cure additive manufacturing resin, comprising: (i) a light polymerizable component, (ii) a photoinitiator, (iii) a heat polymerizable component, and (iv) a non-reactive diluent, which resin is useful for the production of three-dimensional objects by additive manufacturing. Methods of using the same are also provided.

A photoinitiated polymerizable composition for 3D printing, the polymerizable composition comprising a nanogel component that comprises nanogel particles, wherein the nanogel particles comprise a copolymer with polymerizable reactive groups suitable for reacting with each other or a reactive diluent monomer, a reactive oligomer, a resin, or a combination thereof that is present in the polymerizable composition upon photoinitiation, wherein the nanogel component has a glass transition temperature that is in a range of about −50 C and about 20 C and an average molecular weight that is in a range of about 10 kg/mol and about 100 kg/mol, and wherein the nanoparticles have an average hydrodynamic radius that is in a range of 1 nm to about 5 nm.

A binder comprises a monomer and an initiator. The monomer comprises at least one of a difunctional monomer and a monofunctional monomer. A method of manufacturing a part includes depositing a layer of particulate material on a working surface; selectively applying a binder in at least one of an edge of the layer of particulate material and an infill pattern representative of a stress of the object; repeating the steps of depositing and selectively applying to form a plurality of layers of particulate material with the applied binder; and exposing the plurality of layers of particulate material with the applied binder to an excitation source to decompose the initiator and initiate polymerization of the monomer to thereby form the green body part.

The present invention provides a compound, a composition, a cured object, an optically anisotropic body, and a reflective film which have high refractive index anisotropy Δn and excellent light resistance, and which exhibit liquid crystallinity. The compound of the present invention is a compound represented by General Formula (1). ##STR00001##

The invention relates to a crosslinkable composition, which comprises a component a) at least one halogenated bisphenol A diglycidyl ether tetra(meth)acrylate and a component b) at least one diluent from mono(meth)acrylates of a monoalcohol comprising a biphenyl structure, and at least one optional component from components c), d), e), f) and g). It also relates to its use for coatings or materials, in particular for 3D printed articles for optical applications, as it also relates to the crosslinked composition and to the finished product, in particular the 3D article which results therefrom.

A photocurable composition includes a photopolymerizable component and a photopolymerization initiator. In a case in which a rectangular sheet-like test piece is produced by photomodeling under conditions in which the photocurable composition is irradiated with visible light having a wavelength of 405 nm at an irradiation dose of 12 mJ/cm.sup.2 to form a cured layer with a thickness of 50 .Math.m, the cured layer is stacked in a thickness direction thereof to form a rectangular sheet-like modeling product with a length of 40 mm, a width of 10 mm, and a thickness of 1 mm, and the modeling product is irradiated with ultraviolet rays having a wavelength of 365 nm at an irradiation dose of 10 J/cm.sup.2 to produce the test piece, the test piece has an X-ray absorption coefficient of from 9.0 cm.sup.-1 to 34.0 cm.sup.-1.

An aqueous emulsion is made by emulsion polymerizing at least one free-radically polymerizable monomer and one or more di- or higher-functional chain-extending monomers in the presence of an aqueous solution of an oligomer made from a mixture of free-radically polymerizable monomers including acid-functional free-radically polymerizable comonomers, adhesion-promoting free-radically polymerizable comonomers and other free-radically polymerizable comonomers. The aqueous emulsion is substantially free of adipic dihydrazide, has a minimum film forming temperature≤55° C., and on drying has a Koenig hardness of at least 40 sec.

Modelling material which includes (a) at least one radically polymerizable monomer, (b) at least one initiator for the radical polymerization and (c) at least one inert component. The inert component (c) is soluble in the polymer formed by polymerization of the monomer (a), wherein the solubility of component (c) decreases as the temperature increases, with the result that a phase separation takes place above a particular temperature. The material is suitable in particular for the production of models of dental restorations for investment casting processes.

Provided herein is a method of making a clear or translucent object by additive manufacturing, comprising (a) providing a clear or translucent light polymerizable resin, the resin comprising: (i) light-polymerizable monomers, prepolymers, or a combination thereof; (ii) a photoinitiator; and (iii) a polysubstituted linear polyacene ultraviolet light absorbing compound which compound is polysubstituted with bromo, chloro, —Se—R′, —S—R′ or combinations thereof, where each R′ is independently selected from alkyl, aryl, and arylalkyl; and then (b) producing by stereolithography with ultraviolet light a clear or translucent object from said light polymerizable resin.

Provided herein is a method of making a clear or translucent object by additive manufacturing, comprising (a) providing a clear or translucent light polymerizable resin, the resin comprising: (i) light-polymerizable monomers, prepolymers, or a combination thereof; (ii) a photoinitiator; and (iii) a polysubstituted linear polyacene ultraviolet light absorbing compound which compound is polysubstituted with bromo, chloro, —Se—R′, —S—R′ or combinations thereof, where each R′ is independently selected from alkyl, aryl, and arylalkyl; and then (b) producing by stereolithography with ultraviolet light a clear or translucent object from said light polymerizable resin.