Provided are method of producing a shaped fluoropolymer articles. The methods include subjecting a composition comprising a fluoropolymer to additive processing in an additive processing device. Also provided are articles obtained with the methods and 3D-printable compositions.

Provided are method of producing a shaped fluoropolymer articles. The methods include subjecting a composition comprising a fluoropolymer to additive processing in an additive processing device. Also provided are articles obtained with the methods and 3D-printable compositions.

A method for producing a molded article from a molding material, wherein the molding material contains a fluorine-containing graft chain. Also disclosed is a molding material for a fluorine-containing molded article including a resin material having a graft chain.

A method for producing a molded article from a molding material, wherein the molding material contains a fluorine-containing graft chain. Also disclosed is a molding material for a fluorine-containing molded article including a resin material having a graft chain.

A method for producing modified polytetrafluoroethylene including: polymerizing tetrafluoroethylene and a modifying monomer in an aqueous medium in the presence of a polymer (I) containing a polymerization unit (I) based on a monomer represented by the following general formula (I) to obtain a modified polytetrafluoroethylene:

CX.sup.1X.sup.3═CX.sup.2R(—CZ.sup.1Z.sup.2-A.sup.0).sub.m  (I)

wherein X.sup.1 and X.sup.3 are each independently F, Cl, H, or CF.sub.3; X.sup.2 is H, F, an alkyl group, or a fluorine-containing alkyl group; A.sup.0 is an anionic group; R is a linking group; Z.sup.1 and Z.sup.2 are each independently H, F, an alkyl group, or a fluorine-containing alkyl group; and m is an integer of 1 or more. Also disclosed is a composition containing the modified polytetrafluoroethylene and the polymer (I).

A method for producing modified polytetrafluoroethylene including: polymerizing tetrafluoroethylene and a modifying monomer in an aqueous medium in the presence of a polymer (I) containing a polymerization unit (I) based on a monomer represented by the following general formula (I) to obtain a modified polytetrafluoroethylene:

CX.sup.1X.sup.3═CX.sup.2R(—CZ.sup.1Z.sup.2-A.sup.0).sub.m  (I)

wherein X.sup.1 and X.sup.3 are each independently F, Cl, H, or CF.sub.3; X.sup.2 is H, F, an alkyl group, or a fluorine-containing alkyl group; A.sup.0 is an anionic group; R is a linking group; Z.sup.1 and Z.sup.2 are each independently H, F, an alkyl group, or a fluorine-containing alkyl group; and m is an integer of 1 or more. Also disclosed is a composition containing the modified polytetrafluoroethylene and the polymer (I).

The invention provides a fluorine-containing graft copolymer, and a preparation method and use thereof. The method includes the following steps: under a protective atmosphere, reacting a compound of Formula (I) and a compound of Formula (II) in a first organic solvent in the presence of a catalyst and a ligand at 20-30° C., to obtain the fluorine-containing graft copolymers of Formula (III) after complete reaction. The compounds of Formulas (I) and (II), and the fluorine-containing graft copolymer of Formula (III) have a structural formula shown below:

##STR00001##

##STR00002##

##STR00003##

and the compound of Formula (II) comprises a polyethylene glycol segment and a terminal alkynyl group, wherein a=4-8; b=6-8; n=1-20; and m=3-22. In the present invention, a graft copolymer of a main-chain-type “semi-fluorinated” alternating copolymer is obtained for the first time by post-polymerization modification using a reactive functional group contained in the main-chain-type “semi-fluorinated” alternating copolymers.

The invention provides a fluorine-containing graft copolymer, and a preparation method and use thereof. The method includes the following steps: under a protective atmosphere, reacting a compound of Formula (I) and a compound of Formula (II) in a first organic solvent in the presence of a catalyst and a ligand at 20-30° C., to obtain the fluorine-containing graft copolymers of Formula (III) after complete reaction. The compounds of Formulas (I) and (II), and the fluorine-containing graft copolymer of Formula (III) have a structural formula shown below:

##STR00001##

##STR00002##

##STR00003##

and the compound of Formula (II) comprises a polyethylene glycol segment and a terminal alkynyl group, wherein a=4-8; b=6-8; n=1-20; and m=3-22. In the present invention, a graft copolymer of a main-chain-type “semi-fluorinated” alternating copolymer is obtained for the first time by post-polymerization modification using a reactive functional group contained in the main-chain-type “semi-fluorinated” alternating copolymers.

The present invention is to provide a binder composition of a non-aqueous electrolyte secondary battery, which contains a vinylidene fluoride polymer and is capable of further enhancing adhesive strength of the electrode mixture layer to a surface of a current collector. The above objective can be achieved by a binder composition of a non-aqueous electrolyte secondary battery, the binder composition comprising a vinylidene fluoride copolymer for a binder of a non-aqueous electrolyte secondary battery, the vinylidene fluoride copolymer containing: a first constituent unit derived from vinylidene fluoride, and a second constituent unit containing an isocyanate group or having a structure that produces an isocyanate group when heated at 200° C. for 1 hour. This binder composition can be used in a mixture for producing an electrode for a non-aqueous electrolyte secondary battery, an electrode for a non-aqueous electrolyte secondary battery, and a non-aqueous electrolyte secondary battery.

The present invention is to provide a binder composition of a non-aqueous electrolyte secondary battery, which contains a vinylidene fluoride polymer and is capable of further enhancing adhesive strength of the electrode mixture layer to a surface of a current collector. The above objective can be achieved by a binder composition of a non-aqueous electrolyte secondary battery, the binder composition comprising a vinylidene fluoride copolymer for a binder of a non-aqueous electrolyte secondary battery, the vinylidene fluoride copolymer containing: a first constituent unit derived from vinylidene fluoride, and a second constituent unit containing an isocyanate group or having a structure that produces an isocyanate group when heated at 200° C. for 1 hour. This binder composition can be used in a mixture for producing an electrode for a non-aqueous electrolyte secondary battery, an electrode for a non-aqueous electrolyte secondary battery, and a non-aqueous electrolyte secondary battery.