A dip-molded article includes an external molded layer and internal molded layer. The external molded layer includes a content of an ethylenically unsaturated nitrile-based monomer-derived repeating unit is 35 wt % to 60 wt %, and the internal molded layer in which a content of an ethylenically unsaturated nitrile-based monomer-derived repeating unit is 10 wt % to 28 wt %.

A method of preparing a carboxylic acid-modified nitrile-based copolymer latex is provided. The method of preparing a carboxylic acid-modified nitrile-based copolymer later includes emulsion-polymerizing a monomer mixture including a conjugated diene-based monomer, an ethylenically unsaturated nitrile-based monomer, and an ethylenically unsaturated acid monomer in the presence of a cross-linking agent including glyoxal.

A method of preparing a carboxylic acid-modified nitrile-based copolymer latex is provided. The method of preparing a carboxylic acid-modified nitrile-based copolymer later includes emulsion-polymerizing a monomer mixture including a conjugated diene-based monomer, an ethylenically unsaturated nitrile-based monomer, and an ethylenically unsaturated acid monomer in the presence of a cross-linking agent including glyoxal.

A composite particle includes a discrete, hollow, ceramic spheroid and a fluoropolymer layer disposed thereon. The fluoropolymer is a homopolymer or copolymer of a perfluoroalkyl vinyl ether; a perfluoroalkoxy vinyl ether; at least one fluoroolefin independently represented by formula C(R).sub.2═CF—Rf, wherein Rf is fluorine or a perfluoroalkyl having from 1 to 8 carbon atoms and R is hydrogen, fluorine, or chlorine; or a combination thereof. Methods of making the composite particles, composite materials, and articles including them are also disclosed.

A composite particle includes a discrete, hollow, ceramic spheroid and a fluoropolymer layer disposed thereon. The fluoropolymer is a homopolymer or copolymer of a perfluoroalkyl vinyl ether; a perfluoroalkoxy vinyl ether; at least one fluoroolefin independently represented by formula C(R).sub.2═CF—Rf, wherein Rf is fluorine or a perfluoroalkyl having from 1 to 8 carbon atoms and R is hydrogen, fluorine, or chlorine; or a combination thereof. Methods of making the composite particles, composite materials, and articles including them are also disclosed.

A glove according to the present invention includes a glove body configured to cover a hand of a wearer. The glove body has an outermost layer including a matrix resin and cellulose particles and constituting an outer surface of the glove. The outermost layer includes the cellulose particles in the range of more than 1 part to 9 parts or less by mass based on 100 parts by mass of the matrix resin. At least some of the cellulose particles are at least partially exposed from the outer surface.

A glove according to the present invention includes a glove body configured to cover a hand of a wearer. The glove body has an outermost layer including a matrix resin and cellulose particles and constituting an outer surface of the glove. The outermost layer includes the cellulose particles in the range of more than 1 part to 9 parts or less by mass based on 100 parts by mass of the matrix resin. At least some of the cellulose particles are at least partially exposed from the outer surface.

A latex composition for dip molding having an excellent flow mark property and syneresis property and being capable of providing a molded article having excellent tensile properties and texture is provided. A method of preparing the latex composition, and a dip-molded article produced using the latex composition are also provided.

The present invention relates to a latex composition for dip-forming including two different types of carboxylic acid modified-nitrile based copolymer latex, and a dip-formed article prepared therefrom having excellent durability for sweat, and having high tensile strength and elongation percentage. Accordingly, the latex composition for dip-forming has excellent tensile strength, elongation percentage, stress and durability, and is useful in industries requiring these, for example, a rubber glove industry and the like.

The present disclosure relates to a protective glove, which has different polymer layers arranged in a multi-layered polymer composite material. According to the present disclosure, the protective glove contains polyvinyl alcohol and a protective layer on top of this containing a fluorinated elastomer. The present disclosure also relates to a method for manufacturing a protective glove of this kind. The combination of various polymers and their arrangement in the polymer composite material achieve a powerful protective action against a multitude of chemical compound classes while simultaneously producing advantageous mechanical properties.