Patent classifications
C08G69/40
BETA-PEPTIDO SUGAR-COPOLYMER
There is provided a β-peptido sugar-copolymer having the structure of formula (I) as defined herein, or a stereoisomer, a tautomer, an N-oxide, a hydrate, a solvate, or a salt thereof, or a mixture of the same. There is provided a process to make the β-peptido sugar-copolymer as defined herein. There are further provided medical applications of the β-peptido sugar-copolymer as defined herein. In a preferred embodiment, a block-like copolymer poly(amido-D-glucose)-block-poly-β-(L)-homolysine (PDGu-b-PBLK) synthesized via anionic ring-opening polymerization (ROP) demonstrates an antimicrobial efficacy, an enhanced selectivity towards different bacteria, biocompatibility vs. mammalian cells and spontaneous assembly.
BETA-PEPTIDO SUGAR-COPOLYMER
There is provided a β-peptido sugar-copolymer having the structure of formula (I) as defined herein, or a stereoisomer, a tautomer, an N-oxide, a hydrate, a solvate, or a salt thereof, or a mixture of the same. There is provided a process to make the β-peptido sugar-copolymer as defined herein. There are further provided medical applications of the β-peptido sugar-copolymer as defined herein. In a preferred embodiment, a block-like copolymer poly(amido-D-glucose)-block-poly-β-(L)-homolysine (PDGu-b-PBLK) synthesized via anionic ring-opening polymerization (ROP) demonstrates an antimicrobial efficacy, an enhanced selectivity towards different bacteria, biocompatibility vs. mammalian cells and spontaneous assembly.
METHOD FOR PREPARING HIGH MOLECULAR WEIGHT FURAN POLYAMIDE
A method for preparing a high molecular weight furan polyamide includes the following steps: 1) charging dimethyl furan dicarboxylate and aliphatic diamine into a reaction container at equal molar weight, and increasing the temperature to 60-120° C. under inert gas; 2) adding a catalyst when the reaction system becomes transparent liquid, increasing the temperature to 140-150° C., and keeping at an atmospheric pressure or a pressure of 41-61 kPa for 0-1 h; and then increasing the temperature to 190-200° C. and reacting for 1-3 h; and 3) depressurizing the system to 3-16 kPa for 0-3 h; and finally, reducing the pressure to 0.003-0.100 KPa for 1-3 h to obtain the high molecular weight furan polyamide.
METHOD FOR PREPARING HIGH MOLECULAR WEIGHT FURAN POLYAMIDE
A method for preparing a high molecular weight furan polyamide includes the following steps: 1) charging dimethyl furan dicarboxylate and aliphatic diamine into a reaction container at equal molar weight, and increasing the temperature to 60-120° C. under inert gas; 2) adding a catalyst when the reaction system becomes transparent liquid, increasing the temperature to 140-150° C., and keeping at an atmospheric pressure or a pressure of 41-61 kPa for 0-1 h; and then increasing the temperature to 190-200° C. and reacting for 1-3 h; and 3) depressurizing the system to 3-16 kPa for 0-3 h; and finally, reducing the pressure to 0.003-0.100 KPa for 1-3 h to obtain the high molecular weight furan polyamide.
Polymer Composition For Waterproof-Breathable Films
A composition of: 75 to 98% by weight, relative to the weight of the composition, of at least one copolymer A containing polyamide blocks and polyether blocks; 2 to 15% by weight, relative to the weight of the composition, of at least one copolymer B including units derived from ethylene, from an alkyl (meth)acrylate and from a comonomer including at least one acid, anhydride or epoxide function; and 0 to 10% by weight, relative to the weight of the composition, of at least one additive. The polyether blocks of copolymer A include polyethylene glycol blocks. Further, a process for manufacturing a film and to said film.
Polymer Composition For Waterproof-Breathable Films
A composition of: 75 to 98% by weight, relative to the weight of the composition, of at least one copolymer A containing polyamide blocks and polyether blocks; 2 to 15% by weight, relative to the weight of the composition, of at least one copolymer B including units derived from ethylene, from an alkyl (meth)acrylate and from a comonomer including at least one acid, anhydride or epoxide function; and 0 to 10% by weight, relative to the weight of the composition, of at least one additive. The polyether blocks of copolymer A include polyethylene glycol blocks. Further, a process for manufacturing a film and to said film.
ELASTOMERIC ADDITIVE MANUFACTURING COMPOSITION
A composition useful for additive manufacturing is comprised of a thermoplastic elastomer blended with an aliphatic polyketone, wherein the thermoplastic elastomer is a continuous phase having dispersed therein separated domains of polyketone. The composition is useful for additive printing methods employing heating and extrusion of the composition to form extrudates that are printed an article comprised of fused layers of the composition. The composition facilitates the formation of extrusion based elastomeric additive manufactured articles.
Thermoplastic Composition
A composition including a particulate solid, a plastic material and a polymer represented by formula (1):
A-(B).sub.n (1)
wherein: A is a residue of a polyether having a polyether segment and 2 or 3 amine groups; wherein the polyether segment is derived from monomers of at least one of ethylene oxide, propylene oxide, or tetrahydrofuran; wherein the polyether segment has a number average molecular weight of from 160 to 2000; and wherein the amine groups are primary or secondary; each B is independently a residue of a C.sub.6-C.sub.50 fatty acid or fatty acid anhydride, which is linear or branched, and which is saturated or unsaturated; and n is 2 or 3; wherein each B is independently bound to A by an amide bond or a cyclic imide group. Methods of using, and use of, a polymer represented by the formula (1) as a dispersant in a composition further comprising a particulate solid and a plastic material.
LIGHT-SENSITIVE RESIN ORIGINAL PRINTING PLATE FOR LETTERPRESS PRINTING
A photosensitive resin printing original plate for letterpress printing having a photosensitive resin layer formed of a photosensitive resin composition containing at least a polymer compound (A), a dibasic acid diester (B) represented by the following general formula (I), a photopolymerizable compound (C), and a photopolymerization initiator (D), in which the content of the dibasic acid diester (B) in the photosensitive resin composition is 2.5 to 15 mass %:
##STR00001## (where R.sup.1 represents a divalent aliphatic hydrocarbon group having 2 to 8 carbon atoms, a divalent aromatic hydrocarbon group having 6 to 14 carbon atoms, or a divalent aliphatic cyclic hydrocarbon group having 4 to 14 carbon atoms, and R.sup.2 and R.sup.3 may be the same as or different from each other and each represents a linear or branched aliphatic hydrocarbon group having 1 to 12 carbon atoms).
LIGHT-SENSITIVE RESIN ORIGINAL PRINTING PLATE FOR LETTERPRESS PRINTING
A photosensitive resin printing original plate for letterpress printing having a photosensitive resin layer formed of a photosensitive resin composition containing at least a polymer compound (A), a dibasic acid diester (B) represented by the following general formula (I), a photopolymerizable compound (C), and a photopolymerization initiator (D), in which the content of the dibasic acid diester (B) in the photosensitive resin composition is 2.5 to 15 mass %:
##STR00001## (where R.sup.1 represents a divalent aliphatic hydrocarbon group having 2 to 8 carbon atoms, a divalent aromatic hydrocarbon group having 6 to 14 carbon atoms, or a divalent aliphatic cyclic hydrocarbon group having 4 to 14 carbon atoms, and R.sup.2 and R.sup.3 may be the same as or different from each other and each represents a linear or branched aliphatic hydrocarbon group having 1 to 12 carbon atoms).