An expandable structural adhesive film for bonding metal parts. The adhesive film comprises at least one first epoxy compound; at least one epoxy curing agent; at least one blowing agent; at least one film-forming agent; and at least one impact modifier. The structural adhesive film exhibits an elongation at break of at least 300% according to tensile test DIN EN ISO 527 and a free expansion rate according to EN 2667-3 of at least 45%.

The present invention addresses the problem of providing a prepreg that has excellent short-time and low-pressure handling properties, during pasting and layering work. In order to solve the problem, this invention has the following configuration. The prepreg includes reinforcing fibers and an epoxy resin composition, has a fiber content of 90 mass % or less, and satisfies conditions (a) and (b) below. (a) When the average thickness of the prepreg is set as D (D being 3 μm or greater), the viscosity at 25° C. of the epoxy resin composition at a site (I) located at a depth of D/4 to 3D/4 from the surface on one side of the prepreg is 50,000 to 300,000 Pa.Math.s inclusive. (b) From among sites (II) located at a depth of up to 0.5 μm from each surface on both sides of the prepreg, the viscosity at 25° C. of the epoxy resin composition at least at a site (II) on the one side is 10,000 to 40,000 Pa.Math.s inclusive.

Provided is a sheet-like prepreg that has both a low coefficient of linear thermal expansion and high flexibility and offers excellent anti-warpage performance and cracking resistance. The sheet-like prepreg according to the present invention includes a curable composition and a sheet-like porous support impregnated with the curable composition. The sheet-like porous support is made from a material having a coefficient of linear thermal expansion of 10 ppm/K or less. The sheet-like prepreg gives a cured product having a glass transition temperature of −60° C. to 100° C. The curable composition includes one or more curable compounds (A) and at least one of a curing agent (B) and a curing catalyst (C). The curable compounds (A) include an epoxide having a weight per epoxy equivalent of 140 to 3000 g/eq in an amount of 50 weight percent or more of the totality of the curable compounds (A).

An object of the present invention is to provide a fiber-reinforced thermoplastic resin sheet which can be manufactured into a molded body exhibiting excellent appearance quality as well as exhibits both high moldability and strength and a manufacturing method of such a fiber-reinforced thermoplastic resin sheet. The present invention relates to a fiber-reinforced thermoplastic resin sheet which is a random laminated body of a tape-shaped unidirectional prepreg and contains spread reinforcement fibers and a polymer (a) and in which the polymer (a) is a polymer of at least a bisphenol A type epoxy compound represented by Formula (1): ##STR00001##
where n is an integer of 1 to 4
and a bisphenol compound selected from the group consisting of bisphenol A, bisphenol F, bisphenol S, bisphenol B, bisphenol E, and bisphenol P.

Provided is a method for producing a sheet molding compound including an aging step for thickening a sheet-like resin compound. The method includes applying a load of 0.2 to 50 g/cm.sup.2 to at least part of the sheet-like resin compound for 1 hour or more under a condition of an internal temperature of 20 to 120° C. in the aging step. A sheet molding compound obtained from this method for producing a sheet molding compound and its molded article have excellent carbon fiber impregnability and the like and can thus suitably be used for the exteriors, structures, and the like of automotive components, railway vehicle components, aerospace vehicle components, ship components, housing equipment components, sports components, light vehicle components, construction and civil engineering components, OA equipment, and the like.

Provided is a resin composition that exhibits satisfactory impregnability into reinforcing fibers, while having rapid curability, and that is suitable for fiber-reinforced composite materials producing molded articles having high heat resistance. A two-pack resin composition for fiber-reinforced composite materials is configured of a base material including an epoxy resin (A) and a (meth)acrylate compound (B) having three or more (meth)acryloyl groups in a molecule, and a curing agent including an amine compound (C) represented by the following general formula (1), a mass ratio of the base material to the curing agent being within the range of from 85:15 to 65:35, Wherein the epoxy resin (A) includes 75% by mass to 100% by mass of a bisphenol A epoxy resin; the base material has a viscosity of 10,000 mPa.Math.s or less; and the curing agent has a viscosity of 800 mPa.Math.s or less. X—(CH.sub.2NH.sub.2).sub.n (1) (In the formula, X represents an n-valent organic group having 1 to 16 carbon atom; and n represents 2 or 3).

This disclosure relates to a multilayer structure containing: a substrate; a coupling layer deposited on the substrate; and a dielectric layer deposited on the coupling layer, wherein shear strength is increased by a factor of at least about 2 in the presence of the coupling layer compared to a multilayer in the absence of the coupling layer.

A surface protect material is described that is high in UV resistance, able to protect the surface of the prepreg used as the parent material, able to prevent a fiber composite material from being deteriorated by UV, able to prevent defects during painting, able to serve for control of the resin flow, and is low in the volatilization percentage during curing, where the surface protect material is a coating agent for spraying or manual application comprising an epoxy resin composition containing at least the components [A] to [D]: [A] non-aromatic epoxy resin, [B] pigment having an number average particle size of 0.1 to 10 μm, [C] non-aromatic thermoplastic resin, and [D] cationic curing agent or anionic curing agent.

The present invention provides a prepreg from which a fiber-reinforced composite article in which interlayer peeling at the time of a point impact is suppressed can be obtained; a fiber-reinforced composite article; and a manufacturing method thereof.

An epoxy resin composition for fiber reinforced composite materials comprising components (A) to (E): component (A), an epoxy resin; component (B), a dicyandiamide or a derivative thereof; component (C), a polyisocyanate compound; component (D), a urea compound as represented by formula (1): ##STR00001##
(wherein R.sup.1 and R.sup.2 are each independently H, CH.sub.3, OCH.sub.3, OC.sub.2H.sub.5, NO.sub.2, halogen, or NH—CO NR.sup.3R.sup.4; and R.sup.3 and R.sup.4 are each independently a hydrocarbon group, allyl group, alkoxy group, alkenyl group, aralkyl group, or an alicyclic compound containing both R.sup.3 and R.sup.4, all containing 1 to 8 carbon atoms); and component (E), at least one compound selected from the group consisting of quaternary ammonium salts, phosphonium salts, imidazole compounds, and phosphine compounds.