A method for preventing hardener compounds to be formed from hardener precursors in an aerosol formulation suitable for use in aerosol for making a paint is disclosed.

The invention relates to a composition that is liquid at room temperature, can be fixed by radiation and cured by heat, comprising the following components: (A) an at least bifunctional epoxy-containing compound; (B) an at least bifunctional thiol; (C) a radiation-curable compound; (D) a photoinitiator; (E) a stabilizer blend that contains at least one sulfonyl isocyanate and at least one acid; and (F) a nitrogen compound as an accelerator. The compositions are processable at room temperature over a period of at least 24 h and can be completely cured even at low temperatures.

An amino-functional addition product from the reaction of at least one diamine of the formula (I) with at least one aromatic diepoxide in a stoichiometric ratio in the range of 1.3 to 1.7 mole diamine per 1 mole-equivalent of epoxy groups. The addition product is liquid at room temperature without a diluent and has surprisingly low viscosity. The composition allows the manufacture of low-emission epoxy-resin coatings that have good workability, cure particularly rapidly and with high surface quality in cold and damp conditions, and allow for a wide range of combinations with other amines and diluents.

Provided is a curative part usable in a two-part curable composition. The curative part includes a liquid amine; a heterogeneous dispersant; and core-shell rubber particles having an elastomeric core and a (meth)acrylic shell. The core-shell rubber particles and the heterogeneous dispersant can be collectively shear-dispersed in the liquid amine such that the core-shell rubber particles are substantially non-aggregated and the curative part is phase-stable over a period of at least 3 months at ambient temperature. Advantageously, large amounts of core-shell rubber particles can thus be incorporated into a cured resin matrix, which can afford significantly enhanced impact performance.

An amine-functional adduct from the reaction of an amine mixture containing at least one diamine of formula (I) and at least one diamine of formula (II) in a weight ratio ranging from 65/35 to 95/5 with at least one diepoxide in a stoichiometric ratio of at least 1. 2 moles of diamine of the formula (I) to 1 mole equivalent of epoxide groups. The adduct is liquid at room temperature without diluent even in the presence of a small excess of diamine and is surprisingly low in viscosity. In addition, it is particularly cost-effective, as it is available from an amine mixture that is technically easy to produce. The adduct enables low-emission or emission-free epoxy resin coatings with surprisingly good workability at surprisingly fast curing, which have a high hardness and low tendency to yellowing, and which hardly tend to blushing-related defects even in cold and humid conditions.

A curable epoxy resin adhesive including first and second amine curing agents each having a respective curing property determined by mixing the respective amine curing agent alone with a test epoxy resin to form a first or second curable mixture, and each curing property comprises a gel time when the curable mixture is at an ambient temperature of 25° C. and a peak exotherm temperature when the curable mixture is cured in air at a curing temperature of 70° C. A ratio between the first and second gel times is from 4-15:1 and the second amine curing agent has peak exotherm temperature is higher than the peak exotherm temperature of the first amine curing agent by a temperature Δt which is at least 2° C.

Disclosed herein are compositions including (a) a first component comprising (1) an epoxy-adduct that is the reaction product of reactants comprising a first epoxy compound, a polyol, and an anhydride and/or a diacid and (2) a second epoxy compound; (b) rubber particles having a core/shell structure and/or graphenic carbon particles; and (c) a second component that chemically reacts with the first component at ambient or slightly thermal conditions. Also disclosed herein are compositions including (a) an epoxy-capped flexibilizer; (b) a heat-activated latent curing agent; and optionally (c) rubber particles having a core/shell structure and/or graphenic carbon particles; (d) an epoxy/CTBN adduct; and/or (e) an epoxy/dimer acid adduct. The heat-activated latent curing agent may include at least one reaction product of reactants including an epoxy compound and an amine and/or an alkaloid.

A multifunctional surfacing material capable of providing lightning strike protection (LSP) and burn-through resistance. In one embodiment, the multifunctional surfacing material is composed of a conductive layer positioned between two resin layers, at least one of which contains one or more fire retardant compounds. In another embodiment, the multifunctional surfacing material is composed of a conductive layer positioned between two resin layers one of which is a thermally-stable layer. The surfacing material is co-curable with a composite substrate, e.g. prepreg or prepreg layup, which contains fiber-reinforced matrix resin.

A multifunctional surfacing material capable of providing lightning strike protection (LSP) and burn-through resistance. In one embodiment, the multifunctional surfacing material is composed of a conductive layer positioned between two resin layers, at least one of which contains one or more fire retardant compounds. In another embodiment, the multifunctional surfacing material is composed of a conductive layer positioned between two resin layers one of which is a thermally-stable layer. The surfacing material is co-curable with a composite substrate, e.g. prepreg or prepreg layup, which contains fiber-reinforced matrix resin.

A curing agent for epoxy resins, including 1-amino-3-aminomethyl-3,5,5-trimethylcyclohexane and N-benzyl-1,2-ethandiamine in an amount for the ratio of the number of its amine hydrogens to be in the range of 90/10 to 20/80. The curing agent permits suitable epoxy resin compositions that have excellent workability and that cure particularly rapidly in cold and damp conditions, without blushing-induced surface defects, thus achieving coatings of in particular high hardness, high glass transition temperature and surprisingly little tendency to yellowing.