C08J2479/04

RESIN COMPOSITION AND ARTICLE MADE THEREFROM
20220204746 · 2022-06-30 ·

A resin composition includes 100 parts by weight of a maleimide resin; 20 parts by weight to 60 parts by weight of a benzoxazine resin; 5 parts by weight to 40 parts by weight of an epoxy resin; 120 parts by weight to 240 parts by weight of silica including spherical silica having a sediment volume of less than or equal to 0.4 mL/g and a particle size distribution D50 of less than or equal to 1.0 μm; and 0.5 part by weight to 1.6 parts by weight of an imidazole compound having a long-chain alkyl group, wherein the imidazole compound having a long-chain alkyl group includes octylimidazole, undecylimidazole, heptadecylimidazole or a combination thereof. The resin composition may be used to make a prepreg, a resin film, a laminate or a printed circuit board, and at least one of the following improvements can be achieved, including glass transition temperature, ratio of thermal expansion, copper foil peeling strength, thermal resistance after moisture absorption, dissipation factor, amount of resin cluster and appearance of cooper-free circuit board.

ADDITIVE MIXTURES FOR RHEOLOGY MODIFICATION OF POLYMERS

A mixture can be used for modifying the rheology of polymeric substrates. The mixture contains a hydroxylamine ester and an isocyanate functionalized with a thio compound.

Heat-curable resin composition, prepreg, and fiber-reinforced composite material

A thermosetting resin composition at least including: [A] an epoxy resin containing two or more glycidyl groups; [B] a cyanate ester resin containing two or more cyanate groups; and [C] an amine compound; and satisfying the following conditions (1) and (2): (1) 0.25≤the number of moles of glycidyl groups in the thermosetting resin composition/the number of moles of cyanate groups in the thermosetting resin composition≤1.5; and (2) 0.05≤the number of moles of active hydrogen contained in the amino groups in the thermosetting resin composition/the number of moles of cyanate groups in the thermosetting resin composition<0.5; and a prepreg and a fiber reinforced composite material using the thermosetting resin composition. Provided are a thermosetting resin composition having excellent mechanical properties and heat resistance in a high-temperature environment after moisture absorption, and having excellent reactivity that allows curing in a short time; a prepreg prepared by impregnating a reinforced fiber with a thermosetting resin composition, which prepreg has excellent handling ability (tackiness properties) at room temperature; and a fiber reinforced composite material including a thermosetting resin composition and a reinforced fiber.

Resin composition for semiconductor package, prepreg and metal clad laminate using the same

The present invention relates to a resin composition having a high flow property, low thermal expansion characteristics, and excellent mechanical properties, and a prepreg and a metal clad laminate formed from the same.

Energy self-sufficient high-efficiency photo-thermal evaporative nano-particle porous membrane, preparation method and application thereof

Disclosed are an energy self-sufficient high-efficiency photothermal evaporative nano-particle porous membrane and application thereof, including: dissolving polymer A in solvent B to obtain solution A; dripping solution A into solvent C to obtain a polymer A nano hydrogel dispersion; evenly mixing polymer A nano hydrogel dispersion and nano particle dispersion of photothermal conversion material D to obtain a co-blended dispersion; performing suction-filtering to the co-blended dispersion on a surface of a solvent-resistant membrane E to form an A-D co-blended membrane; and performing suction-filtering to a solvent F using the A-D co-blended membrane, followed by drying to obtain a high-efficiency photothermal evaporative nano-particle porous membrane.

BENZOXAZINE RESIN COMPOSITION, PREPREG, AND FIBER-REINFORCED COMPOSITE MATERIAL
20220289921 · 2022-09-15 · ·

A curable benzoxazine resin composition for a fiber-reinforced composite material is provided which contains at least a component [A], a component [B], and a component [C]. The component [A] includes at least one multifunctional benzoxazine resin having a non-hydrocarbon linkage such as carbonyl, oxygen, sulfur, sulfone or sulfoxide between aromatic moieties. The component [B] includes at least one multifunctional benzoxazine resin having a direct bond or a hydrocarbon linkage between aromatic moieties. The component [C] includes at least one cycloaliphatic epoxy resin containing at least two epoxy groups which are part of cycloaliphatic rings. The curable benzoxazine resin composition is useful in the molding of fiber-reinforced composite materials. More particularly, the curable benzoxazine resin composition makes possible a fiber-reinforced composite material where the cured material obtained by heating has superior performance in extreme use environments, such as high temperature and high compressive load.

