C08J11/02

Method for recovering ethylene and vinyl-based comonomer

The present invention relates to a method for recovering ethylene and a vinyl-comonomer that is capable of improving the rate of recovery of unreacted monomers remaining after polymerization of ethylene and a vinyl-based comonomer and increasing process efficiency through the reduction of costs. Specifically, the method for recovering ethylene and a vinyl-comonomer includes: a step of polymerizing ethylene and a vinyl-based comonomer at a pressure of 1500 bar or more; a step of depressurizing the product obtained in the polymerization step including an ethylene-vinyl-based comonomer polymer, ethylene, and a vinyl-based comonomer to 0.1 bar to 5 bar; a step of adding ethylene to the product obtained in the polymerization step under the pressure of 0.1 bar to 5 bar; and a step of separating ethylene and a vinyl-based comonomer from the product obtained in the polymerization step to which the ethylene is added.

Method for recovering ethylene and vinyl-based comonomer

The present invention relates to a method for recovering ethylene and a vinyl-comonomer that is capable of improving the rate of recovery of unreacted monomers remaining after polymerization of ethylene and a vinyl-based comonomer and increasing process efficiency through the reduction of costs. Specifically, the method for recovering ethylene and a vinyl-comonomer includes: a step of polymerizing ethylene and a vinyl-based comonomer at a pressure of 1500 bar or more; a step of depressurizing the product obtained in the polymerization step including an ethylene-vinyl-based comonomer polymer, ethylene, and a vinyl-based comonomer to 0.1 bar to 5 bar; a step of adding ethylene to the product obtained in the polymerization step under the pressure of 0.1 bar to 5 bar; and a step of separating ethylene and a vinyl-based comonomer from the product obtained in the polymerization step to which the ethylene is added.

Catalyst Complex and Method of Degradation of a Polymer Material

A catalyst complex for catalysis of degradation of a polymer material is described. Said complex comprises a magnetic particulate body containing iron oxide at its surface with an average diameter of 150-450 nm, and a plurality of catalytic groups grafted onto the iron oxide surface of the magnetic particulate body, which catalytic groups comprise a bridging moiety and a catalyst entity, wherein the bridging moiety comprises a functional group for adhesion or bonding to the iron oxide surface and a linking group towards the catalyst entity, and wherein the catalyst entity comprises a positively charged aromatic heterocycle moiety, and a negatively charged moiety for balancing the positively charged aromatic moiety.

Catalyst Complex and Method of Degradation of a Polymer Material

A catalyst complex for catalysis of degradation of a polymer material is described. Said complex comprises a magnetic particulate body containing iron oxide at its surface with an average diameter of 150-450 nm, and a plurality of catalytic groups grafted onto the iron oxide surface of the magnetic particulate body, which catalytic groups comprise a bridging moiety and a catalyst entity, wherein the bridging moiety comprises a functional group for adhesion or bonding to the iron oxide surface and a linking group towards the catalyst entity, and wherein the catalyst entity comprises a positively charged aromatic heterocycle moiety, and a negatively charged moiety for balancing the positively charged aromatic moiety.

Recovery of unreacted monomers from olefin polymerization processes
10526428 · 2020-01-07 · ·

A process, for recovery of unreacted olefin monomer(s) from a particulate product of an olefin polymerization reactor, the particulate polymer product is supplied to a degassing vessel, where the particulate product is countercurrently contacted with at least a first gaseous stripping stream, which includes at least 5% by weight unreacted olefin monomer, and then with an inert gas stream under conditions effective to strip hydrocarbon impurities from the polymer product and produce a stripped polymer product, is provided.

Recovery of unreacted monomers from olefin polymerization processes
10526428 · 2020-01-07 · ·

A process, for recovery of unreacted olefin monomer(s) from a particulate product of an olefin polymerization reactor, the particulate polymer product is supplied to a degassing vessel, where the particulate product is countercurrently contacted with at least a first gaseous stripping stream, which includes at least 5% by weight unreacted olefin monomer, and then with an inert gas stream under conditions effective to strip hydrocarbon impurities from the polymer product and produce a stripped polymer product, is provided.

Method for recovering solvent and cellulose in the production of cellulosic spun-bonded nonwoven fabrics

A plant (1) for the production of spunbonded nonwoven (8), comprising a spinning solution production (3), a spinning system (2), a device (6) for the delivery of coagulation liquid, at least one conveying device (7, 9) for depositing the spunbonded nonwoven (8), and a collecting device (13) for the spunbonded nonwoven (8), wherein at least one discharge device (14) is provided between the device (6) for the delivery of coagulation liquid and the collecting device (13) for the spunbonded nonwoven (8).

Method for recovering solvent and cellulose in the production of cellulosic spun-bonded nonwoven fabrics

A plant (1) for the production of spunbonded nonwoven (8), comprising a spinning solution production (3), a spinning system (2), a device (6) for the delivery of coagulation liquid, at least one conveying device (7, 9) for depositing the spunbonded nonwoven (8), and a collecting device (13) for the spunbonded nonwoven (8), wherein at least one discharge device (14) is provided between the device (6) for the delivery of coagulation liquid and the collecting device (13) for the spunbonded nonwoven (8).

PROCESS FOR THE RECOVERY AND RECYCLING OF UNREACTED MONOMER IN A SINGLE-STEP PROCESS FOR THE PRODUCTION OF A CARBON-FIBER PRECURSOR

A process for the recovery and recycling of unreacted monomer in a one-step process for the production of a carbon-fiber precursor. An integrated and improved single-step process for the production of a carbon-fiber precursor is also described, which starts from the co-monomers and reaches the spinning step obtaining the final precursor fiber, which provides for the recovery of the unreacted monomers at the end of the polymerization step and their recycling to the polymerization process itself.

METHODS FOR PRODUCING SYNTHETIC OLIGONUCLEOTIDES AND REMOVAL AGENTS FOR REMOVING IMPURITIES FROM ORGANIC WASH SOLVENTS USED IN OLIGONUCLEOTIDE SYNTHESIS

The present invention provides methods for utilizing blended compositions of acetonitrile and toluene as organic wash solvents in the production of a synthetic oligonucleotide, the blended compositions producing higher synthetic oligonucleotide yields than a pure acetonitrile wash solvent. The method also provides a process for removing one or more impurities from the acetonitrile and toluene containing wash solvent received as a waste stream from the oligonucleotide synthesis process. The process includes adding at least one of an iodine reactive compound, a sulfur reactive compound and/or an acidic reactive compound to the waste stream, and fractionating the waste stream. The fractionation produces an overhead fraction and a bottom fraction where the overhead fraction includes the acetonitrile and the toluene, and the bottom fraction includes the one or more impurities.