Luminescent reporter compounds that are rotaxanes having the structure

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where BZC is a reporter molecule based on a squaraine type molecule, or similar reporter, and K is a macrocycle that encircles and interlocks with the reporter molecule. Applications of the reporter compounds are provided, as well as reactive intermediates used to synthesize the reporter compounds, and methods of synthesizing the reporter compounds.

Various embodiments of the present invention are directed to polyrotaxanes comprising a poloxamer core and at least one cyclodextrin and methods for treating Niemann-Pick type C (NPC) and imaging (e.g., MRI) using the polyrotaxanes various embodiments of the present invention.

A photochromic polyrotaxane compound which comprises an axial molecule and a plurality of cyclic molecules clathrating the axial molecule, wherein at least one side chain containing a photochromic moiety is bonded to at least one of the cyclic molecules, and a curable composition comprising the photochromic polyrotaxane compound and a polymerizable compound.

The present invention provides an adhered structure in which members of the same or different materials are adhered to each other with a high adhesive strength and a method for producing the adhered structure. The adhered structure of the present invention comprises a first solid member, a second solid member, and an adhesive member. The first solid member and the second solid member are adhered to each other through the adhesive member. The adhesive member contains a polymer. The polymer is chemically bonded to the first solid member and the second solid member.

A composition for a semiconductor encapsulant includes an epoxy resin, a curing agent, a filler, and a polyrotaxane, wherein the polyrotaxane includes a linear polymer A, an end group B, and a cyclic molecule C threaded through by the linear polymer. The cyclic molecule C has at least one functional group selected from the group consisting of an epoxy group, an oxetane group, and an alkoxysilyl group, or has a functional group capable of reacting with the at least one functional group.

Disclosed is a resin composition including a thermoplastic resin (A) and a polyrotaxane (B) whose cyclic molecule is modified with a graft chain having a reactive functional group at the end, which are mixed together, the resin composition containing a fibrous filler (C) in the amount of 1 to 200 parts by weight relative to 100 parts by weight of the total amount of the thermoplastic resin (A) and the polyrotaxane (B). To provide a resin composition capable of affording a molded article having excellent balance between rigidity and toughness.

The present disclosure provides a rotaxane polymer binder containing a polymer based on a rotaxane structure. The polymer binder may further contain a polymer cross-linked with a polar polymer. The polar polymer may be a polymer containing the element F, O or N in a functional group and having high polarity.

In addition, the present disclosure provides an electrode containing the rotaxane polymer binder as a binder for a lithium secondary battery, and a secondary battery containing the electrode.

The invention concerns a method for producing a three-dimensional object, in particular an artificial tooth, by stereolithography wherein a liquid photocurable resin composition is cured by light. Said photocurable resin composition contains, based on the total weight of the photocurable resin composition, (i) from 90 to 99.9% by weight of a radical polymerizable organic compound (A) selected from radical polymerizable monomers, oligomers, pre-polymers and mixtures thereof; and (ii) from 0.1 to 10% by weight of a photosensitive radical polymerization initiator (B). Said radical polymerizable organic compound (A) comprises, based on the weight of the radical polymerizable organic compound (A), from 0.5 to 20% by weight of a polyrotaxane compound comprising a polymer chain selected from polyethylene glycol (PEG), polypropylene glycol (PPG), polyethylene glycol-polypropylene glycol (PEG-PPG) block copolymer or polydimethylsiloxane (PDMS), onto which the cyclodextrin ring(s) is/are slipped and wherein the cyclodextrin is derivatized with at least a radical polymerizable group. The invention also concerns a relative liquid photocurable resin composition and articles produced thereby.

The present invention provides an optical composition from which an optical article having reduced poor appearance such as cloudiness and optical strain during lens base material production can be obtained, and when a photochromic compound is added, a photochromic cured body having excellent photochromism and mechanical strength can also be formed, and a polyrotaxane used therefor. The polyrotaxane has a composite molecular structure formed of an axle molecule and a plurality of cyclic molecules clathrating the axle molecule, satisfying at least one of (X) and (Y). (X): A side chain having a secondary or tertiary hydroxyl group is introduced into at least part of the cyclic molecule of the polyrotaxane. (Y): A side chain having a group represented by -A (A is an organic group, and contains at least one hydroxyl group) is introduced into at least part of the cyclic molecule of the polyrotaxane, and a pKa of the hydroxyl group of the compound represented by H-A is 6 or more and less than 14.

A new synthetic pathway for hyperbranched polyacrylates and polymethacrylates including the steps of preparing an inimer and polymerizing the inimer to form hyperbranched polymers or copolymers.