C08J5/04

POLYCARBONATE/POLYORGANOSILOXANE COPOLYMER AND RESIN COMPOSITION INCLUDING SAID COPOLYMER
20230052441 · 2023-02-16 · ·

Provided is a polycarbonate-polyorganosiloxane copolymer, which is produced by using a diol monomer (a1) and a polyorganosiloxane (a2) satisfying the following condition, including: a polyorganosiloxane block (A-1) including a specific repeating unit; and a polycarbonate block (A-2) formed of a specific repeating unit: a mixture, which is obtained by bringing the diol monomer (a1), the polyorganosiloxane (a2), a carbonic acid diester, and a basic catalyst present at the same amount ratio as that at a time of production of the polycarbonate-polyorganosiloxane copolymer into contact with each other at from 100° C. to 250° C. for from 0.5 hour to 5 hours, has a haze value of 30 or less measured under conditions of 23° C. and an optical path length of 10 mm in conformity with ISO 14782:1999.

THERMOSETTING RESIN COMPOSITION AND PREPREG, LAMINATE AND PRINTED CIRCUIT BOARD USING SAME
20230045848 · 2023-02-16 ·

Provided are a thermosetting resin composition and a prepreg, laminate and printed circuit board using same. The thermosetting resin composition comprises a resin component, the resin component comprising a modified cyclic olefin copolymer having a structure as shown in formula I and another unsaturated resin. By introducing a methacrylate end group having a certain polarity into a cyclic olefin copolymer, a modified cyclic olefin copolymer is formed. The modified cyclic olefin copolymer can form a thermosetting material by means of cross-linking with itself or another unsaturated resin, whereby the bonding property can be significantly improved while retaining the excellent dielectric properties of the cyclic olefin copolymer itself. The laminate prepared using the thermosetting resin composition has good dielectric properties, a good peel strength and a good heat resistance, and can meet all the performance requirements for printed circuit board substrates in the current high-frequency and high-speed communication field.

Method for producing a carbon fibre by recycling cotton

The invention concerns a method for producing a carbon fibre, that comprises a step of preparing a continuous fibre made of cellulose from cotton fabrics, by extracting, from these fabrics, cotton in the form of short, discontinuous fibres, and implementing a solvent spinning process; this step being followed by a step of carbonising said obtained continuous fibre made from cellulose, in order to form a carbon fibre. This carbon fibre can be used, in particular, for producing articles made from composite material made from carbon fibres and polymer organic resin.

Pre-impregnated fibre-reinforced composite material and manufactured article obtained by forming and complete curing of said pre-impregnated fibre-reinforced composite material

The invention relates to a pre-impregnated fibre-reinforced composite material in laminar form, obtained impregnating a fibrous mass with a polymeric binder composition and intended to be subjected to successive forming and complete curing operations to produce a fibre-reinforced composite material. The polymeric binder composition comprises one or more resins chosen in the group consisting of siloxane resins and silsesquioxane resins, and can optionally comprise one or more organic resins. The polymeric binder composition appears as a liquid with viscosity between 55000 and 10000 mPas at temperatures between 50° C. and 70° C. The polymeric binder composition forms a polymeric binder matrix, not cross-linked or only partially cross-linked, that fills the interstices of the fibrous mass. The invention also relates to a method for making said pre-impregnated fibre-reinforced composite material in laminar form. The invention also relates to a manufactured article obtained by hot forming and complete curing of the aforesaid pre-impregnated fibre-reinforced composite material, as well as a method for making said manufactured article.

Thermoplastic composition made from a polyamide polymer obtained from a prepolymer and a chain extender and manufacturing method

A composition including at least one polyamide polymer obtained from at least one reactive polyamide prepolymer including at least one chain extender (PA.sub.1-All.sub.1-PA.sub.1), the polyamide polymer being prepared at a temperature T.sub.1 no lower than the temperature melting temperature or glass transition temperature of the polymer and having a mean molecular weight Mn.sub.1. The composition has a melt viscosity which can be modulated according to the temperature to which the composition is exposed, wherein the temperature is between T.sub.2 and T.sub.3, T.sub.2 and T.sub.3 being higher than T.sub.1, and the melt viscosity η.sub.2 or η′.sub.3 observed at the temperature T.sub.2 or T.sub.3, respectively, being lower than the melt viscosity η.sub.2 or η.sub.3 of the polyamide polymer, which does not include a chain extender and has the same mean molecular weight Mn.sub.1(PA.sub.1) observed at the same temperature T.sub.2 or T.sub.3. The composition includes one or more polyamides.

