A thermochromic writing instrument, comprising: a writing body, storing a thermochromic ink therein, stored in a barrel; an operation body provided in the barrel to be operated to longitudinally move the writing body; a nib of the writing body configured to be capable of appearing from a front end of the writing instrument, wherein the writing instrument further includes a friction unit, rubbing handwriting in the thermochromic ink and capable of thermally changing the color of the handwriting by frictional heat generated at that time, and at least one clip body as the operation body, the friction unit is provided at a rear end of the barrel, and the clip body is provided in an area other than the rear end of the barrel.

A thermochromic writing instrument, comprising: a writing body, storing a thermochromic ink therein, stored in a barrel; an operation body provided in the barrel to be operated to longitudinally move the writing body; a nib of the writing body configured to be capable of appearing from a front end of the writing instrument, wherein the writing instrument further includes a friction unit, rubbing handwriting in the thermochromic ink and capable of thermally changing the color of the handwriting by frictional heat generated at that time, and at least one clip body as the operation body, the friction unit is provided at a rear end of the barrel, and the clip body is provided in an area other than the rear end of the barrel.

Disclosed is a coating composition suitable for coating onto a wall or other substrate to yield a dry-erase coating. The composition may be prepared by providing an aminoalkoxysilane, and in the substantial absence of water, reacting a portion of the aminoalkoxysilane with a carbonate and reacting a portion of the aminoalkoxysilane with an epoxy compound. These reactions will result in a coating composition that comprises a mixture of alkoxysilylamines and alkoxysilylcarbamates. The coating composition can also include an alkyl amine in an amount effective to catalytically deprotect alkoxy groups to yield silanol groups, facilitating fast crosslinking.

The present disclosure relates to a method for preparing a thermochromic water-based gel ink composition, as well as a thermochromic water-based gel ink composition thereof comprising a specific monocarboxylic or polycarboxylic acid. The present disclosure also concerns a writing instrument, such as a ballpoint pen, a brush pen, a marker, a highlighter, and a felt pen, comprising a thermochromic water-based gel ink composition according to the disclosure.

A marking system comprises a substrate having a surface coated with a color-triggering developer and a deactivating ink composition; and a marking composition comprising at least one color precursor. At least one “non-color developing portion” of the surface is coated with both the color-triggering developer and the deactivating ink composition, and at least one “color-developing portion” of the surface is coated with the color-triggering developer and is not coated with the deactivating ink composition. Color development occurs at the color-developing portion(s) and does not occur at the non-color developing portion(s) upon application of the marking composition to the surface of the substrate.

A marking system comprises a substrate having a surface coated with a color-triggering developer and a deactivating ink composition; and a marking composition comprising at least one color precursor. At least one “non-color developing portion” of the surface is coated with both the color-triggering developer and the deactivating ink composition, and at least one “color-developing portion” of the surface is coated with the color-triggering developer and is not coated with the deactivating ink composition. Color development occurs at the color-developing portion(s) and does not occur at the non-color developing portion(s) upon application of the marking composition to the surface of the substrate.

Provided is an aqueous ink composition for a writing instrument which is excellent in storage stability of particles, such as pigments, a writing property with the passage of time, followability, and quality of the drawn lines, though having a low viscosity, as compared with aqueous ink compositions prepared by using conventional thickeners and gelling agents, such as xanthan gum. The ink composition for a writing instrument described above includes an aqueous ink composition for a writing instrument containing 0.05 to 1.5% by mass of an oxidized cellulose and having a limiting viscosity of 16 mPa.Math.s or less derived from Casson's equation, a viscosity value of 100 to 3000 mPa.Math.s at a shear rate of 3.83 s.sup.−1 and a viscosity value of 10 to 40 mPa.Math.s at a shear rate of 383 s.sup.−1.

Scrub resistant inks and methods and apparatus for fabrication and use thereof are provided. Scrub-resistant ink compositions may include a dye for marking skin; and a solvent dissolving a marking effective amount of the dye, wherein the solvent comprises about 0.1 to about 90 percent of a polar aprotic solvent. Apparatus for marking patients may include an ink reservoir; an ink dispenser having a fluid connection to the ink reservoir to dispense the ink at a desired rate to mark a patient; and a scrub resistant ink disposed in the ink reservoir. Methods for forming scrub-resistant ink compositions may include providing a marking effective amount of a dye suitable for use in marking skin; and mixing the dye with a first solvent comprising 0.1% to 90% of a polar aprotic solvent. Methods of marking patients may include applying an ink as recited above to a body part of the patient.

Scrub resistant inks and methods and apparatus for fabrication and use thereof are provided. Scrub-resistant ink compositions may include a dye for marking skin; and a solvent dissolving a marking effective amount of the dye, wherein the solvent comprises about 0.1 to about 90 percent of a polar aprotic solvent. Apparatus for marking patients may include an ink reservoir; an ink dispenser having a fluid connection to the ink reservoir to dispense the ink at a desired rate to mark a patient; and a scrub resistant ink disposed in the ink reservoir. Methods for forming scrub-resistant ink compositions may include providing a marking effective amount of a dye suitable for use in marking skin; and mixing the dye with a first solvent comprising 0.1% to 90% of a polar aprotic solvent. Methods of marking patients may include applying an ink as recited above to a body part of the patient.

Disclosed herein are printable compositions that include a UV-A blocking compound, wherein the composition is free of colorants that are visible under white light or UV light. Also disclosed herein are images formed by printing the printable composition on a substrate surface, wherein the substrate surface includes one or more Uv fluorescent materials on at least a portion thereof. Also disclosed herein are methods of forming an image on a substrate including printing a selected amount of the printable composition on top of a UV fluorescent material.