CROSS-LINKED HIGH STABLE ANION EXCHANGE BLEND MEMBRANES WITH POLYETHYLENEGLYCOLS AS HYDROPHILIC MEMBRANE PHASE
20220212183 · 2022-07-07 ·

The invention relates to:—anion exchange blend membranes consisting the following blend components:—a halomethylated polymer (a polymer with —(CH2)x—CH2—Hal groups, Hal=F, CI, Br, I; x=0-12), which is quaternised with a tertiary or a n-alkylated/n-arylated imidazole, an N-alkylated/N-arylated benzimidazole or an N-alkylated/N-arylated pyrazol to form an anion exchanger polymer. - an inert matrix polymer in which the anion exchange polymer is embedded and which is optionally covalently crosslinked with the halomethylated precursor of the anion exchanger polymer,—a polyethyleneglycol with epoxide or halomethyl terminal groups which are anchored by reacting with N—H-groups of the base matrix polymer using convalent cross-linking—optionally an acidic polymer which forms with the anion-exchanger polymer an ionic cross-linking (negative bound ions of the acidic polymer forming ionic cross-linking positions relative to the positive cations of the anion-exchanger polymer)—optionally a sulphonated polymer (polymer with sulphate groups —SO2Me, Me=any cation), which forms with the halomethyl groups of the halomethylated polymer convalent crosslinking bridges with sulfinate S-alkylation. The invention also relates to a method for producing said membranes, to the use of said membranes in electrochemical energy conversion processes (e.g. Redox-flow batteries and other flow batteries, PEM-electrolyses, membrane fuel cells), and in other membrane methods (e.g. electrodialysis, diffusion dialysis).

Prepreg, metal-clad laminate and printed wiring board

Disclosed herein is a prepreg including a woven fabric base and a semi-cured product of a resin composition impregnated into the woven fabric base. The resin composition contains a maleimide resin as Component (A), an acrylic resin as Component (B), and a phenol resin as Component (C). The Component (B) has a weight average molecular weight falling within the range from 200,000 to 850,000.

Cross-linked high stable anion exchange blend membranes with polyethyleneglycols as hydrophilic membrane phase
11278879 · 2022-03-22 ·

The invention relates to: —anion exchange blend membranes consisting the following blend components: —a halomethylated polymer (a polymer with —(CH.sub.2).sub.x—CH.sub.2—Hal groups, Hal=F, Cl, Br, I; x=0-12), which is quaternised with a tertiary or a n-alkylated/n-arylated imidazole, an N-alkylated/N-arylated benzimidazole or an N-alkylated/N-arylated pyrazol to form an anion exchanger polymer. —an inert matrix polymer in which the anion exchange polymer is embedded and which is optionally covalently crosslinked with the halomethylated precursor of the anion exchanger polymer, —a polyethyleneglycol with epoxide or halomethyl terminal groups which are anchored by reacting with N—H-groups of the base matrix polymer using covalent cross-linking—optionally an acidic polymer which forms with the anion-exchanger polymer an ionic cross-linking (negative bound ions of the acidic polymer forming ionic cross-linking positions relative to the positive cations of the anion-exchanger polymer)—optionally a sulphonated polymer (polymer with sulphate groups —SO.sub.2Me, Me=any cation), which forms with the halomethyl groups of the halomethylated polymer covalent crosslinking bridges with sulfinate S-alkylation. The invention also relates to a method for producing said membranes, to the use of said membranes in electrochemical energy conversion processes (e.g. Redox-flow batteries and other flow batteries, PEM-electrolyses, membrane fuel cells), and in other membrane methods (e.g. electrodialysis, diffusion dialysis).

LAMINATED FILM

The invention provides a laminated film containing at least a base material layer, a covering layer, and an inorganic thin-film layer in this order, wherein (a) the base material layer comprises a resin composition that contains at least 70 mass % of polybutylene terephthalate resin; (b) the laminated film has a piercing strength of 0.6 N/μm or more as measured in accordance with JIS Z 1707 after having undergone a 95° C.-boiling treatment for 30 minutes; (c) the base material layer has a surface orientation degree of 0.144-0.160; and (d) when the value of oxygen transmission rate obtained by measuring the laminated film under a 23° C.×65% RH condition is defined as (A) and the value of oxygen transmission rate obtained by measuring same under a 40° C.×90% RH condition is defined as (B), the barrier value deterioration rate of the laminated film, as calculated as (B/A)×100, is 300% or less.