Patent classifications
C08G64/18
POLYESTER ELASTOMER RESIN COMPOSITION
The present invention is a polyester elastomer resin composition that has excellent extrusion moldability and surface smoothness even in a thin shape, while maintaining mechanical characteristics, and that is halogen-free and has excellent flame retardancy as well as heat aging resistance and hydrolysis resistance. The polyester elastomer resin composition comprises a polyester elastomer (A) and a phosphorus flame retardant (B); the polyester elastomer (A) comprises a hard segment composed of a polyester and at least one soft segment selected from aliphatic polyethers, aliphatic polyesters, and aliphatic polycarbonates, and has a Shore D surface hardness of 55 or less; the phosphorus flame retardant (B) has an average particle size D50 of 20 μm or less and a phosphorus concentration of 15 mass % or more; and the polyester elastomer resin composition comprises 5 to 50 parts by mass of the phosphorus flame retardant (B) and optionally a predetermined amount of an acid end capping agent (C) based on 100 parts by mass of the polyester elastomer (A), and has an acid value of 10 eq/ton or less.
Polycarbonate-polyorganosiloxane copolymer and method for continuously producing same
Provided are a polycarbonate-polyorganosiloxane copolymer having a carbon tetrachloride concentration of less than 4 ppm by mass, and the following production method for producing the polycarbonate-polyorganosiloxane copolymer. More specifically, provided is a method of continuously producing a polycarbonate-polyorganosiloxane copolymer, the method comprising the steps of: (A) continuously or intermittently taking a polymerization reaction liquid, which is obtained by polymerizing a dihydric phenol compound, a carbonate precursor, and a specific polyorganosiloxane in the presence of an alkaline compound aqueous solution and a water-insoluble organic solvent, out of a reactor; (B) separating the polymerization reaction liquid taken out in the step (A) into an aqueous phase and a water-insoluble organic solvent phase; (C) washing the water-insoluble organic solvent phase separated in the step (B), followed by separation thereof into an aqueous phase and a water-insoluble organic solvent phase; (D) concentrating the water-insoluble organic solvent phase separated in the step (C); and (E) recovering part or all of the water-insoluble organic solvent removed by evaporation in the step (D), followed by distillation purification thereof in a distillation column, the water-insoluble organic solvent obtained in the step (E) being reused as at least part of the water-insoluble organic solvent in the step (A) or as an extraction solvent for the aqueous phase separated in the step (B), or as both thereof, in the step (E), the distillation purification being performed while a concentration of the polycarbonate-polyorganosiloxane copolymer in a column bottom liquid of the distillation column is controlled to 6% by mass or less.
Polysiloxane-polycarbonate block cocondensates
The present invention relates to polysiloxane-polycarbonate block cocondensates comprising particular rearrangement structures and having improved rheological properties and melt stability as well as to mouldings and extrudates made from these polysiloxane-polycarbonate block cocondensates.
Process for preparing polysiloxane-polycarbonate block cocondensates
The present invention relates to a process for preparing polysiloxane-polycarbonate block cocondensates proceeding from specific polycarbonates and hydroxyaryl-terminated polysiloxanes.
PROCESS FOR THE PREPARATION OF A BLOCK COPOLYMER COMPRISING A FIRST POLYOLEFIN BLOCK AND A SECOND POLYMER BLOCK AND THE PRODUCTS OBTAINED THEREFROM
The present invention relates to a process for the preparation of a block copolymer comprising a first type of polyolefin block and at least one type of second polymer block, the process comprising the steps of: A) polymerizing at least one type of olefin monomer using a catalyst system to obtain a first polyolefin block containing a main group metal on at least one chain end; the catalyst system comprising: i) a metal catalyst or metal catalyst precursor comprising a metal from Group 3-10 of the IUPAC Periodic Table of elements; and ii) at least one type of chain transfer agent; and iii) optionally a co-catalyst; B) reacting the first polyolefin block containing a main group metal on at least one chain end obtained in step A) with at least one type of oxidizing agent and subsequently at least one type of metal substituting agent to obtain a first polyolefin block containing at least one functionalized chain end; C) forming at least one second polymer block on the first polyolefin block, wherein as an initiator the functionalized chain end of the first polyolefin block obtained in step B) is used to obtain the block copolymer.
PROCESS FOR PRODUCING POLYCARBONATE
A method of producing a polycarbonate, including: introducing a tertiary amine into a reaction process; and performing interfacial polycondensation between an alkali aqueous solution of a dihydric phenol and phosgene in the presence of an organic solvent, in which: (i) a portion into which the tertiary amine is introduced comprises at least a tertiary amine storage tank, a tertiary amine supply pipe, and a diluent solvent supply pipe; (ii) the portion further includes a pressure control valve in the tertiary amine supply pipe on an upstream side of a merging portion with the diluent solvent supply pipe; and (iii) when a pressure P.sub.1 of an inside of the tertiary amine storage tank pressurized by a pressurization gas and a pressure P.sub.2 in a portion ranging from an outlet of the storage tank to an upstream side of the pressure control valve, a relationship of P.sub.1≦P.sub.2 is satisfied.
Process for preparing polysiloxane-polycarbonate block cocondensates using a salt of a weak acid
The present invention relates to a process for preparing polysiloxane-polycarbonate block cocondensates proceeding from specific polycarbonates and hydroxyaryl-terminated polysiloxanes in presence of a salt of a weak acid.
Preparation of siloxane-containing block copolycarbonates by means of reactive extrusion
The present invention relates to a process for preparing polysiloxane-polycarbonate block cocondensates proceeding from specific polycarbonates and hydroxyaryl-terminated polysiloxanes. More particularly, the present invention relates to the preparation of the said block cocondensates by means of a reactive extrusion.
PROCESS FOR PREPARING A POLYOXYALKYLENE CARBONATE POLYOL
The invention relates to a process for preparing a polyoxyalkylene carbonate polyol by reacting a polyoxyalkylene polyol with a cyclic carbonate in the presence of an amine catalyst. The invention further relates to polyoxyalkylene carbonate polyols obtainable using the method according to the invention and to a process for preparing polyurethanes by reacting the polyoxyalkylene carbonate polyols according to the invention with polyisocyanates.
POLYCARBONATE RESIN COMPOSITION AND MOLDED ARTICLE THEREOF
A polycarbonate resin composition which has excellent low-temperature impact resistance and flowability high enough to enable thin molding and provides a coated molded article having a good appearance and high impact resistance. The resin composition comprises 100 parts by weight of a resin component including a polycarbonate resin (component A) and a polycarbonate-polydiorganosiloxane copolymer resin (component B) and 0.5 to 2.5 parts by weight of a polyolefin resin (component C).