Thermoset compositions and methods for forming three-dimensional articles via an additive fabrication process, and articles made therefrom are disclosed herein. In an embodiment, a composition comprises a first network-forming component comprising a TPA-based polyester comprising a backbone and having at least 2 polymerizable groups, one or more first network monomers, and a first network initiator. The backbone of the TPA-based polyester comprises the reaction product of a terephthalic acid and a polyol. The composition may further comprise a second network-forming component.

Thermoset compositions and methods for forming three-dimensional articles via an additive fabrication process, and articles made therefrom are disclosed herein. In an embodiment, a composition comprises a first network-forming component comprising a TPA-based polyester comprising a backbone and having at least 2 polymerizable groups, one or more first network monomers, and a first network initiator. The backbone of the TPA-based polyester comprises the reaction product of a terephthalic acid and a polyol. The composition may further comprise a second network-forming component.

Provided are an inkjet printing apparatus and a method for inspecting an inkjet head using same. The inkjet printing apparatus comprises: an inspection stage unit on which an inspection substrate is seated; an inkjet head unit including at least one inkjet head that ejects ink containing dipoles and a solvent in which the dipoles disperse, on the inspection stage unit; and a particle count inspection unit that is located so as to be spaced apart from the inkjet head unit in one direction. The particle count inspection unit comprises: a first heat treatment unit that is located on the top portion of the inspection stage unit; and a first sensing unit that is located on the bottom portion of the inspection stage unit and measures the number of dipoles sprayed onto the inspection substrate.

A clear ink includes resin particles, water, and a compound represented by General Formula (1) below. The resin particles have a volume average particle diameter of 50 nm or less. A dried film of the clear ink has glass transition temperatures (Tg) at 50 degrees Celsius or higher and at lower than 0 degrees Celsius.

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In the General Formula (1), R.sup.1 represents an alkyl group having 1 or more but 4 or less carbon atoms.

A clear ink includes resin particles, water, and a compound represented by General Formula (1) below. The resin particles have a volume average particle diameter of 50 nm or less. A dried film of the clear ink has glass transition temperatures (Tg) at 50 degrees Celsius or higher and at lower than 0 degrees Celsius.

##STR00001##

In the General Formula (1), R.sup.1 represents an alkyl group having 1 or more but 4 or less carbon atoms.

Curable ink compositions include at least one aromatic (meth)acrylate, at least one multifunctional (meth)acrylate with heteroaromatic groups, fused aromatic groups, heteroalkylene groups, or a group containing both heteroalkylene and aromatic groups, and a photoinitiator. The curable ink composition is Inkjet printable, having a viscosity of 30 centipoise or less at a temperature of from room temperature to 35° C., and is free from solvents. The ink composition, when printed and cured has a refractive index of 1.55 or greater, and is optically clear. The cured ink composition, when cured to a thickness of from 1-16 micrometers, has a surface roughness of less than or equal to 5 nanometers.

Curable ink compositions include at least one aromatic (meth)acrylate, at least one multifunctional (meth)acrylate with heteroaromatic groups, fused aromatic groups, heteroalkylene groups, or a group containing both heteroalkylene and aromatic groups, and a photoinitiator. The curable ink composition is Inkjet printable, having a viscosity of 30 centipoise or less at a temperature of from room temperature to 35° C., and is free from solvents. The ink composition, when printed and cured has a refractive index of 1.55 or greater, and is optically clear. The cured ink composition, when cured to a thickness of from 1-16 micrometers, has a surface roughness of less than or equal to 5 nanometers.

Powdering on a front surface of a printed matter or the like is appropriately performed. A printing apparatus configured to perform printing on a medium includes: an ink ejection portion configured to eject an ink to the medium; and a powdering portion configured to perform powdering that applies powder to the medium. The powdering portion includes: a liquid applying device configured to apply, to the medium, a powder containing liquid that is a liquid including the powder and a solvent and an energy ray emitting portion configured to irradiate the powder containing liquid applied to the medium with energy rays. The powder containing liquid is a liquid that generates heat when irradiated with energy rays. The energy ray emitting portion irradiates the powder containing liquid applied to the medium with energy rays to evaporate the solvent of the powder containing liquid, so that the powder adheres to the medium.

A method for producing a laminated body including a first curable liquid composition and a second curable liquid composition, the method including: forming a first liquid layer formed of the first curable liquid composition; impacting the second curable liquid composition onto the first liquid layer, to form a second liquid droplet layer formed of the second curable liquid composition inside the first liquid layer or at a lower part of the first liquid layer in a direction in which second liquid droplets for the second liquid droplet layer are impacted onto the first liquid layer; and curing the first liquid layer and the second liquid droplet layer.

A method for producing a laminated body including a first curable liquid composition and a second curable liquid composition, the method including: forming a first liquid layer formed of the first curable liquid composition; impacting the second curable liquid composition onto the first liquid layer, to form a second liquid droplet layer formed of the second curable liquid composition inside the first liquid layer or at a lower part of the first liquid layer in a direction in which second liquid droplets for the second liquid droplet layer are impacted onto the first liquid layer; and curing the first liquid layer and the second liquid droplet layer.