C08F255/02

Process for Producing Modified Olefin Polymer in an Extruder

The present invention is directed to a process for producing a modified olefin polymer in an extruder having a feed zone, a melting zone, optionally a mixing zone and optionally a die zone, (A) introducing a stream of an olefin polymer into the feed zone of the extruder; (B) introducing a stream of a free radical generator directly into the feed zone or the melting zone or the mixing zone, if present, of the extruder; (C) introducing a stream of a functionally unsaturated compound directly into the feed zone or the melting zone or the mixing zone, if present, of the extruder; (D) extruding the mixture in the extruder at a temperature which is greater than the decomposition temperature of the free radical generator and the melting temperature of the olefin polymer but less than the decomposition temperature of the olefin polymer thereby producing the modified olefin polymer in the extruder; and, optionally, (G) passing the melt of the modified olefin polymer through the die zone to a pelletiser.

AMIDOXIME-FUNCTIONALIZED MATERIALS AND THEIR USE IN EXTRACTING METAL IONS FROM LIQUID SOLUTIONS

A method of producing a functionalized material that extracts metal ions from solution, the method comprising: (i) providing a precursor material having nitrile groups appended to its surface; and (ii) reacting said nitrile groups with hydroxylamine or a derivative thereof in the presence of a polar aprotic solvent at a temperature of 60-80° C. for at least 1 hour, to convert at least a portion of said nitrile groups to amidoxime and imide dioxime groups, followed by reaction with a base capable of hydrolyzing any remaining nitrile groups to carboxylic acid groups; wherein said functionalized material has a higher uranium absorption capacity than a functionalized material produced under same conditions except that the nitrile groups are reacted with hydroxylamine in only a protic solvent. The invention is also directed to functionalized materials produced by the above-described method, and methods for using the functionalized material for extracting metal ions from metal-containing solutions.

AMIDOXIME-FUNCTIONALIZED MATERIALS AND THEIR USE IN EXTRACTING METAL IONS FROM LIQUID SOLUTIONS

A method of producing a functionalized material that extracts metal ions from solution, the method comprising: (i) providing a precursor material having nitrile groups appended to its surface; and (ii) reacting said nitrile groups with hydroxylamine or a derivative thereof in the presence of a polar aprotic solvent at a temperature of 60-80° C. for at least 1 hour, to convert at least a portion of said nitrile groups to amidoxime and imide dioxime groups, followed by reaction with a base capable of hydrolyzing any remaining nitrile groups to carboxylic acid groups; wherein said functionalized material has a higher uranium absorption capacity than a functionalized material produced under same conditions except that the nitrile groups are reacted with hydroxylamine in only a protic solvent. The invention is also directed to functionalized materials produced by the above-described method, and methods for using the functionalized material for extracting metal ions from metal-containing solutions.

METHOD FOR PREPARING ACRYLIC ACID FROM BETA-PROPIOLACTONE

A method is for preparing acrylic acid from β-propiolactone and for using β-propiolactone. The process is based on a specific reactivity of β-propiolactone whereby acrylic acid is formed under operating conditions that are mild, especially in terms of temperature.

METHOD FOR PREPARING ACRYLIC ACID FROM BETA-PROPIOLACTONE

A method is for preparing acrylic acid from β-propiolactone and for using β-propiolactone. The process is based on a specific reactivity of β-propiolactone whereby acrylic acid is formed under operating conditions that are mild, especially in terms of temperature.

Thermoplastic elastomer composition and thermoplastic elastomer manufactured by using the same

A thermoplastic elastomer composition includes about 80 parts by weight of an ethylene propylene diene monomer (EPDM) including 5-ethylidene-2-norbornene (ENB) and polyethylene, about 30 parts by weight to about 70 parts by weight of polypropylene, about 20 parts by weight to about 40 parts by weight of a filler, and about 60 parts by weight to about 90 parts by weight of a plasticizer.

Thermoplastic elastomer composition and thermoplastic elastomer manufactured by using the same

A thermoplastic elastomer composition includes about 80 parts by weight of an ethylene propylene diene monomer (EPDM) including 5-ethylidene-2-norbornene (ENB) and polyethylene, about 30 parts by weight to about 70 parts by weight of polypropylene, about 20 parts by weight to about 40 parts by weight of a filler, and about 60 parts by weight to about 90 parts by weight of a plasticizer.

SILANE CROSSLINKABLE RUBBER COMPOSITION AND SILANE CROSSLINKED RUBBER MOLDED BODY, METHOD OF PRODUCING THE SAME, AND SILANE CROSSLINKED RUBBER MOLDED ARTICLE

A silane crosslinkable rubber composition having a silane crosslinkable rubber in which a silane coupling agent is grafted onto a base rubber containing 61 to 99 mass % of ethylene-α-olefin rubber and 1 to 39 mass % of polypropylene-based resin, and with respect to 100 parts by mass of the base rubber, 0.3 to 400 parts by mass of inorganic filler, and 0.0001 to 0.5 parts by mass of silanol condensation catalyst; a silane crosslinked rubber molded body obtained by bringing the rubber composition into contact with water after molding; a silane crosslinked rubber molded article including the rubber molded body; and a method of producing a silane crosslinkable rubber composition and a silane crosslinked rubber molded body.

SILANE CROSSLINKABLE RUBBER COMPOSITION AND SILANE CROSSLINKED RUBBER MOLDED BODY, METHOD OF PRODUCING THE SAME, AND SILANE CROSSLINKED RUBBER MOLDED ARTICLE

A silane crosslinkable rubber composition having a silane crosslinkable rubber in which a silane coupling agent is grafted onto a base rubber containing 61 to 99 mass % of ethylene-α-olefin rubber and 1 to 39 mass % of polypropylene-based resin, and with respect to 100 parts by mass of the base rubber, 0.3 to 400 parts by mass of inorganic filler, and 0.0001 to 0.5 parts by mass of silanol condensation catalyst; a silane crosslinked rubber molded body obtained by bringing the rubber composition into contact with water after molding; a silane crosslinked rubber molded article including the rubber molded body; and a method of producing a silane crosslinkable rubber composition and a silane crosslinked rubber molded body.

POLYOLEFIN/(METH)ACRYLIC COMPOSITE POLYMER COMPOSITION AND METHOD OF PREPARING SAME

A composite polymer composition comprising: the emulsion polymerization product of: (i) an aqueous polyolefin dispersion comprising the melt kneading product of one or more polyolefins, from 0.5 to 25 wt % of one or more dispersion stabilizing agents and water, and (ii) one or more (meth)acrylic monomers; wherein the one or more polyolefins have a Tg equal to or less than 50° C.; wherein the melt kneading product (i) comprises polymer particles having a volume average particle size between 50 nm and 2000 nm dispersed in the water; wherein the one or more dispersion stabilizing agents comprises a fatty acid or fatty acid salt stabilizing agent; and wherein the one or more (meth)acrylic monomers graft onto the polymer particles form composite polymer particles is provide. Also provided is a method of making the composition and impact modifiers comprising the composition.