A multifunctional diffusion barrier comprising at least one organic polymer and a 2D graphene or 2D graphene derivative material and a method for preparing the multifunctional barrier. The multifunctional diffusion barrier can be used as a liquid and/or gas barrier, or as structural material, or as sealing material, or as a self-cleaning material or as protective material against UV radiation in aeronautical, automotive, marine or building field. The multifunctional diffusion barrier is suitable in producing parts of aircraft such as a fuel tank, a fuel tank conduit and a gasket.

An aluminum borate whisker reinforced and toughened non-metallic matrix composite is provided, which specifically includes a non-metallic material reinforced and toughened with aluminum borate whiskers. The composite exhibits a higher bending strength and fracture toughness and a higher wear resistance. A method for preparing the composite is also provided. The method includes mixing the aluminum borate whiskers and the non-metallic material to form a mixture; and sintering the mixture by a vacuum hot press method, or molding the mixture.

There is provided a piezoelectric composite comprising a piezoelectric polymer and particles of a filler dispersed in the polymer, wherein the filler is in micro or nanoparticle form and is present in a filler:polymer weight ratio between about 1:99 and about 95:5. There is also provided an ink and ink cartridge for 3D printing of the piezoelectric composite. There is also provided a piezoelectric 3D printed material comprising the piezoelectric composite and a bifunctional material comprising the piezoelectric composite with one or more conductive electrodes adjacent to the piezoelectric composite. Methods of manufacture and uses thereof are also provided, including methods for 3D printing of a piezoelectric 3D printed material via solvent-cast or FDM 3D printing starting from the piezoelectric composite and/or the ink.

There is provided a piezoelectric composite comprising a piezoelectric polymer and particles of a filler dispersed in the polymer, wherein the filler is in micro or nanoparticle form and is present in a filler:polymer weight ratio between about 1:99 and about 95:5. There is also provided an ink and ink cartridge for 3D printing of the piezoelectric composite. There is also provided a piezoelectric 3D printed material comprising the piezoelectric composite and a bifunctional material comprising the piezoelectric composite with one or more conductive electrodes adjacent to the piezoelectric composite. Methods of manufacture and uses thereof are also provided, including methods for 3D printing of a piezoelectric 3D printed material via solvent-cast or FDM 3D printing starting from the piezoelectric composite and/or the ink.

Compounds having an elastomer material, a filler material, at least one additive material, and at least one accelerant material are disclosed. In various embodiments, the filler material comprises a graphene-based carbon material. In various embodiments, the graphene-based carbon material comprises graphene comprising up to 15 layers, carbon aggregates having a median size from 1 to 50 microns, a surface area of the carbon aggregates at least 50 m.sup.2/g, when measured via a Brunauer-Emmett-Teller (BET) method with nitrogen as the adsorbate, and no seed particles.

Embodiments described herein can include a composition comprising a thermoset resin with a plurality of graphene flakes dispersed therein, each of the plurality of graphene flakes having a lateral dimension and a thickness. The composition further comprises a reinforcement material dispersed in the thermoset resin. At least about 90% of the plurality of graphene flakes are oriented such that the lateral dimension is within about 10 degrees of a parallel alignment with a horizontal plane. In some embodiments, at least about 95%, or at least about 99% of the plurality of graphene flakes are oriented such that the lateral dimension is within about 10 degrees of a parallel alignment with the horizontal plane. In some embodiments, the reinforcement material can include at least one of a plurality of fibers or a plurality of beads.

A monolithic thermocasting system for thermocasting polymer and solid material and method of use having an internal frame system; an external frame system disposed external to the internal frame system; a mold cavity formed between the internal frame system and the external frame system, the mold cavity sized to receive the polymer and solid material and shaped to form an architectural member; a duct; and a heater element disposed in the duct for outputting thermal energy to the mold cavity to heat the polymer and solid material, the thermal energy being sufficient to thermocast the polymer and solid material to a combined building material.

A method of producing an adhesive resin includes: a heating and kneading step of kneading a mixture containing a ring structure-containing hydrocarbon resin, an adhesive functional group-containing compound, and a peroxide while heating the mixture to obtain a heated and kneaded product; and a cooling and kneading step, performed in succession to the heating and kneading step, of kneading the heated and kneaded product while cooling the heated and kneaded product to obtain a cooled and kneaded product. The adhesive resin has a yellowness index (Yi) of 3.0 or less when 0.8 parts by mass of 2-(5-chloro-2-benzotriazolyl)-6-tert-butyl-p-cresol is added to 100 parts by mass of the adhesive resin.

A rubber composition is prepared by mixing a specific hydrazide compound at a ratio of 0.5 to 3.0 parts by mass, zinc oxide at a ratio of 1 to 5 parts by mass, and carbon black having N.sub.2SA of 60 to 150 m.sup.2/g at a ratio of 30 to 60 parts by mass per 100 parts by mass of diene rubber containing 80 parts by mass or more of natural rubber. The rubber composition is prepared through (a) mixing the hydrazide compound and the carbon black to obtain a mixture, and (b) mixing the zinc oxide with the mixture obtained in step (a) to obtain a mixture. A maximum ultimate temperature during the mixture in step (a) is from 140 to 170° C. A storage modulus and elongation at break have a specific relationship.

The present invention is a unique process of manufacturing rigid members with precise “shape keeping” properties and with reflective properties pertaining to radio frequency energy, so that air, land, sea and space devices or vehicles may be constructed including parabolic reflectors formed without discrete permanent layering. Rather, such parabolic reflectors or similarly, vehicles, may be formed by homogeneous construction where discrete layering is absent, and where energy reflectivity or scattering characteristics are embedded within the homogeneous mixture of carbon nanotubes and associated graphite powders and epoxy, resins and hardeners. The mixture of carbon graphite nanofiber and carbon nanotubes generates higher electrode conductivity and magnetized attraction through molecular polarization. In effect, the rigid members may be tuned based on the application. The combination of these materials creates a unique matrix that is then set in a memory form at a specific temperature, and then applied to various materials through a series of multiple layers, resulting in unparalleled strength and durability.