Thermoplastic composition made from a polyamide polymer obtained from a prepolymer and a chain extender and manufacturing method

A composition including at least one polyamide polymer obtained from at least one reactive polyamide prepolymer including at least one chain extender (PA.sub.1-All.sub.1-PA.sub.1), the polyamide polymer being prepared at a temperature T.sub.1 no lower than the temperature melting temperature or glass transition temperature of the polymer and having a mean molecular weight Mn.sub.1. The composition has a melt viscosity which can be modulated according to the temperature to which the composition is exposed, wherein the temperature is between T.sub.2 and T.sub.3, T.sub.2 and T.sub.3 being higher than T.sub.1, and the melt viscosity η.sub.2 or η′.sub.3 observed at the temperature T.sub.2 or T.sub.3, respectively, being lower than the melt viscosity η.sub.2 or η.sub.3 of the polyamide polymer, which does not include a chain extender and has the same mean molecular weight Mn.sub.1(PA.sub.1) observed at the same temperature T.sub.2 or T.sub.3. The composition includes one or more polyamides.

Insertion of catalyst into dry carbon fibers prior to resin impregnation

Systems and methods are provided for fabrication of enhanced carbon fiber laminates that utilize encapsulated catalyst. One embodiment is a method that includes acquiring a batch of dry fibers, and acquiring a batch of catalyst capsules that each comprise catalyst that accelerates polymerization of monomers of a resin, and a shell that encapsulates the catalyst and liquefies at a curing temperature. The method further includes interspersing the catalyst capsules among the dry fibers, and impregnating the fibers with the resin after interspersing the catalyst capsules with the fibers.

Resin composite having excellent soundproofing and mechanical properties

Disclosed are a resin composite having excellent soundproofing and mechanical properties, and a molded product including the same. The resin composite may include a resin composition, porous particles and a reinforcing material, and the molded product including the same include no volatile organic compounds (VOCs). As consequence, displeasure caused by generation of the VOCs and exhaust of toxic gas during combustion may be reduced thereby being environmentally friendly. Further, the resin composite and the molded product including the same demonstrate sufficient mechanical strength and may thus be directly applied to a housing or the like of an apparatus which generates noise without introduction of any additional soundproofing material. For example, the resin composite and the molded product may include a specific content of the porous particles having pores having a specific size to secure an appropriate volume fraction and may thus efficiently and economically block noise transmission.

EPOXY RESIN COMPOSITION, PREPREG, AND FIBER REINFORCED COMPOSITE MATERIAL

An object of the present invention is to provide an epoxy resin composition that can be preferably used for prepreg and fiber reinforced composite material applications and is excellent in elastic modulus, strength, and pot life. The present invention is the epoxy resin composition including the following components [A] to [C] and satisfying the following conditions (1) to (4):

[A]: epoxy resin
[B]: aromatic diamine
[C]: a compound having a boiling point of 130° C. or more and a molecular weight m of 50 or more and 250 or less, the compound having no epoxy group in the molecule and having substantially no curing ability of an epoxy resin (1): the ratio H/E between the amount by mole, E, of the epoxy group in the component [A] and the amount by mole, H, of active hydrogen in the component [B] is 0.50 or more and 1.30 or less. (2): at least a part of the component [C] satisfies 0.10 or more and 0.60 or less in a ratio m/M of a molecular weight m thereof to a theoretical molecular weight between crosslinking points, M, of a cured product of the epoxy resin composition. (3): the ratio C/E of the amount by mole, E, for epoxy groups of the component [A] to the amount by mole, C, of the component [C] satisfying the condition (2) is 0.01 or more and 0.20 or less; and (4): the viscosity at 70° C. for 2 hours is 5.0 times or less the initial viscosity at 70° C.

RESIN COMPOSITION, MOLDED ARTICLE, MASTER BATCH, AND MANUFACTURING METHODS THEREFOR

The invention provides a thermoplastic resin composition, a molded article, and production methods therefor. The thermoplastic resin composition can sufficiently exhibit a cellulose addition effect and impart excellent mechanical strength to the molded article, particularly a foam molded article. More specifically, the invention provides a resin composition and a foam molded article thereof. The resin composition contains: a cellulose fiber (A); an amorphous resin (B) having a glass transition temperature of 160° C. or lower; a crystalline resin (C) having a melting point (melting peak temperature) of 80° C. to 150° C. and a melting start temperature lower than the melting point by 30° C. or more; and a thermoplastic resin (D) having a melting point or a glass transition temperature higher than the melting point of the crystalline resin (C) by 5° C. or more.