The present invention concerns methods of forming a three-dimensional object, and polymerizable liquids such as dual cure resins useful for making a three-dimensional object by sterolithography, such as by continuous liquid interface production (CLIP).

The present invention concerns methods of forming a three-dimensional object, and polymerizable liquids such as dual cure resins useful for making a three-dimensional object by sterolithography, such as by continuous liquid interface production (CLIP).

A process for producing an article by three-dimensional printing includes applying a 1,1-di-activated vinyl compound-containing liquid binder over a predetermined area of a layer of solid particles. The liquid binder infiltrates gaps between the solid particles to form a first cross-sectional layer of an article, and the 1,1-di-activated vinyl compound reacts to solidify the liquid binder and bind the solid particles in the first cross-sectional layer of the article. Also provided is an article produced by the three-dimensional printing process, set forth herein.

A process for producing an article by three-dimensional printing includes applying a 1,1-di-activated vinyl compound-containing liquid binder over a predetermined area of a layer of solid particles. The liquid binder infiltrates gaps between the solid particles to form a first cross-sectional layer of an article, and the 1,1-di-activated vinyl compound reacts to solidify the liquid binder and bind the solid particles in the first cross-sectional layer of the article. Also provided is an article produced by the three-dimensional printing process, set forth herein.

The present disclosure refers to the development of novel random bipolymers, which are comprised of alkyl acrylate and alkoxy alkyl acrylate monomers, as hydrophobic and hydrophilic components, respectively. These bipolymers are synthesized by means of semi-continuous emulsion polymerization, under strict conditions of monomer deficiency, to ensure the randomness and homogeneity of the chains. The application in dissolution of these random bipolymers has shown a dehydrating capacity superior to that of polyethers and phenolic resins, with the additional advantage of being soluble in crude oil. The random bipolymers show excellent performance as breakers of water-in-crude oil emulsions, coalescers of water droplets and clarifiers of the removed aqueous phase, and are chemically stable under acidic conditions.

The present disclosure refers to the development of novel random bipolymers, which are comprised of alkyl acrylate and alkoxy alkyl acrylate monomers, as hydrophobic and hydrophilic components, respectively. These bipolymers are synthesized by means of semi-continuous emulsion polymerization, under strict conditions of monomer deficiency, to ensure the randomness and homogeneity of the chains. The application in dissolution of these random bipolymers has shown a dehydrating capacity superior to that of polyethers and phenolic resins, with the additional advantage of being soluble in crude oil. The random bipolymers show excellent performance as breakers of water-in-crude oil emulsions, coalescers of water droplets and clarifiers of the removed aqueous phase, and are chemically stable under acidic conditions.

The cross-linked polymer compound according to the present invention includes skeleton units of Formula (1)-(2),

##STR00001## wherein R.sup.1 is one or more selected from hydrogen, an alkyl group, a hydroxy group, an amino group, a mercapto group, a substituted carbonyl group, and any alkyl group having, as a substituent, one or more selected from a hydroxy group, an amino group, a mercapto group, and a substituted carbonyl group; X is one or more selected from —COO.sup.−, —SO.sub.3.sup.−, and —P(═O)(O.sup.−).sub.2; and Y is one or more selected from Li.sup.+, Na.sup.+, and K.sup.+, and

##STR00002## wherein R.sup.2 are each independently one or more selected from hydrogen, an alkyl group, a hydroxy group, an amino group, a mercapto group, a substituted carbonyl group, and any alkyl group having, as a substituent, one or more selected from a hydroxy group, an amino group, a mercapto group, and a substituted carbonyl group.

The cross-linked polymer compound according to the present invention includes skeleton units of Formula (1)-(2),

##STR00001## wherein R.sup.1 is one or more selected from hydrogen, an alkyl group, a hydroxy group, an amino group, a mercapto group, a substituted carbonyl group, and any alkyl group having, as a substituent, one or more selected from a hydroxy group, an amino group, a mercapto group, and a substituted carbonyl group; X is one or more selected from —COO.sup.−, —SO.sub.3.sup.−, and —P(═O)(O.sup.−).sub.2; and Y is one or more selected from Li.sup.+, Na.sup.+, and K.sup.+, and

##STR00002## wherein R.sup.2 are each independently one or more selected from hydrogen, an alkyl group, a hydroxy group, an amino group, a mercapto group, a substituted carbonyl group, and any alkyl group having, as a substituent, one or more selected from a hydroxy group, an amino group, a mercapto group, and a substituted carbonyl group.

The present application provides a film containing: a compound (A) containing at least one selected from the group consisting of a maleimide compound and a citraconimide compound; an organic peroxide (B) containing at least one selected from the group consisting of organic peroxides represented by specific formulae; and a hydroperoxide (C).

The invention relates to on-demand debondable pressure sensitive adhesive and laminating adhesive compositions and uses thereof. The debondable pressure sensitive adhesives and laminating adhesives are applied onto a substrate to form a bond, and upon exposure to electron beam or UV light energy source, the adhesive can dissociate from the substrate. The debondable pressure sensitive adhesives and laminating adhesives are particularly suitable for recycling in a circular economy.