The invention described herein generally pertains to a composition and a method for improving the shelf life of a gaseous hydrofluoroolefin propellant, the improvement comprising at least the increased aromatic polyester polyol(s) in combination with a tertiary amine catalyst comprising at least two cyclohexyl rings and an aliphatic metal salt catalyst, the amine catalyst having less than 10% nitrogen on a weight basis.

The present invention relates to compositions for use in refrigeration, air-conditioning, and heat pump systems wherein the composition comprises a fluoroolefin and at least one other component. The compositions of the present invention are useful in processes for producing cooling or heat, as heat transfer fluids, foam blowing agents, aerosol propellants, and fire suppression and fire extinguishing agents.

An aerosol can configuration includes an outer can, an inner container and a spray head with a discharge element. The spray head has an outlet valve connected to the interior of the outer can and an outlet valve connected to the interior of the inner container. The two outlet valves are opened jointly by pressing on the spray head, so that the contents of the outer can and the contents of the inner container jointly enter the discharge element. To form a foam, the outer can contains at least 30-70% by weight isocyanate, in particular diphenylmethane 4,4-diisocyanate, 3-15% by weight polyol with an OH number of less than 300, and 5-30% by weight liquid gas at a critical temperature of +70 C. At least 5-30% by weight polyol with an OH number of more than 300, and 1-10% by weight liquid gas with a critical temperature of +70 C. are contained in the inner container.

The present application provides foams having improved insulation and thermal performance and processes of forming said foams. Exemplary foams described herein are prepared according to a process comprising reacting or extruding a foamable composition comprising (i) a compound selected from E-CHCl?CHCF.sub.3, ZCF.sub.3CH?CHCF.sub.3, and E-CF.sub.3CH?CHCF.sub.3, or any mixture thereof, and (2) a C.sub.5 hydrocarbon (e.g. cyclopentane), under conditions effective to form the foam.

A process for producing polyurethane foam by reacting at least one polyol component with at least one isocyanate component in the presence of at least one blowing agent and of one or more catalysts that catalyze the isocyanate-polyol and/or isocyanate-water reactions and/or the isocyanate trimerization, wherein the reaction is conducted in the presence of selected polyether-siloxane copolymers, is described.

An in-situ foaming system for forming a flame-retardant polyurethane foam in situ comprising a first liquid containing a polyisocyanate (A), a second liquid containing a polyol (B), a trimerization catalyst (C), a foaming agent (D), a foam stabilizer (E), and additives (F) comprising red phosphorus and at least one member selected from the group consisting of phosphoric acid esters, phosphate-containing flame retardants, bromine-containing flame retardants, boron-containing flame retardants, antimony-containing flame retardants, and metal hydroxides.

The present invention relates to compositions for use in refrigeration, air-conditioning, and heat pump systems wherein the composition comprises a fluoroolefin and at least one other component. The compositions of the present invention are useful in processes for producing cooling or heat, as heat transfer fluids, foam blowing agents, aerosol propellants, and fire suppression and fire extinguishing agents.

Two-component formulation for producing open-cell flexible foams having compressive strength of 1N/cm.sup.2, contained in 2-component aerosol can with crosslinker sleeve which can be opened prior to deploying formulation from aerosol can wherein the contents thereof enter aerosol can, wherein first component is present in aerosol can and second component that is reactive to first component is present separately in crosslinker sleeve and wherein aerosol can includes prepolymer composed of 25-35% by weight MDI and 40-55% by weight of polyol mixture having free isocyanate groups, and 10-21% by weight of propellant gas mixture and crosslinker sleeve includes 4-10% by weight of crosslinker mixture, wherein weight data are based on weight of formulation. Polyol mixture includes at least one trifunctional polyether and bifunctional polyester polyols, together with flame retardant, foam stabilizer, cell opener, amine catalyst, and crosslinker mixture including ethylene glycol in deficiency relative to free isocyanate groups and amine catalyst.

A catalyst for use in a rigid foaming system including an isocyanate and a halogenated olefinic blowing agent is described and a process for creating a rigid foaming system thereof. The catalyst can include a morpholine ring and a central N-alkyl group.

A two-component aerosol can for dispensing sealing and assembly foams based on isocyanates, having an outer pressure container which holds a prepolymer component and a propellant gas, the outer pressure container being in communication with a first valve device and with a first channel; an inner container which holds a curing component and a propellant gas, the inner container being in communication with a second valve device and with a second channel; and a spray head which comprises a device for simultaneously actuating the first and second valve devices; and a spray tube into which the first and second channels jointly open.