The present invention relates to an antifouling coating composition, an antifouling coating film, a substrate with an antifouling coating film, a antifouling substrate, a method for producing substrate with an antifouling coating film, and a method for preventing substrate from fouling. The antifouling coating composition includes a hydrolyzable polymer (A) including at least one selected from the group consisting of a polymer (A1) having a structural unit represented by the formula (1) below and a polymer (A2) having a structural unit represented by the formula (2) below, a tertiary carboxylic acid component (B) including versatic acid, and an antifouling agent component (C).

##STR00001##

[In the formula (1), M is zinc or copper, and R.sup.1 independently at each occurrence is a hydrogen atom or a methyl group.]

—COO-M-O—COR.sup.2  (2)

[In the formula (2), M is zinc or copper, and R.sup.2 is an organic group.]

The present invention relates to an antifouling coating composition, an antifouling coating film, a substrate with an antifouling coating film, a antifouling substrate, a method for producing substrate with an antifouling coating film, and a method for preventing substrate from fouling. The antifouling coating composition includes a hydrolyzable polymer (A) including at least one selected from the group consisting of a polymer (A1) having a structural unit represented by the formula (1) below and a polymer (A2) having a structural unit represented by the formula (2) below, a tertiary carboxylic acid component (B) including versatic acid, and an antifouling agent component (C).

##STR00001##

[In the formula (1), M is zinc or copper, and R.sup.1 independently at each occurrence is a hydrogen atom or a methyl group.]

—COO-M-O—COR.sup.2  (2)

[In the formula (2), M is zinc or copper, and R.sup.2 is an organic group.]

To provide a water/oil repellent composition whereby it is possible to obtain an article which is excellent in each of water repellency, oil repellency and heavy rain durability, a method for its production, and an article which is excellent in each of water repellency, oil repellency, heavy rain durability and texture. The water/oil repellent composition comprises a copolymer containing structural units based on a monomer (a), structural units based on a monomer (b) and structural units based on a monomer (c). Here, the monomer (a) is a compound represented by (Z—Y).sub.nX (wherein Z is a C.sub.1-6 perfluoroalkyl group, etc.; Y is a bivalent organic group, etc.; n is 1 or 2; and X is a polymerizable unsaturated group). The monomer (b) is a (meth)acrylate having no polyfluoroalkyl group and having an alkyl group with at least 12 carbon atoms. The monomer (c) is a monomer having a poly(oxypolyfluoroalkylene) chain.

The invention provides a marine antifouling composition comprising: (a) 1 to 50% by weight of a cylic volatile methylsiloxane selected from the group consisting of hexamethylcyclotrisiloxane, octamethylcyclotetrasiloxane, decamethylcyclopenta-siloxane and dodeca-methylcyclohexasiloxane; (b) 1 to 20% of a surfactant selected from the group consisting of polyoxyethylene monostearate, steareth-40, octylphenoxy polyethoxyethanol, steareth-20, and a C.sub.11-C.sub.15 secondary alcohol ethoxylate; and (c) the balance water.

An article having antifouling properties and intended to be employed in aquatic uses, in particular marine uses, which comprises: a) a support, b) optionally, at least one primer coat on said support comprising at least one anticorrosive product, c) optionally, at least one intermediate primer coat promoting adhesion between the coats, d) at least one adhesion-promoting coat or tie coat, deposited on said primer coat or on said support when the primer coat is absent, and e) at least one antifouling coat or topcoat, deposited on said adhesion-promoting coat or tie coat.

A surface-treating composition including a fluorine-containing polymer which is able to form a layer having both high surface slip property and high friction durability. The surface-treating composition includes a first compound (a reactive fluorine-containing polymer which is a fluorine-containing silane polymer) and a second compound (a non-reactive fluorine-containing polymer which is a fluorine-containing oil), and the proportion of the first compound is 15 to 70% by mass with respect to the total mass of the first compound and the second compound.

The present invention relates to a PVC-based metallopolymer nanocomposite. The PVC-based metallopolymer nanocomposite includes a core-forming metal ion, a nucleophilic thiol having three mercapto functional groups, and poly(vinyl chloride) (PVC). The present invention also relates to a metallopolymer nanocomposite surface modified with silica that is prepared by grafting the PVC-based metallopolymer nanocomposite with a silane compound.

Disclosed is a flow meter comprising at least two measuring sensors spaced apart from each other, preferably ultrasonic sensors, whose measuring signals are reflected by a deposition-resistant reflector.

The present invention relates to adurable and multifunctional superhydrophobic coating composition and water based fabrication method of producing the durable and multifunctional superhydrophobic coating composition via chemical modification and functionalization of hydrophilic material by silanes under room temperature without any organic solvents. Synthesis of chemically modified cellulose nanofibers or clay in water forms excellent water repelling thin films upon coating over various substrates. The super hydrophobic materials are used as additive for paints, pigments, paper, varnish and, textile and used for various industrial applications such as construction of buildings and other super structures.

A hydroxyl-covered silicon quantum dot nanoparticle having a silicon core, a plurality of silicon quantum dots, and a plurality of hydrocarbon chains is illustrated. A first portion of a surface associated with the silicon core is passivated by a plurality of silicon hydroxyl groups (Si—OH). The silicon quantum dots are attached to a second portion of the surface associated with the silicon core. The hydrocarbon chains are bonded to each of the silicon quantum dots through a plurality of silicon carbide bonds (Si—C), wherein each termination of the hydrocarbon chains has a carbon hydroxyl group (C—OH), such that the hydroxyl-covered silicon quantum dot nanoparticle is thoroughly covered by the carbon hydroxyl groups (C—OH) and the silicon hydroxyl groups (Si—OH).